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党静, 戚萌, 朱涛林, 等. 太阳能辐射数据驱动下光电催化与光伏电解协同制氢的地区适应性分析[J]. 太阳能学报, 2026,47(2):797-806.
党静, 戚萌, 朱涛林, et al. 太阳能辐射数据驱动下光电催化与光伏电解协同制氢的地区适应性分析[J]. 2026, 47(2): 797-806.
党静, 戚萌, 朱涛林, 等. 太阳能辐射数据驱动下光电催化与光伏电解协同制氢的地区适应性分析[J]. 太阳能学报, 2026,47(2):797-806. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1985.
党静, 戚萌, 朱涛林, et al. 太阳能辐射数据驱动下光电催化与光伏电解协同制氢的地区适应性分析[J]. 2026, 47(2): 797-806. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1985.
基于全国各省的太阳能辐射数据
深入分析光电催化直接制氢和光伏电解间接制氢两种技术在不同地理区域的适应性和效率变化。通过综合评估全年辐照度、日照时长、波长分布及昼夜变化等关键因素
揭示了不同辐射条件对制氢效率的影响。首先
光电催化剂的性能取决于吸收波长范围
不同催化剂在光谱中的吸收效率差异显著
TiO2的实际制氢能力稳定
因环境友好、高稳定性和低成本成为当前的主力。通过与CdS催化剂制氢能力的对比
TiO2需通过改性等手段
进一步扩大可吸收波长范围
提高反应效率
进而提升可见光利用率
以适应工业化需求。其次
太阳辐射的季节性波动会影响光电催化剂的制氢能力
夏季制氢量最高
冬季最低
通过优化催化剂可提升全年制氢效率。光伏制氢在所有季节中均优于光电催化
特别在夏季
协同光伏与光电催化技术可最大化太阳能利用率
平衡季节性波动影响。分析表明
西部和南部地区
特别是西藏等地的太阳辐照度与制氢能力最高。未来
需深入研究光电催化剂优化与光伏发电协同制氢
以实现更高效的、更低成本的氢能生产。
This study investigates the adaptability and efficiency variations of two hydrogen production technologies
direct photoelectrocatalytic hydrogen production and indirect photovoltaic electrolysis hydrogen production
across diverse geographical regions
utilizing solar radiation data from various provinces. By systematically assessing key factors including annual radiation intensity
daylight duration
wavelength distribution
and diurnal variations
the study elucidates the impact of differing radiation conditions on hydrogen production efficiency. The performance of photoelectrocatalysts is contingent upon their absorption wavelength range. Significant variations in absorption efficiency across the spectrum are observed among different catalysts. TiO stands out for its stable hydrogen production capabilities
attributed to its environmental friendliness
high stability
and low cost
positioning it as the current predominant catalyst. A comparative analysis with CdS catalysts reveals that TiO necessitates modifications to broaden its absorption wavelength range
enhance reaction efficiency
and improve the utilization of visible light. Seasonal fluctuations in solar radiation influence the hydrogen production capabilities of photoelectrocatalysts. Hydrogen production reaches its zenith in summer and is at its nadir in winter. Optimizing the catalysts can bolster hydrogen production efficiency year-round. Photovoltaic hydrogen production consistently outperforms photoelectrocatalysis across all seasons
particularly in summer. Integrating photovoltaic and photoelectrocatalytic technologies can optimize solar energy utilization and mitigate seasonal variations. Regions in the west and south
notably areas such as Tibet
exhibit the highest solar radiation and hydrogen production potential. Future research should concentrate on refining photoelectrocatalysts and synergizing photovoltaic power generation with hydrogen production to achieve more efficient and cost-effective hydrogen energy production.
赵明智, 段佩瑶, 常春, 等. 太阳能辐射资源计算分析与特性模拟方法[J]. 太阳能学报, 2023, 44(3): 22-28.
李建林, 梁忠豪, 李光辉, 等. 太阳能制氢关键技术研究[J]. 太阳能学报, 2022, 43(3): 2-11.
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GOTO Y, HISATOMI T, WANG Q, et al.A particulate photocatalyst water-splitting panel for large-scale solar hydrogen generation[J]. Joule, 2018, 2(3): 509-520.
SHI X J, JEONG H, OH S J, et al.Unassisted photoelectrochemical water splitting exceeding 7% solar-to-hydrogen conversion efficiency using photon recycling[J]. Nature communications, 2016, 7: 11943.
LEE M, TURAN B, BECKER J P, et al.A bias-free, stand-alone, and scalable photovoltaic-electrochemical device for solar hydrogen production[J]. Advanced sustainable systems, 2020, 4(8): 2000070.
LIM J Y, SAFDER U, HOW B S, et al.Nationwide sustainable renewable energy and Power-to-X deployment planning in South Korea assisted with forecasting model[J]. Applied energy, 2021, 283: 116302.
LI Y N, LI L Y, YUAN H K, et al.Scaling solar photocatalytic hydrogen production in China: Integrated geospatial-meteorological analysis[J]. Applied energy, 2025, 381: 125179.
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