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钟金豹, 范浩熙, 王永鹏, 等. 改性海泡石基复合蓄热材料的制备与性能[J]. 太阳能学报, 2025,(11):129-135.
钟金豹, 范浩熙, 王永鹏, et al. 改性海泡石基复合蓄热材料的制备与性能[J]. 2025, (11): 129-135.
钟金豹, 范浩熙, 王永鹏, 等. 改性海泡石基复合蓄热材料的制备与性能[J]. 太阳能学报, 2025,(11):129-135. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1303.
钟金豹, 范浩熙, 王永鹏, et al. 改性海泡石基复合蓄热材料的制备与性能[J]. 2025, (11): 129-135. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1303.
通过洗涤、干燥和高温煅烧等物理改性方法对海泡石处理得到改性海泡石(ST)
采用真空吸附法以月桂酸(LA)、棕榈酸(PA)二元共晶复合相变材料制备改性海泡石基月桂酸-棕榈酸复合相变蓄热材料(LA-PA/ST)。通过扫面差示量热仪(DSC)、傅里叶变换红外光谱仪(FTIR)、扫描电子显微镜(SEM)、热重分析仪(TG)、热常数分析仪(Hot Disk)及热循环实验等测试方法对LA-PA/ST复合相变材料的热物性、结构分析、热稳定性、导热系数和热可靠性进行系统研究。结果表明:LA-PA与ST的最佳吸附质量比为1∶5时
LA-PA均匀分布在ST的孔隙中且在熔融状态下不发生泄漏。纯LA-PA相变材料导热系数为0.29 W/(m·K)
而LA-PA/ST导热系数为1.26 W/(m∙K)
与纯LA-PA相比
LA-PA/ST导热系数大大提升;且在100 ℃温度下时几乎不失重
初始失重1%的温度为128.36 ℃;经过200次热循环实验后相变温度降低0.03 ℃;搭建实验平台进行光热转换特性测试
蓄热时间减少461 s
放热时间增加1711 s;实验数据表明LA-PA/ST具有良好的导热性、热稳定性和热循环稳定性。
Through physical modification methods such as washing
drying
and high-temperature calcination
sepiolite was treated to obtain modified sepiolite (ST). Using the vacuum adsorption method
ST was used as the support to prepare a lauric acid (LA) and palmitic acid (PA) binary eutectic composite phase change materials
resulting in modified sepiolite-based lauric acid-palmitic acid composite phase change heat storage materials (LA-PA/ST). The thermophysical properties
structural features
thermal conductivity and thermal reliability of the composite phase change materials (PCMs) were systematically investigated by testing methods such as differential scanning calorimeter (DSC)
Fourier transform infrared spectroscopy (FTIR)
scanning electron microscope (SEM) thermogravimetric analyzer (TG)
HotDisk analyzer and thermal cycling experiments. The results indicated that at an optimal adsorption mass ratio of LA-PA to ST of 1:5
LA-PA was uniformly distributed within the pores of ST and showed no leakage in the molten state. The thermal conductivity of pure LA-PA is 0.29 W/(m·K)
whereas that of LA-PA/ST increases significantly to 1.26 W/(m·K). Additionally
the composite exhibited nearly no weight loss at 100 ℃
with initial 1% weight loss occurring at 128.36 ℃. After 200 thermal cycling experiments
the phase change temperature decreased by only 0.03 ℃. An experimental setup was constructed to evaluate the photothermal conversion performance
revealing a 461 s reduction in heat storage time and a 1711 s extension in heat release time. These experimental data demonstrate that LA-PA/ST possesses good thermal conductivity
thermal stability
and thermal cycling stability.
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