EN甲烷与太阳能互补利用零碳排放制氢系统
甲烷与太阳能互补利用零碳排放制氢系统
- 太阳能学报 2025年第11期 页码：500-508
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DOI：doi:10.19912/j.0254-0096.tynxb.2024-1252
中图分类号： K123-
网络出版：2025-12-04，
纸质出版：2025-12-04
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马文静, 韩巍, 宋新阳, 等. 甲烷与太阳能互补利用零碳排放制氢系统[J]. 太阳能学报, 2025,(11):500-508.
马文静, 韩巍, 宋新阳, et al. 甲烷与太阳能互补利用零碳排放制氢系统[J]. 2025, (11): 500-508.
马文静, 韩巍, 宋新阳, 等. 甲烷与太阳能互补利用零碳排放制氢系统[J]. 太阳能学报, 2025,(11):500-508. DOI： doi:10.19912/j.0254-0096.tynxb.2024-1252.
马文静, 韩巍, 宋新阳, et al. 甲烷与太阳能互补利用零碳排放制氢系统[J]. 2025, (11): 500-508. DOI： doi:10.19912/j.0254-0096.tynxb.2024-1252.
摘要
为实现高效低碳制氢
提出一种甲烷与太阳能互补利用的零碳排放制氢系统。该系统将一段式甲烷重整解耦为两段式甲烷重整：部分高温烟气作为反应物引入预重整器
预重整反应热由太阳能提供;重整反应热由驰放气与电解池排放的氧气燃烧提供。剩余烟气预热完待电解的水后直接进行冷凝并分离CO2。对新系统和参比系统进行能量和㶲平衡分析
结果表明新系统能量和㶲效率提升至42.88%和39.21%
与参比系统相比分别提高了4.77和4.53个百分点。采用图像㶲分析方法揭示系统性能提升的主要原因：对太阳能进行热化学和电化学综合利用
不仅提高了太阳能利用效率
还取消了高能耗CO2分离装置
㶲效率共提高4.23个百分点;两段式甲烷和烟气重整减少燃烧过程中将高品位甲烷化学能转化为低品位热能
同时也减少了换热过程的㶲损失
㶲效率共提高2.02个百分点。
Abstract
To achieve efficient and low-carbon hydrogen generation
a zero carbon emission hydrogen production system combining methane and solar energy is proposed. The system decouples one-stage methane reforming into two-stage methane reforming： a portion of high-temperature flue gas is introduced into the pre-reforming reactor as reactants
and the reaction heat is provided by solar energy; The reaction heat during the reforming process is providedby combusting purge gas with oxygen from the electrolytic cell. Another part of the flue gas is directly condensed and separated carbon dioxide after preheating the water to be electrolyzed. Energy and exergy balance analyses are conducted on the proposed and reference systems. The results demonstrate that the energy and exergy efficiencies of the proposed system are improved to 42.88% and 39.21%
respectively
by 4.77 and 4.53 percentage points compared to the reference system. Using the exergy utilization diagram （EUD） reveals the main reasons for improved system performance. Comprehensive utilization of solar energy through thermochemistry and electrochemistry. This not only increases the efficiency of solar energy utilization
but also eliminates high-energy consumption carbon dioxide separation devices
resulting in a total increase of 4.23 percentage points in exergy efficiency. The two-stage methane with flue gas reforming process reduces the exergy destruction of high-grade methane chemical energy into low-grade thermal energy during combustion
as well as the heat loss in the heat exchange process
resulting in a total increase of 2.02 percentage points in exergy efficiency.
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references
刘贵洲, 窦立荣, 黄永章, 等. 氢能利用的瓶颈分析与前景展望[J]. 天然气与石油, 2021, 39(3): 1-9.
RAO V T, SEKHAR Y R, PANDEY A K, et al.Thermal analysis of hybrid photovoltaic-thermal water collector modified with latent heat thermal energy storage and two side serpentine absorber design[J]. Journal of energy storage, 2022, 56: 105968.
张盛, 郑津洋, 戴剑锋, 等. 可再生能源大规模制氢及储氢系统研究进展[J]. 太阳能学报, 2024, 45(1): 457-465.
ABDIN Z, WEBB C J, GRAY E M.Modelling and simulation of a proton exchange membrane (PEM) electrolyser cell[J]. International journal of hydrogen energy, 2015, 40(39): 13243-13257.
SHEU E J, MOKHEIMER E M A, GHONIEM A F. A review of solar methane reforming systems[J]. International journal of hydrogen energy, 2015, 40(38): 12929-12955.
雷宇, 袁熹, 王颖, 等. 基于太阳能的甲烷重整制氢技术研究进展[J]. 太阳能学报, 2022, 43(12): 154-160.
李勇霞, 段立强, 潘盼, 等. 基于太阳能热驱动甲烷重整制氢的燃料电池发电系统性能研究[J]. 太阳能学报, 2022, 43(9): 131-138.
GUO K, LIU M K, WANG B, et al.Hydrogen production and solar energy storage with thermo-electrochemically enhanced steam methane reforming[J]. Science bulletin, 2024, 69(8): 1109-1121.
DONG H, FANG J, YAN X Y, et al.Experimental investigation of solar hydrogen production via photo-thermal driven steam methane reforming[J]. Applied energy, 2024, 368: 123532.
王秋实, 蒋潇甫, 段立强, 等. 高温太阳能热化学与甲烷互补的SOFC-GT-KC复合动力系统研究[J]. 太阳能学报, 2023, 44(10): 218-228.
ZENG W Q, LI L, SONG M X, et al.The effect of different atmosphere treatments on the performance of Ni/Nb-Al2O3 catalysts for methane steam reforming[J]. International journal of hydrogen energy, 2023, 48(16): 6358-6369.
王彬, 郭轲, 邵煜, 等. 太阳能甲烷重整制氢研究进展[J]. 洁净煤技术, 2024, 30(9): 1-25.
HE S, LI S, GAO L.Proposal and energy saving analysis of novel methanol-electricity polygeneration system based on staged coal gasification method[J]. Energy conversion and management, 2021, 233: 113931.
ZHAO Y J, LIU Q, DUAN Y Y, et al.A multi-dimensional feasibility analysis of coal to methanol assisted by green hydrogen from a life cycle viewpoint[J]. Energy conversion and management, 2022, 268: 115992.
XIN Y, XING X L, LI X, et al.A biomass-solar hybrid gasification system by solar pyrolysis and PV-solid oxide electrolysis cell for sustainable fuel production[J]. Applied energy, 2024, 356: 122419.
徐钢, 张钟, 吴志聪, 等. 基于绿氢和生物质富氧燃烧技术的零碳甲醇合成系统[J]. 动力工程学报, 2022, 42(10): 925-932.
YUN S, LEE J, CHO H, et al.Oxy-fuel combustion-based blue hydrogen production with the integration of water electrolysis[J]. Energy conversion and management, 2023, 291: 117275.
SU B S, WANG Y L, XU Z L, et al.Novel ways for hydrogen production based on methane steam and dry reforming integrated with carbon capture[J]. Energy conversion and management, 2022, 270: 116199.
NIKOO M K, AMIN N A S. Thermodynamic analysis of carbon dioxide reforming of methane in view of solid carbon formation[J]. Fuel processing technology, 2011, 92(3): 678-691.
LI D, DUAN L Q.Techno-economic analysis of a new thermal storage operation strategy for a solar aided liquid air energy storage system[J]. Journal of energy storage, 2024, 78: 110029.
WANG Q S, DUAN L Q, LU Z Y, et al.Thermodynamic performance coMParison of SOFC-MGT-CCHP systems coupled with two different solar methane steam reforming processes[J]. International journal of hydrogen energy, 2023, 48(71): 27473-27491.
CAO Y L, ZHANG H, LIU X Y, et al.A strategy of mid-temperature natural gas based chemical looping reforming for hydrogen production[J]. International journal of hydrogen energy, 2022, 47(24): 12052-12066.
WANG H S, LI W J, LIU T, et al.Thermodynamic analysis and optimization of photovoltaic/thermal hybrid hydrogen generation system based on complementary combination of photovoltaic cells and proton exchange membrane electrolyzer[J]. Energy conversion and management, 2019, 183: 97-108.
AOUALI F Z, BECHERIF M, RAMADAN H S, et al.Analytical modelling and experimental validation of proton exchange membrane electrolyser for hydrogen production[J]. International journal of hydrogen energy, 2017, 42(2): 1366-1374.
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