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石孟可, 张军. 抗酸胶膜组合封装TOPCon电池双玻组件可靠性研究[J]. 太阳能学报, 2025,(10):313-319.
石孟可, 张军. 抗酸胶膜组合封装TOPCon电池双玻组件可靠性研究[J]. 2025, (10): 313-319.
石孟可, 张军. 抗酸胶膜组合封装TOPCon电池双玻组件可靠性研究[J]. 太阳能学报, 2025,(10):313-319. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1119.
石孟可, 张军. 抗酸胶膜组合封装TOPCon电池双玻组件可靠性研究[J]. 2025, (10): 313-319. DOI: doi:10.19912/j.0254-0096.tynxb.2024-1119.
首先研究抗酸聚乙烯-醋酸乙烯酯(EVA)胶膜的材料性能
包括醋酸浓度值、体积电阻率、高温剥离力、抗酸EVA和抗酸共挤聚乙烯-醋酸乙烯酯/聚乙烯-α-烯烃(EPE)胶膜组合封装双玻小组件的电致发光(EL)图
然后对比研究抗酸EVA胶膜+抗酸共挤EPE胶膜组合、常规双共挤EPE胶膜组合、抗酸双EVA胶膜组合封装n型TOPCon电池双玻组件的可靠性。实验结果表明
抗酸EVA胶膜在高压加速老化测试(PCT)后释放的醋酸含量较常规EVA胶膜减少;抗酸胶膜组合封装双玻小组件在PCT144 h和DH1000 h老化后EL无明显发黑腐蚀现象
说明在此湿热条件下抗酸EVA胶膜不会明显腐蚀TOPCon电池;抗酸EVA胶膜体积电阻率高于1015 Ω·cm
满足光伏组件绝缘性使用要求;在80 ℃下
抗酸EVA胶膜与玻璃仍保持一定的粘结力
具备高温抗脱层能力。抗酸共挤EPE+抗酸EVA胶膜组合和常规双共挤EPE胶膜组合封装n型TOPCon电池双玻组件在DH3000 h、PID288 h及TC600老化后
功率衰减PL均低于4%
符合国际电工委员会(IEC)标准。因此
抗酸共挤EPE+抗酸EVA胶膜组合可取代常规双共挤EPE胶膜组合封装组件
满足胶膜粒子供应
实现降本提效。
Firstly
four experiments were conducted to assess the properties of acetic acid-resistant ethylene-vinyl acetate copolymer(EVA) film: acid concentration test
high temperature stripping test
volume resistivity test
and electroluminescence(EL) test of small double-glass modules encapsulated with a combination of acetic acid-resistant EVA and ethylene vinyl acetate/polyolefin elastomer(EPE). Secondly
the reliability of N-type TOPCon solar cells' double-glass photovoltaic modules——encapsulated with acetic acid-resistant EVA and EPE
conventional EPE and EPE
as well as combinations of acetic acid-resistant EVA and EVA——is meticulously examined. The results indicate that the acetic acid concentration in acetic acid-resistant EVA is lower than that in conventional EVA after the PCT test. Furthermore
there is no significant black discoloration observed due to corrosion on the small modules' EL after both the PCT144 h and DH1000 h tests. This suggests that acetic acid-resistant EVA exhibits minimal corrosion effects on TOPCon solar cells under these conditions. The volume resistivity of acetic acid-resistant EVA exceeds 10 Ω·cm
thereby meeting the insulation requirements for photovoltaic (PV) modules. The acetic acid-resistant EVA exhibits a stable adhesion to glass at a temperature of 80 ℃
thereby mitigating the risk of delamination under high-temperature conditions. The power degradation of double-glass PV modules encapsulated by acetic acid-resistant EPE and EVA combination and double EPE combination is less than 4% after DH3000 h
PID288 h and TC600 test
which can meet the International Electrotechnical Commission(IEC) standard. Therefore
the combination of acetic acid-resistant EPE and EVA can be utilized to encapsulate double-glass modules
serving as a replacement for the conventional EPE and EVA combination. This approach effectively meets the demand for encapsulation film particles while contributing to cost reduction.
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GB/T1410—2006, 固体绝缘材料体积电阻率和表面电阻率试验方法[S].
ASTM D903-98(2017), 粘合剂剥离或剥离强度的标准试验方法[S].
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GB/T 29848—2018, 光伏组件封装用乙烯-醋酸乙烯酯共聚物(EVA)胶膜[S].
朱威武, 李宾, 袁晓, 等. EVA封装胶膜的功能复合改性与耐老化性能[J]. 太阳能学报, 2019, 40(6): 1576-1582.
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