疏水/超疏水表面防/除冰原理及其研究进展

高淑蓉; 焦丽丽; 易孟超; 金佳鑫; 王晓东

doi:10.7638/kqdlxxb-2020.0179

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疏水/超疏水表面防/除冰原理及其研究进展

研究论文 | 更新时间：2026-05-28

- 疏水/超疏水表面防/除冰原理及其研究进展
- Mechanism and research progress of anti/de-icing using hydrophobic/superhydrophobic surfaces
- 空气动力学学报 2021年39卷第2期页码：151-160
- 作者机构：
  
  1. 华北电力大学新能源电力系统国家重点实验室,北京,102206
  2. 华北电力大学工程热物理研究中心,北京,102206
- 作者简介：
  
  高淑蓉（1989-），女，陕西人，博士，讲师，研究方向：液滴传热传质，撞击结冰. E-mail：18010188595@163.com
  王晓东*（1973-），男，博士，教授，研究方向：湿润动力学与界面现象，相变传热与微尺度换热. E-mail：wangxd99@gmail.com
- 基金信息：
  
  国家自然科学基金重点项目（51936004）;国家自然科学基金青年基金项目（52006068）;北京市自然科学基金面上项目（3212025）;中央高校基本科研业务专项资金项目（2020MS060）
- DOI：10.7638/kqdlxxb-2020.0179
  中图分类号： TQ028.8
- 纸质出版：2021
- 稿件说明：
移动端阅览
高淑蓉, 焦丽丽, 易孟超, 等. 疏水/超疏水表面防/除冰原理及其研究进展[J]. 空气动力学学报, 2021, 39(2): 151−160.

GAO Shurong, JIAO Lili, YI Mengchao, et al. Mechanism and research progress of anti/de-icing using hydrophobic/superhydrophobic surfaces[J]. 2021, 39(2): 151-160.
高淑蓉, 焦丽丽, 易孟超, 等. 疏水/超疏水表面防/除冰原理及其研究进展[J]. 空气动力学学报, 2021, 39(2): 151−160. DOI： 10.7638/kqdlxxb-2020.0179

GAO Shurong, JIAO Lili, YI Mengchao, et al. Mechanism and research progress of anti/de-icing using hydrophobic/superhydrophobic surfaces[J]. 2021, 39(2): 151-160. DOI： 10.7638/kqdlxxb-2020.0179.

摘要

液体防冰、电热防冰、气热防冰、机械除冰等传统的防/除冰技术具有显著的防/除冰效果，但存在消耗能源大、防冰时间有限以及除冰不彻底等问题，而基于疏水/超疏水表面的防/除冰技术则具有独特的优势。本文首先阐述了利用疏水表面和超疏水表面防/除冰的原理及其影响因素；然后，总结了常用的疏水表面和超疏水表面在防/除冰中存在的问题，并指出利用液滴的反弹特性可更加有效地抑制结冰；最后，提出未来有必要对撞击液滴的动力学过程、传热过程和结冰过程的耦合特性进行系统研究，进而为利用液滴的反弹特性抑制结冰提供一定的理论指导。

Abstract

Inhibiting icing of droplets is of great significance in practical engineering applications

and thus

employing an economical and efficient anti/de-icing method is a research hotspot. Traditional technologies such as liquid anti-icing

electric heating anti-icing

air heating anti-icing

and mechanical de-icing have significant anti/de-icing effects

but they also suffer from issues such as high energy consumption

limited anti-icing time

and incomplete de-icing effect; whereas the anti/de-icing technique based on hydrophobic/superhydrophobic surfaces can have obvious advantages. In this study

we first review the mechanism and affecting factors of anti/de-icing process using hydrophobic and superhydrophobic surfaces. Then

we address the existing problems for this anti/de-icing technique

and point out that the efficiency of the anti/de-icing process can be further improved by using the rebound characteristics of droplets. Finally

we suggest that it is necessary to systematically study the coupling characteristics of the kinetic process

the heat transfer process and the freezing process of impacting droplets in the future

so that it can provide a theoretical guidance for ice inhibition using the rebound characteristics of droplets.

关键词

Keywords

references

ZHANG X, LIU X, MIN J C, et al. Shape variation and unique tip formation of a sessile water droplet during freezing[J]. Applied Thermal Engineering, 2019: 927-934.

BAI G Y, GAO D, LIU Z, et al. Probing the critical nucleus size for ice formation with graphene oxide nanosheets[J]. Nature, 2019, 576(7787): 437-441.

SOSSO G C, CHEN J, COX S F, et al. Crystal nucleation in liquids: open questions and future challenges in molecular dynamics simulations[J]. Chemical Reviews, 2016, 116(12): 7078-7116.

YANG G M, GUO K H, LI N, et al. Freezing mechanism of supercooled water droplet impinging on metal surfaces[J]. International Journal of Refrigeration-revue Internationale Du Froid, 2011, 34(8): 2007-2017.

JIANG X L, ZHOU H Y, HE K, et al. Anti-icing performance degradation of fan blades using super-hydrophobic coating[J]. High voltage technology, 2019, 45(1), 167-172. (in Chinese)

VAZIRINASAB E, MAGHSOUDI K, JAFARI R, et al. A comparative study of the icephobic and self-cleaning properties of Teflon materials having different surface morphologies[J]. Journal of Materials Processing Technology, 2020.

RICO V J, LOPEZSANTOS C, VILLAGRA M, et al. Hydrophobicity, freezing delay, and morphology of laser-treated aluminum surfaces[J]. Langmuir, 2019, 35(19): 6483-6491.

WANG L F, HE Z D. The impact of aircraft icing on flight safety[N]. China Aviation News, 2018-04-17(006). (in Chinese)

ZHU Y C. Research on ice-coating growth model and key parameters of overhead transmission lines[D]. Xidian University, 2017. (in Chinese)

VAZIRINASAB E, JAFARI R, MOMEN G. Application of superhydrophobic coatings as a corrosion barrier: a review[J]. Surface and Coatings Technology, 2018, 341: 40–56.

WANG L P, KONG W L, WANG F X, et al. Effect of nucleation time on freezing morphology and type of a water droplet impacting onto cold substrate[J]. International Journal of Heat and Mass Transfer, 2019: 831-842.

ALIZADEH A, YAMADA M, LI R, et al. Dynamics of ice nucleation on water repellent surfaces[J]. Langmuir, 2012, 28(6): 3180-3186.

HAO P F, LV C J, ZHANG X W, et al. Freezing of sessile water droplets on surfaces with various roughness and wettability[J]. Applied Physics Letters, 2014, 104(16).

RICHARD D, QUÉRÉ D. Bouncing water drops[J]. Europhysics Letters, 2000, 50: 769–775.

FU Q T, LIU E J, WILSON P W, et al. Ice nucleation behaviour on sol–gel coatings with different surface energy and roughness[J]. Physical Chemistry Chemical Physics, 2015, 17(33): 21492-21500.

RUAN M, LI W, WANG B S, et al. Preparation and anti-icing behavior of superhydrophobic surfaces on aluminum alloy substrates[J]. Langmuir, 2013, 29(27): 8482-8491.

ZHAN X L, YAN Y D, ZHANG Q H, et al. A novel superhydrophobic hybrid nanocomposite material prepared by surface-initiated AGET ATRP and its anti-icing properties[J]. Journal of Materials Chemistry, 2014, 2(24): 9390-9399.

JUNG S, DORRESTIJN M, RAPS D, et al. Are superhydrophobic surfaces best for icephobicity[J]. Langmuir, 2011, 27(6): 3059-3066.

EBERLE P, TIWARI M K, MAITRA T, et al. Rational nanostructuring of surfaces for extraordinary icephobicity[J]. Nanoscale, 2014, 6(9): 4874-4881.

GUO P, ZHENG Y M, WEN M X, et al. Icephobic/anti-icing properties of micro/nanostructured surfaces[J]. Advanced Materials, 2012, 24(19): 2642-2648.

FLETCHER N H J. Size effect in heterogeneous nucleation[J]. Journal of Chemical Physics, 1958, 29(3): 572-576.

KETCHAM W M, HOBBS P V. An experimental determination of the surface energies of ice[J]. Philosophical Magazine, 1969, 19(162): 1161-1173.

TOURKINE P, MERRER M L, QUERE D, et al. Delayed freezing on water repellent materials[J]. Langmuir, 2009, 25(13): 7214-7216.

JAMIESON M J, NICHOLSON C E, COOPER S J, et al. First study on the effects of interfacial curvature and additive interfacial density on heterogeneous nucleation. ice crystallization in oil-in-water emulsions and nanoemulsions with added 1-heptacosanol[J]. Crystal Growth Design, 2005, 5(2): 451-459.

XU D H, JOHNSON W L. Geometric model for the critical-value problem of nucleation phenomena containing the size effect of nucleating agent[J]. Physical Review B, 2005, 72(5): 052101.

COOPER S J, NICHOLSON C E, LIU J, et al. A simple classical model for predicting onset crystallization temperatures on curved substrates and its implications for phase transitions in confined volumes[J]. Journal of Chemical Physics, 2008, 129(12): 124715.

HEYDARI G, THORMANN E, JARN M, et al. Hydrophobic surfaces: topography effects on wetting by supercooled water and freezing delay[J]. Journal of Physical Chemistry C, 2013, 117(42): 21752-21762.

YAMADA Y, ONISHI G, HORIBE A, et al. Sessile droplet freezing on hydrophobic structured surfaces under cold ambient conditions[J]. Langmuir, 2019, 35(50): 16401-16406.

HUANG L Y, LIU Z L, LIU Y M, et al. Effect of contact angle on water droplet freezing process on a cold flat surface[J]. Experimental Thermal and Fluid Science, 2012, 40: 74-80.

ZHANG Y, ANIMDANSO E, BEKELE S, et al. Effect of surface energy on freezing temperature of water[J]. ACS Applied Materials Interfaces, 2016, 8(27): 17583-17590.

SHEN Y Z, WANG G Y, TAO J, et al. Anti-icing performance of superhydrophobic texture surfaces depending on reference environments[J]. Advanced Materials Interfaces, 2017, 4(22): 1700836.

DOTAN A, DODIUK H, LAFORTE C, et al. The relationship between water wetting and ice adhesion[J]. Journal of Adhesion Science and Technology, 2009, 23(15): 1907-1915.

PETRENKO V F, PENG S. Reduction of ice adhesion to metal by using self-assembling monolayers (SAMs)[J]. Canadian Journal of Physics, 2003, 81(1-2): 387-393.

PETRENKO V F, WHITWORTH R W. Physics of ice[M]. Oxford University Press, 2002.

BHARATHIDASAN T, KUMAR S V, BOBJI M S, et al. Effect of wettability and surface roughness on ice-adhesion strength of hydrophilic, hydrophobic and superhydrophobic surfaces[J]. Applied Surface Science, 2014, 314: 241-250.

KULINICH S A, FARZANEH M. How wetting hysteresis influences ice adhesion strength on superhydrophobic surfaces[J]. Langmuir, 2009, 25(16): 8854-8856.

MURASE H, NANISHI K, KOGURE H, et al. Interactions between heterogeneous surfaces of polymers and water[J]. Journal of Applied Polymer Science, 1994, 54(13): 2051-2062.

CHEN J, LIU J, HE M, et al. Superhydrophobic surfaces cannot reduce ice adhesion[J]. Applied Physics Letters, 2012, 101(11): 111603.

YEONG Y H, MILIONIS A, LOTH E, et al. Atmospheric ice adhesion on water-repellent coatings: wetting and surface topology effects[J]. Langmuir, 2015, 31(48): 13107-13116.

MEULER A J, MCKINLEY G H, COHEN R E, et al. Exploiting topographical texture to impart icephobicity[J]. ACS Nano, 2010, 4(12): 7048-7052.

MENINI R, GHALMI Z, FARZANEH M, et al. Highly resistant icephobic coatings on aluminum alloys[J]. Cold Regions Science and Technology, 2011, 65(1): 65-69.

MEULER A J, SMITH J D, VARANASI K K, et al. Relationships between water wettability and ice adhesion[J]. ACS Applied Materials Interfaces, 2010, 2(11): 3100-3110.

YANG S Q, XIA Q, ZHU L, et al. Research on the icephobic properties of fluoropolymer-based materials[J]. Applied Surface Science, 2011, 257(11): 4956-4962.

HASSAN M F, LEE H P, LIM S P, et al. The variation of ice adhesion strength with substrate surface roughness[J]. Measurement Science and Technology, 2010, 21(7): 075701.

MEMON H, LIU J P, DE FOCATIIS D S A, et al. Intrinsic dependence of ice adhesion strength on surface roughness[J]. Surface and Coatings Technology, 2020, 385: 125382.

ZOU M, BECKFORD S, WEI R, et al. Effects of surface roughness and energy on ice adhesion strength[J]. Applied Surface Science, 2011, 257(8): 3786-3792.

CHU F Q, WU X M, WANG L L, et al. Dynamic melting of freezing droplets on ultraslippery superhydrophobic surfaces[J]. ACS Applied Materials Interfaces, 2017, 9(9): 8420-8425.

BOREYKO J B, SRIJANTO B R, NGUYEN T D, et al. Dynamic defrosting on nanostructured superhydrophobic surfaces[J]. Langmuir, 2013, 29(30): 9516-9524.

YANG Q, ZHU Z W, TAN S, et al. How micro-/nanostructure evolution influences dynamic wetting and natural deicing abilities of bionic lotus surfaces[J]. Langmuir, 2020, 36(15): 4005-4014.

WANG H, HE G G, TIAN Q Q. Effects of nano-fluorocarbon coating on icing[J]. Applied Surface Science, 2012, 258(18): 7219-7224.

CAO L L, JONES A K, SIKKA V K, et al. Anti-icing superhydrophobic coatings[J]. Langmuir, 2009, 25(21): 12444-12448.

ZUO Z P, LIAO R J, GUO C, et al. Fabrication and anti-icing property of coral-like superhydrophobic aluminum surface[J]. Applied Surface Science, 2015, 331: 132-139.

SHEN Y Z, TAO H J, CHEN S L, et al. Icephobic/anti-icing potential of superhydrophobic Ti6Al4V surfaces with hierarchical textures[J]. Rsc Advances, 2015, 5(3): 1666-1672.

NGUYEN T B, PARK S, LIM H. Effects of morphology parameters on anti-icing performance in superhydrophobic surfaces[J]. Applied Surface Science, 2018, 435: 585-591.

WEN M X, WANG L, ZHANG M Q, et al. Antifogging and icing-delay properties of composite micro-and nanostructured surfaces[J]. ACS applied materials interfaces, 2014, 6(6): 3963-3968.

SARSHAR M A, SWARCTZ C, HUNTER S, et al. Effects of contact angle hysteresis on ice adhesion and growth on superhydrophobic surfaces under dynamic flow conditions[J]. Colloid and Polymer Science, 2013, 291(2): 427-435.

ARIANPOUR F, FARZANEH M, KULINICH S A. Hydrophobic and ice-retarding properties of doped silicone rubber coatings[J]. Applied Surface Science, 2013, 265: 546-552.

YANG J, LI W. Preparation of superhydrophobic surfaces on Al substrates and the anti-icing behavior[J]. Journal of Alloys and Compounds, 2013, 576: 215-219.

JUNG S, TIWARI M K, DOAN N V, et al. Mechanism of supercooled droplet freezing on surfaces[J]. Nature Communications, 2012, 3(1): 1-8.

YANG Q, LUO Z Z, JIANG F M, et al. Air cushion convection inhibiting icing of self-cleaning surfaces[J]. ACS Applied Materials Interfaces, 2016, 8(42): 29169-29178.

TANG Y Q, ZHANG Q H, ZHAN X L, et al. Superhydrophobic and anti-icing properties at overcooled temperature of a fluorinated hybrid surface prepared via a sol–gel process[J]. Soft Matter, 2015, 11(22): 4540-4550.

RAHIMI M, AFSHARI A, THORMANN E. Effect of aluminum substrate surface modification on wettability and freezing delay of water droplet at subzero temperatures[J]. ACS Applied Materials Interfaces, 2016, 8(17): 11147-11153.

KULINICH S A, FARZANEH M. Ice adhesion on super-hydrophobic surfaces[J]. Applied Surface Science, 2009, 255(18): 8153-8157.

DAVIS A, YEONG Y H, STEELE A, et al. Superhydrophobic nanocomposite surface topography and ice adhesion[J]. ACS Applied Materials Interfaces, 2014, 6(12): 9272-9279.

DENG T, VARANASI K K, HSU M, et al. Nonwetting of impinging droplets on textured surfaces[J]. Applied Physics Letters, 2009, 94(13): 133109.

EXTRAND C W. Designing for optimum liquid repellency[J]. Langmuir, 2006, 22(4): 1711-1714.

FORTIN G, PERRON J. Ice adhesion models to predict shear stress at shedding[J]. Journal of Adhesion Science and Technology, 2012, 26(4-5): 523-553.

BOINOVICH L B, EMELYANENKO A M. Anti-icing potential of superhydrophobic coatings[J]. Mendeleev Communications, 2013, 1(23): 3-10.

SARKAR D K, FARZANEH M. Superhydrophobic coatings with reduced ice adhesion[J]. Journal of Adhesion Science and Technology, 2009, 23(9): 1215-1237.

KULINICH S A, FARHADI S, NOSE K, et al. Superhydrophobic surfaces: are they really ice-repellent?[J]. Langmuir, 2011, 27(1): 25-29.

KARMOUCH R, ROSS G G. Experimental study on the evolution of contact angles with temperature near the freezing point[J]. The Journal of Physical Chemistry C, 2010, 114(9): 4063-4066.

HE M, LI H L, WANG J J, et al. Superhydrophobic surface at low surface temperature[J]. Applied Physics Letters, 2011, 98(9): 093118.

WANG Y Y, XUE J, WANG Q J, et al. Verification of icephobic/anti-icing properties of a superhydrophobic surface[J]. ACS Applied Materials Interfaces, 2013, 5(8): 3370-3381.

VARANASI K K, DENG T, SMITH J D, et al. Frost formation and ice adhesion on superhydrophobic surfaces[J]. Applied Physics Letters, 2010, 97(23): 234102.

MOMEN G, JAFARI R, FARZANEH M. Ice repellency behaviour of superhydrophobic surfaces: Effects of atmospheric icing conditions and surface roughness[J]. Applied Surface Science, 2015, 349: 211-218.

SINGH J K, MÜLLER-PLATHE F. On the characterization of crystallization and ice adhesion on smooth and rough surfaces using molecular dynamics[J]. Applied Physics Letters, 2014, 104(2): 021603.

BOINOVICH L B, EMELYANENKO A M, IVANOV V K, et al. Durable icephobic coating for stainless steel[J]. ACS Applied Materials Interfaces, 2013, 5(7): 2549-2554.

STEELE A, BAYER I, LOTH E. Adhesion strength and superhydrophobicity of polyurethane/organoclay nanocomposite coatings[J]. Journal of Applied Polymer Science, 2012, 125(S1): E445-E452.

FARHADI S, FARZANEH M, KULINICH S A. Anti-icing performance of superhydrophobic surfaces[J]. Applied Surface Science, 2011, 257(14): 6264-6269.

ZHENG S L, LI C, FU Q T, et al. Development of stable superhydrophobic coatings on aluminum surface for corrosion-resistant, self-cleaning, and anti-icing applications[J]. Materials Design, 2016, 93: 261-270.

SHEN Y Z, WU Y, TAO J, et al. Spraying fabrication of durable and transparent coatings for anti-icing application: dynamic water repellency, icing delay, and ice adhesion[J]. ACS Applied Materials Interfaces, 2018, 11(3): 3590-3598.

LONG J Y, Wu YING C, GONG D W, et al. Preparation and icing resistance of superhydrophobic copper by femtosecond laser[J]. Chinese Journal of Lasers, 2015, 42(07): 164-171. (in Chinese)

ZHENG H K, CHANG S N, ZHAO Y Y. Anti-ice Dephobic Mechanism and Application of Superhydrophobic/Superlubricated Surface[J]. Progress in Chemistry, 2017, 29(01): 102-118. (in Chinese)

LENG M Y, CHANG S N, DING L. Numerical simulation of impingement freezing of water droplets on cold surfaces with different wetting properties[J]. CIESC Journal, 2016, 67(07): 2784-2792. (in Chinese)

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