水热炭微球的制备及稳定水基钻井液高温性能作用机理

钟汉毅; 陈长志; 李树森; 李大奇; 高泽明; 邱正松; 黄维安; 牟庭波

doi:10.7623/syxb202512011

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水热炭微球的制备及稳定水基钻井液高温性能作用机理

石油工程 | 更新时间：2026-02-02

- 水热炭微球的制备及稳定水基钻井液高温性能作用机理
- Preparation of hydrothermal carbon microspheres and their mechanism in enhancing the high-temperature stability of water-based drilling fluids
- 石油学报 2025年46卷第12期页码：2358-2373
- 作者机构：
  
  1. 深层油气全国重点实验室(中国石油大学(华东)),山东,青岛,266580
  2. 中国石油大学(华东)石油工程学院,山东,青岛,266580
  3. 中石化石油工程技术研究院有限公司,北京,102206
- 作者简介：
- 基金信息：
  
  国家自然科学基金面上项目(No.52174013);中央高校基本科研业务费专项资金项目(24CX02004A);山东省自然科学基金项目(ZR2024ME105)和中国石化超深井钻井工程技术重点实验室开放基金项目(36650000-23-ZC0607-0063)资助。
- DOI：10.7623/syxb202512011
  中图分类号： TE254
- 网络出版：2026-01-09，
  
  纸质出版：2025
- 稿件说明：
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钟汉毅, 陈长志, 李树森, 李大奇, 高泽明, 邱正松, 黄维安, 牟庭波. 水热炭微球的制备及稳定水基钻井液高温性能作用机理[J]. 石油学报, 2025, 46(12): 2358-2373.

钟汉毅, 陈长志, 李树森, et al. Preparation of hydrothermal carbon microspheres and their mechanism in enhancing the high-temperature stability of water-based drilling fluids[J]. ACTA PETROLEI SINICA, 2025, 46(12): 2358-2373.
钟汉毅, 陈长志, 李树森, 李大奇, 高泽明, 邱正松, 黄维安, 牟庭波. 水热炭微球的制备及稳定水基钻井液高温性能作用机理[J]. 石油学报, 2025, 46(12): 2358-2373. DOI： 10.7623/syxb202512011.

钟汉毅, 陈长志, 李树森, et al. Preparation of hydrothermal carbon microspheres and their mechanism in enhancing the high-temperature stability of water-based drilling fluids[J]. ACTA PETROLEI SINICA, 2025, 46(12): 2358-2373. DOI： 10.7623/syxb202512011.

摘要

深层致密油气储层钻井过程中

聚合物类处理剂容易高温降解而导致无黏土相水基钻井液流变和滤失等性能恶化。针对传统高温稳定剂的不足

以β-环糊精为原料

通过"绿色"水热炭化反应制备出炭微球Cy-CMS

对其结构进行综合表征

分别考察不同温度作用前后Cy-CMS对不同聚合物溶液、AM-AMPS-NVP(Cop-1)共聚物实验基浆和无黏土相水基钻井液流变性和滤失性的影响

并探讨其作用机理。研究表明

Cy-CMS表面含有丰富的亲水性含氧官能团

内部为疏水性聚呋喃环

为典型的核壳结构。传统的生物聚合物和抗高温合成聚合物分别在120~140 ℃和180~200 ℃作用后降解失效

加入0.5%Cy-CMS热滚后表观黏度保持率均大于80%。Cop-1实验基浆中加入Cy-CMS

240 ℃热滚后其表观黏度保持率最高达95 %

220 ℃长期静置老化条件下其性能恶化得到明显延缓。以生物聚合物构建的无黏土相水基钻井液中加入0.5%Cy-CMS

160 ℃热滚前后流变性和滤失性保持稳定。Cy-CMS可吸收钻井液中溶解氧并将其降至10

-2

mg/L数量级

同时有效清除高温下产生的自由基

避免聚合物热氧化降解。此外

Cy-CMS还可与聚合物形成桥连结构

进一步提高聚合物的热稳定性。Cy-CMS能显著提高水基钻井液高温甚至超高温作用下的热稳定性

明显优于传统高温稳定剂Na

为深层致密油气无黏土相水基钻井液高温流变和滤失性能调控提供了全新途径。

Abstract

During the drilling of deep tight oil and gas reservoirs

polymer-based additives are susceptible to high-temperature degradation

resulting in the deterioration of properties such as rheology and filtration loss in bentonite-free water-based drilling fluids. To address the limitations of traditional high-tem

perature stabilizers

carbon microspheres (Cy-CMSs)were synthesized via a green hydrothermal carbonization process using β-cyclodextrin as a precursor. The structure of Cy-CMSs was comprehensively characterized

and their effects on the rheological and filtration loss properties of various polymer solutions

experimental base slurries of the AM-AMPS-NVP (Cop-1)copolymer

and bentonite-free water-based drilling fluids were evaluated before and after thermal treatment at different temperatures. The underlying mechanisms of Cy-CMSs were also investigated. The study demonstrated that Cy-CMSs possess abundant hydrophilic oxygen-containing functional groups on the surface and hydrophobic polyfuran rings in the core

exhibiting a typical core-shell structure. Traditional biopolymers and high-temperature-resistant synthetic polymers degrade and lose their functionality after exposure to high temperatures of 120-140 ℃ and 180-200 ℃

respectively. However

the addition of 0.5%Cy-CMSs results in an apparent viscosity retention rate exceeding 80%after hot rolling. When Cy-CMSs were incorporated into the Cop-1 experimental base slurry

the apparent viscosity retention rate reached up to 95%after hot rolling at 240 ℃. Furthermore

under long-term static aging conditions at 220 ℃

the degradation of performance was significantly delayed. After adding 0.5%Cy-CMSs to the bentonite-free water-based drilling fluid formulated with biopolymers

both the rheological and filtration properties remained stable after hot rolling at 160 ℃. Cy-CMSs effectively absorb dissolved oxygen in the drilling fluid

reducing its concentration to the order of 10

-2

mg/L

while also scavenging free radicals generated under high temperatures

thus preventing the thermal oxidative degradation of polymers. In addition

Cy-CMSs can form bridged structures with polymers

further enhancing their thermal stability. Cy-CMSs significantly improve the high-temperature and even ultra-high-temperature thermal stability of water-based drilling fluids

outp

erforming the traditional high-temperature stabilizer Na

. This provides a novel approach for regulating the high-temperature rheological and filtration properties of bentonite-free water-based drilling fluids used in deep and tight oil and gas reservoirs.

关键词

Keywords

references

孙金声,许成元,康毅力,等. 致密/页岩油气储层损害机理与保护技术研究进展及发展建议[J].石油钻探技术,2020,48(4):1-10.

赖锦,肖露,赵鑫,等.深层—超深层优质碎屑岩储层成因与测井评价方法——以库车坳陷白垩系巴什基奇克组为例[J].石油学报,2023,44(4):612-625.

游利军,陈杨,康毅力,等.低渗气藏入井液损害实验评价的产能指数法[J].钻井液与完井液,2020,37(5):620-625.

孙金声,杨景斌,吕开河,等.致密油气钻井液技术研究现状与展望[J].石油学报,2025,46(1):279-288.

EZELL R G,EZZAT A M,TURNER J K,et al.New filtration-control polymer for improved brine-based reservoir drilling-fluids performance at temperatures in excess of 400°F and high pressure[R].SPE 128119,2010.

刘岩生,张佳伟,黄洪春.中国深层—超深层钻完井关键技术及发展方向[J].石油学报,2024,45(1):312-324.

THAEMLITZ C J,PATEL A D,COFFIN G,et al.New environmentally safe high-temperature water-based drilling-fluid system[J].SPE Drilling & Completion,1999,14(3):185-189.

谢彬强,陶怀志,张俊,等.梳型温敏聚合物对无固相水基钻井液高温流变性的调控[J].石油学报,2024,45(2):427-436.

LUO Zhihua,WANG Longxiang,PEI Jingjing,et al.A novel star-shaped copolymer as a rheology modifier in water-based drilling fluids[J].Journal of Petroleum Science and Engineering,2018,168:98-106.

王中华.高性能钻井液处理剂设计思路[J].中外能源,2013,18(1): 36-46.

李凤霞,蒋官澄,王郑库,等.TLJ-1植物胶钻井液抗温能力的提高[J].钻井液与完井液,2010,27(5):31-33.

AKPAN E U,ENYI G C,NASR G G,et al.Stabilizing biopolymers in water-based drilling fluids at high temperature using antioxidants,a formate salt,and polyglycol[J].Journal of Engineering Technology,2018,7(2):469-486.

曹剑锋.几种抗氧化剂体外抗氧化活性的比较研究[D].兰州:西北师范大学,2008.

ASH S G,CLARKE-STURMAN A J,CALVERT R,et al.Chemical stability of biopolymer solutions[R].SPE 12085,1983.

VAN OORT E,BLAND R G,HOWARD S K,et al.Improving HPHT stability of water based drilling fluids[R].SPE 37605,1997.

GLASS J E,SOULES D A,AHMED H,et al.Viscosity stability of aqueous polysaccharide solutions[R].SPE 11691,1983.

ALMUBARAK T,ALMUBARAK M,ALMOAJIL A,et al.Vitamin C:an environmentally friendly multifunctional additive for hydraulic fracturing fluids[R].SPE 211113,2022.

MAHMOUD O,NASR-EL-DIN H A,VRYZAS Z,et al.Nanoparticle-based drilling fluids for minimizing Formation damage in HP/HT applications[R].SPE 178949,2016.

AL-SABA M T,AL FADHLI A,MARAFI A,et al.Application of nanoparticles in improving rheological properties of water based drilling fluids[R].SPE 192239,2018.

BARRY M M,JUNG Y,LEE J K,et al.Fluid filtration and rheological properties of nanoparticle additive and intercalated clay hybrid bentonite drilling fluids[J].Journal of Petroleum Science and Engineering,2015,127:338-346.

任妍君,翟玉芬,路岩岩.抗高温高密度可逆油基钻井液体系[J].石油学报,2023,44(5):841-851.

NICOLAE S A,AU H,MODUGNO P,et al.Recent advances in hydrothermal carbonisation:from tailored carbon materials and biochemicals to applications and bioenergy[J].Green Chemistry,2020,22(15):4747-4800.

刘裴.对称/不对称水热碳微球的可控制备与应用研究[D].武汉:武汉理工大学,2021.

顾艳耿,胡仲秋,邱月,等.亚临界水法提取茶多糖及抗氧化活性研究[J].食品科技,2019,44(6):194-201.

刘立明,刘丽虹,宋功武,等.分光光度法测定Fenton反应产生的羟自由基[J].湖北大学学报(自然科学版),2002,24(4):326-328.

WANG Xueyan,WANG Bingyan,LIU Wenxia,et al.Fabrication of highly stretchable composite organohydrogel for strain sensors with high sensitivity and broad temperature tolerance[J].Applied Materials Today,2024,39:102319.

YAO Mingzhu,LIU Baojie,CONG Zhente,et al.Stabilized Janus micro/nano-paper with lignin nanoparticle bridges for efficient oil-water emulsion separation[J].Journal of Cleaner Production,2025,505:145500.

王丽丽.生物质基胶体碳的制备及应用研究[D].长春:吉林大学,2012.

IQBAL M,ERCAN B,KARAGÖZ S.Hydrothermal carbon spheres produced from glucose,cyclodextrin,and starch[J].Fullerenes,Nanotubes and Carbon Nanostructures,2024,32(1):1-7.

张长存.生物质碳材料的制备及其性能研究[D].济南:山东建筑大学,2016.

HIGGINS L J R,BROWN A P,HARRINGTON J P,et al.Evidence for a core-shell structure of hydrothermal carbon[J].Carbon,2020,161:423-431.

HOWARD S K.Formate brines for drilling and completion:state of the art[R].SPE 30498,1995.

冯玉军,罗传秋,罗平亚,等.疏水缔合水溶性聚丙烯酰胺的溶液结构的研究[J].石油学报(石油加工),2001,17(6):39-44.

BEESE A M,SARKAR S,NAIR A,et al.Bio-inspired carbon nanotube-polymer composite yarns with hydrogen bond-mediated lateral interactions[J].ACS Nano,2013,7(4):3434-3446.

BACCILE N,LAURENT G,BABONNEAU F,et al.Structural characterization of hydrothermal carbon spheres by advanced solid-state MAS 13C NMR investigations[J].The Journal of Physical Chemistry C,2009,113(22):9644-9654.

SEVILLA M,FUERTES A B.Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides[J].Chemistry-A European Journal,2009,15(16):4195-4203.

胡子乔,刘四海,刘金华,等.水溶性聚合物热稳定性研究进展[J].化学通报,2016,79(8):714-718.

李国楠.聚丙烯酰胺凝胶高温稳定性研究[D].北京:中国地质大学(北京),2017.

林梅钦,王兆军,李明远,等.交联聚合物溶液的热稳定性[J].石油学报(石油加工),2008,24(1):112-116.

SHIN S,CHO Y I.The effect of thermal degradation on the non-Newtonian viscosity of an aqueous polyacrylamide solution[J].KSME International Journal,1998,12(2):267-273.

汪君.葡萄糖水热炭化及其活化特性研究[D].武汉:华中科技大学,2013.

陈雅丽.生物质水热碳材料的制备修饰及环境应用研究[D].合肥:中国科学技术大学,2015.

QIU Yang,WANG Zhongying,OWENS A C E,et al.Antioxidant chemistry of graphene-based materials and its role in oxidation protection technology[J].Nanoscale,2014,6(20):11744-11755.

聂挺.量子化学计算研究多酚及多肽清除自由基的构效关系[D].南昌:南昌大学,2016.

WANG Dangfeng,YAN Zihao,REN Likun,et al.Carbon dots as new antioxidants:synthesis,activity,mechanism and application in the food industry[J].Food Chemistry,2025,475:143377.

ZHONG Hanyi,KONG Xiangzheng,QIU Zhengsong,et al.Effect of nano carbon spheres on the properties of oil-based drilling fluids under high temperature conditions[R].IPTC-21404,2021.

杨芳.纳米碳球耐高温钻井液润滑剂的研究[D].长春:吉林大学,2013.

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