二氧化碳高值化化学利用技术的研究进展

曹新悦; 高展颜; 杨应举; 苏毅; 黄俊; 吴大卫; 沈腾; 陈苗; 刘晶

doi:10.19944/j.eptep.1674-8069.2026.04.002

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

二氧化碳高值化化学利用技术的研究进展

特邀专稿 | 更新时间：2026-10-14

- 二氧化碳高值化化学利用技术的研究进展
- Research progress on high-value chemical utilization technology of carbon dioxide
- 电力科技与环保 2026年42卷第4期页码：529-543
- 作者机构：
  
  1.煤燃烧与低碳利用全国重点实验室（华中科技大学能源与动力工程学院），湖北武汉 430074
  2.深圳华中科技大学研究院，广东深圳 518000
  3.中国能源建设集团广东省电力设计研究院有限公司，广东广州 510663
  4.中国船舶集团有限公司第七一一研究所，上海 200000
- 作者简介：
  
  曹新悦（2004—），女，本科生，主要从事二氧化碳高值化利用的储能技术等方面的研究，2717076019@qq.com；
  高展颜（2006—），女，本科生，主要从事二氧化碳高值化利用技术等方面的研究，3088923293@qq.com；
  杨应举（1990—），男，副教授，主要从事CO2高值化利用、氢能、催化燃烧、燃烧污染物控制等方面的研究，yangyingju@hust.edu.cn；
  苏毅（1990—），男，博士研究生，主要从事碳捕集与利用等方面的研究，suyi@smderi.com.cn；
  黄俊（2001—），男，硕士研究生，主要从事二氧化碳催化加氢合成高附加值燃料等方面的研究，m202371242@hust.edu.cn；
  吴大卫（1992—），男，博士研究生，主要从事碳捕集与利用等方面的研究，wudawei@gedi.com.cn；
  沈腾（1990—），男，硕士研究生，主要从事碳捕集与利用等方面的研究，dxrsklcc@163.com；
  陈苗（1983—），女，硕士研究生，主要从事二氧化碳催化加氢等方面的研究，miaochen1001@163.com；
- 基金信息：
  
  湖北省中央引导地方科技发展项目(2024CSA088);广东省基础与应用基础研究基金项目(2025A1515011772);深圳市科技计划项目(JCYJ20230807143703008);#：共同第一作者
- DOI：10.19944/j.eptep.1674-8069.2026.04.002
  中图分类号： TK06
- 收稿：2026-01-25，
  
  录用：2026-06-20，
  
  纸质出版：2026-08-15
- 稿件说明：
移动端阅览
曹新悦,高展颜,杨应举，等.二氧化碳高值化化学利用技术的研究进展[J].电力科技与环保,2026,42(4):529-543.

CAO Xinyue, GAO Zhanyan, YANG Yingju, et al. Research progress on high-value chemical utilization technology of carbon dioxide[J]. Electric Power Technology and Environmental Protection, 2026, 42(4):529-543.
曹新悦,高展颜,杨应举，等.二氧化碳高值化化学利用技术的研究进展[J].电力科技与环保,2026,42(4):529-543. DOI： 10.19944/j.eptep.1674-8069.2026.04.002.

CAO Xinyue, GAO Zhanyan, YANG Yingju, et al. Research progress on high-value chemical utilization technology of carbon dioxide[J]. Electric Power Technology and Environmental Protection, 2026, 42(4):529-543. DOI： 10.19944/j.eptep.1674-8069.2026.04.002.

摘要

目的

在碳中和目标背景下，CO

排放总量及新能源装机容量

持续增长，储能需求也随之激增，利用可再生能源驱动CO

转化为高附加值燃料或化学品，并将其以化学能形式储存，是一种极具前景的大规模长时储能技术。

方法

本文综述了基于CO

高值化利用的储能技术研究进展，包括CO

催化加氢合成碳基燃料储能、电化学还原CO

储能及微藻固定CO

储能，系统分析了各类CO

高值化利用储能技术的路线及特征，结合催化剂开发、系统集成等关键挑战，分析了不同场景下各类技术的适配性。

结果

高值化利用在技术层面要求产物能量密度高、储能效率优异且兼容现有工业基础设施；经济层面要求原料成本低廉、产物附加值高且具备规模化应用可行性；环境层面要求实现碳闭环循环、全生命周期碳排放低且兼具资源循环价值。甲醇、二甲醚和多碳醇等CO

高值化利用液体产物具有更高的能量密度，可更高效地将可再生能源以液体燃料的化学能形式储存，且更易在现有基础设施中实现运输与利用；电催化CO

还原生成的甲酸或甲酸盐储能技术，具有反应条件温和（常温常压）、能耗低且响应迅速的特点，适配中小型储能场景；微藻固定CO

储能技术通过光合作用实现碳固定与能源生产同步，可利用工业废水及烟道气为原料，兼具环境友好性与资源循环性；上述三种技术路线各有侧重、相互补充，可根据储能规模、场景需求等进行差异化选择，全面覆盖多元化储能需求。

结论

总体而言，CO

高值化利用的储能技术为双碳目标下可再生能源的多元化利用、节能减排及新型储能体系的构建，提供了基于整体视角的关键技术支撑。

Abstract

Objective

In the context of the carbon neutrality target

the continuous growth of total CO

emissions and installed capacity of new energy has led to a surge in energy storage demand. It is a highly promising large-scale long-term energy storage technology to utilize renewable energy to drive the conversion of CO

into high-value-added fuels or chemicals and store them in the form of chemical energy.

Methods

This paper reviews the research progress of energy storage technologies based on high-value utilization of CO

including energy storage via catalytic hydrogenation of CO

to synthesize carbon-based fuels

electrochemical energy storage

and energy storage via microalgal CO

fixation. It systematically analyzes the characteristics of various technical routes for energy storage based on high-value CO

utilization

addresses key challenges such as catalyst development and system integration

and evaluates the adaptability of various technologies under different scenarios.

Results

The high-value utilization of CO

requires at the technical level that products have high energy density

excellent energy storage efficiency

and compatibility with existing industrial infrastructure. At the economic level

it demands low raw material costs

high product added value

and feasibility of large-scale application. At the environmental level

it necessitates achieving a closed carbon cycle

low life-cycle carbon emissions

and resource recycling value. Liquid products from the high-value utilization of CO

such as methanol

dimethyl ether and polyhydric alcohols

have a higher energy density

enabling more efficient storage as chemical energy in liquid fuels

easier transportation and simpler utilization in existing infrastructure. The energy storage technology via electrocatalytic CO

reduction to formic acid or formate is characterized by mild reaction conditions (ambient temperature and pressure)

low energy consumption

and rapid response

making it suitable for small and medium-sized energy storage scenarios. The energy storage technology via microalgal CO

fixation achieves the synchronization of carbon fixation and energy production through photosynthesis

and can use industrial wastewater and flue gas as raw materials

boasting both environmental friendliness and resource recyclability. The above three technical routes have their own focuses and complement each other

allowing differentiated selection based on energy storage scale

scenario requirements

etc.

to fully cover diversified energy storage needs.

Conclusion

In general

the energy storage technology based on high-value utilization of CO

provides key technical support from an overall perspective for the diversified utilization of renewable energy

energy conservation and emission reduction

and the construction of new energy storage systems under the carbon peaking and carbon neutrality goals.

关键词

Keywords

references

JACOBSON M Z . Review of solutions to global warming, air pollution, and energy security [J ] . Energy& Environmental Science , 2009 , 2 ( 2 ): 148 - 173 .

罗海中，吴大卫，范永春，等 . 碳中和背景下CCUS技术发展及广东离岸封存潜力评估 [J ] . 南方能源建设， 2023 ， 10 ( 6 ): 1 - 13 .

LUO Haizhong , WU Dawei , FAN Yongchun , et al . Development of CCUS technology in the context of carbon neutrality and assessment of the potential for offshore storage in Guangdong Province [J ] . Southern Energy Construction , 2023 , 10 ( 6 ): 1 - 13 .

KUMAR R , LEE D , AGBULUT U , et al . Different energy storage techniques: Recent advancements,applications, limitations, and efficient utilization of sustainable energy [J ] . Journal of Thermal Analysis and Calorimetry , 2024 , 149 ( 5 ): 1895 - 1933 .

DANISH M S S , UEDA S , FURUKAKOI M , et al . Techno-economic modeling of diverse renewable energy sources integration: Achieving net-zero CO 2 emissions [J ] . IEEJ Transactions on Electrical and Electronic Engineering , 2024 , 19 ( 7 ): 1168 - 1182 .

BORETTI A . Carbon dioxide hydrogenation for sustainable energy storage [J ] . International Journal of Hydrogen Energy , 2024 , 58 : 1386 - 1395 .

GRAVES C , EBBESEN S D , MOGENSEN M , et al . Sustainable hydrocarbon fuels by recycling CO 2 and H 2 O with renewable or nuclear energy [J ] . Renewable and Sustainable Energy Reviews , 2011 , 15 ( 1 ): 1 - 23 .

骆攀，谈文杰，胡恩祥，等 . 二氧化碳催化加氢合成燃料的微通道反应器 [J ] . 南方能源建设， 2024 , 11 ( 4 ): 16 - 22 .

LUO Pan , TAN Wwenjie , HU Enxiang , et al . Microchannel reactor for hydrocarbon fuel synthesis from CO 2 catalytic hydrogenation [J ] . Southern Energy Construction , 2024 , 11 ( 4 ): 16 - 22 .

MA Y Q , XU R , WU X , et al . Progress in catalysts for formic acid production by electrochemical reduction of carbon dioxide [J ] . Topics in Current Chemistry , 2024 , 383 ( 1 ): 2 .

UDAYPAL , GOSWAMI R K , MEHARIYA S , et al . Advances in microalgae-based carbon sequestration:Current status and future perspectives [J ] . Environmental Research , 2024 , 249 : 118397 .

谢停，刘晶，杨应举 . 铁基钙钛矿光热催化CO 2 还原性能研究 [J ] . 工程热物理学报 , 2025 , 46 ( 11 ): 3814 - 3819 .

XIE Ting , LIU Jing , YANG Yingju . Photothermal catalytic CO 2 reduction performance of iron-based perovskite catalysts [J ] . Journal of Engineering Thermophysics , 2025 , 46 ( 11 ): 3814 - 3819 .

XU Y K , WANG L , ZHOU Q , et al . Carbon dioxide enabled hydrogen storage by methanol: Highly selective and efficient catalysis with well-defined heterogeneous catalysts [J ] . Coordination Chemistry Reviews , 2024 , 508 : 215775 .

ESTEVEZ R , AGUADO-DEBLAS L , BAUTISTA F M , et al . A review on green hydrogen valorization by heterogeneous catalytic hydrogenation of captured CO 2 into value-added products [J ] . Catalysts , 2022 , 12 ( 12 ): 1555 .

翟云楚，金丽艳，谢佳家，等 . 二氧化碳加氢合成甲醇工艺系统分析 [J ] . 南方能源建设 , 2024 , 11 ( 5 ): 50 - 56 .

ZHAI Yunchu , JIN Liyan , XIE Jiajia , et al . System analysis of methanol synthesis by carbon dioxide hydrogenation [J ] . Southern Energy Construction , 2024 , 11 ( 5 ): 50 - 56 .

ALIZADEH S M , KHALILI Y , AHMADI M . Comprehensive review of carbon capture and storage integration in hydrogen production: Opportunities, challenges, and future perspectives [J ] . Energies , 2024 , 17 ( 21 ): 5330 .

TI W , NG D K S , ANDIAPPAN V . Optimal integration of hydrogen production process with carbon dioxide capture,utilisation and storage [J ] . Journal of Cleaner Production , 2023 , 415 : 137697 .

张锦川，杨应举，刘晶，等 . Ni/SSZ-13催化剂的CO 2 甲烷化反应性能研究 [J ] . 燃料化学学报， 2021 , 49 ( 7 ): 960 - 966 .

ZHANG Jinchuan , YANG Yingju , LIU Jing , et al . Catalytic activity of Ni/SSZ-13 catalyst for CO 2 methanation [J ] . Journal of Fuel Chemistry and Technology , 2021 , 49 ( 7 ): 960 - 966 .

林海周，罗志斌，裴爱国，等 . 二氧化碳与氢合成甲醇技术和产业化进展 [J ] . 南方能源建设， 2020 , 7 ( 2 ): 14 - 19 .

LIN Haizhou , LUO Zhibin , PEI Aiguo , et al . Technology and industrialization progress on methanol synthesis from carbon dioxide and hydrogen [J ] . Southern Energy Construction , 2020 , 7 ( 2 ): 14 - 19 .

DANG S S , YANG H Y , GAO P , et al . A review of research progress on heterogeneous catalysts for methanol synthesis from carbon dioxide hydrogenation [J ] . Catalysis Today , 2019 , 330 : 61 - 75 .

王霂晗，周宇，沈凯，等 . ZnZrO <math id="M38"><msub><mrow/><mrow><mi>x</mi></mrow></msub></math> https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=120200057&type= https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=120200033&type= 0.93133330 3.21733332 催化二氧化碳加氢制甲醇的工艺性能研究 [J ] . 电力科技与环保 , 2025 , 41 ( 3 ): 405 - 412 .

WANG Muhan , ZHOU Yu , SHEN Kai , et al . Process performance study of ZnZrO <math id="M39"><msub><mrow/><mrow><mi>x</mi></mrow></msub></math> https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=120200069&type= https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=120200047&type= 0.93133330 3.21733332 solid solution catalysts in the hydrogenation of carbon dioxide to methanol [J ] . Electric Power Technology and Environmental Protection , 2025 , 41 ( 3 ): 405 - 412 .

肖江，王会民，王为锋，等 . 陕煤集团400万t/a CO 2 捕集与封存技术研究与探索 [J ] . 煤炭学报 , 2025 , 51 ( 2 ): 1703 - 1711 .

XIAO Jiang , WANG Huimin , WANG Wweifeng , et al . Research and Exploration on Shaanxi coal group's 4-million-ton/year CO 2 capture and storage technology [J ] . Journal of China Coal Society , 2025 , 51 ( 2 ): 1703 - 1711 .

YE J Y , LIU C J , MEI D H , et al . Active oxygen vacancy site for methanol synthesis from CO 2 hydrogenation on In 2 O 3 (110): A DFT study [J ] . ACS Catalysis , 2013 , 3 ( 6 ): 1296 - 1306 .

SHEN C Y , SUN K H , ZHANG Z T , et al . Highly active Ir/In 2 O 3 catalysts for selective hydrogenation of CO 2 to methanol: Experimental and theoretical studies [J ] . ACS Catalysis , 2021 , 11 ( 7 ): 4036 - 4046 .

HU J T , YU L , DENG J , et al . Sulfur vacancy-rich MoS 2 as a catalyst for the hydrogenation of CO 2 to methanol [J ] . Nature Catalysis , 2021 , 4 ( 3 ): 242 - 250 .

肖一杨，杨应举，刘晶 . CO 2 电催化还原的MS2型金属硫化物催化剂理性设计与高通量筛选 [J ] . 工程热物理学报 , 2024 , 45 ( 11 ): 3538 - 3543 .

XIAO Yiyang , YANG Yingju , LIU Jing . Rational design and high-throughput screening of transition-metal dichalcogenides catalysts for CO 2 electroreduction [J ] . Journal of Engineering Thermophysics , 2024 , 45 ( 11 ): 3538 - 3543 .

WANG J J , MEEPRASERT J , HAN Z , et al . Highly dispersed Cd cluster supported on TiO 2 as an efficient catalyst for CO 2 hydrogenation to methanol [J ] . Chinese Journal of Catalysis , 2022 , 43 ( 3 ): 761 - 770 .

WANG W , WANG S P , MA X B , et al . Recent advances in catalytic hydrogenation of carbon dioxide [J ] . Chemical Society Reviews , 2011 , 40 ( 7 ): 3703 - 3727 .

AIT EL FAKIR A , DU P F , YANG B , et al . A review on catalytic ethanol synthesis via hydrogenation of carbon dioxide [J ] . ChemSusChem , 2025 , 18 ( 14 ): e202500188 .

LIU M , YI Y H , WANG L , et al . Hydrogenation of carbon dioxide to value-added chemicals by heterogeneous catalysis and plasma catalysis [J ] . Catalysts , 2019 , 9 ( 3 ): 275 .

LEONZIO G . State of art and perspectives about the production of methanol, dimethyl ether and syngas by carbon dioxide hydrogenation [J ] . Journal of CO 2 Utilization , 2018 , 27 : 326 - 354 .

BABAPOOR A , SAMIMI F , MIRZAYI B , et al . Alternative strategies for effective utilization of carbon dioxide in dimethyl ether synthesis [J ] . Chemical Engineering& Technology , 2023 , 46 ( 5 ): 956 - 968 .

ATEKA A , RODRIGUEZ-VEGA P , ERENA J , et al . A review on the valorization of CO 2 . Focusing on the thermodynamics and catalyst design studies of the direct synthesis of dimethyl ether [J ] . Fuel Processing Technology , 2022 , 233 : 107310 .

LI X P , KE J C , LI R , et al . Research progress of hydrogenation of carbon dioxide to ethanol [J ] . Chemical Engineering Science , 2023 , 282 : 119226 .

ERDHELYI A . Hydrogenation of carbon dioxide on supported Rh catalysts [J ] . Catalysts , 2020 , 10 ( 2 ): 155 .

CAPARROS F J , SOLER L , ROSSELL M D , et al . Remarkable carbon dioxide hydrogenation to ethanol on a palladium/iron oxide single-atom catalyst [J ] . ChemCatChem , 2018 , 10 ( 11 ): 2365 - 2369 .

WANG L X , HE S X , WANG L , et al . Cobalt- nickel catalysts for selective hydrogenation of carbon dioxide into ethanol [J ] . ACS Catalysis , 2019 , 9 ( 12 ): 11335 - 11340 .

王清华，肖一杨，杨应举，等 . 二氧化碳电催化剂理论设计方法研究进展 [J ] . 新能源进展， 2023 , 11 ( 6 ): 524 - 533 .

WANG Qinghua , XIAO Yiyang , YANG Yingju , et al . Recent progress of theoretical design methods for CO 2 electrocatalytic reduction catalysts [J ] . Advances in New and Renewable Energy , 2023 , 11 ( 6 ): 524 - 533 .

YOO J S , CHRISTENSEN R , VEGGE T , et al . Theoretical insight into the trends that guide the electrochemical reduction of carbon dioxide to formic acid [J ] . ChemSusChem , 2016 , 9 ( 4 ): 358 - 363 .

BAHUGUNA A , SASSON Y . Formate-bicarbonate cycle as a vehicle for hydrogen and energy storage [J ] . ChemSusChem , 2021 , 14 ( 5 ): 1258 - 1283 .

NANKYA R , ELGAZZAR A , ZHU P , et al . Catalyst design and reactor engineering for electrochemical CO 2 reduction to formate and formic acid [J ] . Materials Today , 2024 , 76 : 94 - 109 .

JIN S , HAO Z M , ZHANG K , et al . Advances and challenges for the electrochemical reduction of CO 2 to CO: From fundamentals to industrialization [J ] . Angewandte Chemie , 2021 , 133 ( 38 ): 20795 - 20816 .

LI L , OZDEN A , GUO S Y , et al . Stable, active CO 2 reduction to formate via redox-modulated stabilization of active sites [J ] . Nature Communications , 2021 , 12 ( 1 ): 5223 .

ROSS M B , DE LUNA P , LI Y F , et al . Designing materials for electrochemical carbon dioxide recycling [J ] . Nature Catalysis , 2019 , 2 ( 8 ): 648 - 658 .

EWIS D , ARSALAN M , KHALED M , et al . Electrochemical reduction of CO 2 into formate/formic acid:A review of cell design and operation [J ] . Separation and Purification Technology , 2023 , 316 : 123811 .

ZHAO B T , SU Y X . Macro assessment of microalgae-based CO 2 sequestration: Environmental and energy effects [J ] . Algal Research , 2020 , 51 : 102066 .

UDAYAN A , PANDEY A K , SIROHI R , et al . Production of microalgae with high lipid content and their potential as sources of nutraceuticals [J ] . Phytochemistry Reviews , 2023 , 22 ( 4 ): 833 - 860 .

杨桂娟，栾忠奇，周笑辉 . 温度对小球藻生长量和溶氧量影响研究 [J ] . 农机化研究 , 2009 , 31 ( 9 ): 157 - 158,161 .

YANG Gguijuan , LUAN Zhongqi , ZHOU Xiaohui . Researching on the effect of temperature on chlorella growth and dissolved oxygen content [J ] . Journal of Agricultural Mechanization Research , 2009 , 31 ( 9 ): 157 - 158,161 .

张娟梅，江贤章，黄建忠 . 裂殖壶菌Schizochytrium sp .FJU-512细胞油脂的研究[J ] . 福建师范大学学报(自然科学版) , 2007 , 23 ( 2 ): 75 - 80 .

ZHANG Juanmei , JIANG Xianzhang , HUANG Jianzhong . Studies on cell oil produced by schizochytrium sp. FJU-512 [J ] . Journal of Fujian Normal University(Natural Science Edition) , 2007 , 23 ( 2 ): 75 - 80 .

高静思，朱佳，董文艺 . 光照对我国常见藻类的影响机制及其应用 [J ] . 环境工程 , 2019 , 37 ( 5 ): 111 - 116 .

GAO Jingsi , ZHU Jia , DONG Wenyi . Influence mechanism of light on common algae and its application [J ] . Environmental Engineering , 2019 , 37 ( 5 ): 111 - 116 .

马雪彬，李赟，朱葆华，等 . CO 2 对小球藻固碳速率及物质合成的影响 [J ] . 中国海洋大学学报(自然科学版) , 2019 , 49 ( S2 ): 29 - 36 .

MA Xuebin , LI Yun , ZHU Baohua , et al . Effect of CO 2 on carbon sequestration rate and material synthesis of chlorella sp [J ] . Periodical of Ocean University of China , 2019 , 49 ( S2 ): 29 - 36 .

NARALA R R , GARG S , SHARMA K K , et al . Comparison of microalgae cultivation in photobioreactor,open raceway pond, and a two-stage hybrid system [J ] . Frontiers in Energy Research , 2016 , 4 : 29 .

TRIPATHI S , CHOUDHARY S , MEENA A , et al . Carbon capture, storage, and usage with microalgae: A review [J ] . Environmental Chemistry Letters , 2023 , 21 ( 4 ): 2085 - 2128 .

王香增，杨红，刘芳娜，等 . 延长石油CO2捕集与封存技术及实践 [J ] . 煤炭科学技术， 2024 , 52 ( 9 ): 248 - 262 .

WANG Xiangzeng , YANG Hong , LIU Fangna , et al . Technology and practice of CO2 capture and storage from Yanchang Petroleum [J ] . Coal Science and Technology , 2024 , 52 ( 9 ): 248 - 262 .

黄海泉，黄晓巍，姜望，等 . 新型配电网分布式储能系统方案及配置研究综述 [J ] . 南方能源建设 , 2024 , 11 ( 4 ): 42 - 53 .

HUANG Haiquan , HUANG Xxiaowei , JIANG Wang , et al . A review of distributed energy storage system solutions and configurations for new distribution grids [J ] . Southern Energy Construction , 2024 , 11 ( 4 ): 42 - 53 .

赵威翰，徐进，田新，等 . 考虑价格型需求响应的风-光-储综合能源系统日前优化调度研究 [J ] . 电力科技与环保 , 2025 , 41 ( 6 ): 878 - 887 .

ZHAO Weihan , XU Jin , TIAN Xin , et al . Research on day-ahead optimization scheduling of integrated wind-power-storage energy systems considering price-based demand response [J ] . Electric Power Technology and Environmental Protection , 2025 , 41 ( 6 ): 878 - 887 .

WANG C Y , LAI H , WARKENTIN H , et al . Catalysts for electrochemical CO 2 conversion: Material sustainability perspective [J ] . npj Materials Sustainability , 2025 , 3 ( 1 ): 22 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

中国海上风电发展分析与建议

复杂约束下海上风电场相位错列规则排布方法

粉煤灰基胶凝材料固化硫酸盐渍土机理研究

江苏常州煤电集成创新“六个首次”

退役风机叶片与光伏组件的固废处置与应用研究