双碳背景下电还原二氧化碳制甲酸用Bi基催化剂的研究与展望

曹元波; 杨涛; 陈兵; 张虹; 杨丽明; 周冰; 郑彦会; 侯新梅

doi:10.19944/j.eptep.1674-8069.2025.03.002

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双碳背景下电还原二氧化碳制甲酸用Bi基催化剂的研究与展望

特邀专稿 | 更新时间：2026-10-14

- 双碳背景下电还原二氧化碳制甲酸用Bi基催化剂的研究与展望
- Research and prospect of Bi-based catalyst for electroreduction of CO₂ to formic acid under the background of double carbon
- 电力科技与环保 2025年41卷第3期页码：357-372
- 作者机构：
  
  1.北京科技大学碳中和研究院，北京 100083
  2.南开大学法学院，天津 300350
  3.北京氢太科技有限公司，北京 102401
- 作者简介：
  
  曹元波（2000—），男，硕士研究生，主要从事CO2还原催化剂开发与系统优化等方面的研究，s6252308@163.com；
  杨涛（1988—），男，研究员，主要从事水解产氢和CO2还原催化剂开发与系统优化、材料的可控制备与功能化应用等方面的研究，yangtaoustb@ustb.edu.cn
  陈兵（1980—），男，教授，主要从事法学等方面的研究，bing.chen@nankai.edu.cn；
  张虹（1993—），女，工程师，主要从事碳权及数据法律等方面的研究，18756447086@163.com；
  杨丽明（1997—），女，博士研究生，主要从事水解产氢和CO2还原催化剂开发与系统优化等方面的研究，yangliming0619@163.com
  周冰（1968—），男，教授，主要从事前沿绿色能源材料及相关设备的开发等方面的研究，18310932538@139.com；
  郑彦会（1986—），男，教授，主要从事科研项目分析需求定制化方案、实验室成套系统、新能源产品分析检测、新能源产品开发等方面的研究，657191165@qq.com；
  侯新梅（1979—），女，教授，主要从事短流程炼钢用新型耐火材料的可控制备、高温界面反应动力学新方法、制氢用新型电极材料的制备及应用等方面的研究，houxinmeiustb@ustb.edu.cn。
- 基金信息：
  
  国家自然科学基金项目(52474319);北京科技大学青年教师学科交叉研究项目（中央高校基本科研业务费专项资金资助项目）(FRF-IDRY-GD23-003)
- DOI：10.19944/j.eptep.1674-8069.2025.03.002
  中图分类号： TK02;TQ233
- 收稿：2025-04-02，
  
  录用：2025-05-23，
  
  纸质出版：2025-06-15
- 稿件说明：
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曹元波,杨涛,陈兵，等.双碳背景下电还原二氧化碳制甲酸用Bi基催化剂的研究与展望[J].电力科技与环保,2025,41(3):357-372.

CAO Yuanbo, YANG Tao, CHEN Bing, et al. Research and prospect of Bi-based catalyst for electroreduction of CO₂ to formic acid under the background of double carbon[J]. Electric Power Technology and Environmental Protection, 2025, 41(3):357-372. DOI: 10.19944/j.eptep.1674-8069.2025.03.002.
曹元波,杨涛,陈兵，等.双碳背景下电还原二氧化碳制甲酸用Bi基催化剂的研究与展望[J].电力科技与环保,2025,41(3):357-372. DOI： 10.19944/j.eptep.1674-8069.2025.03.002.

CAO Yuanbo, YANG Tao, CHEN Bing, et al. Research and prospect of Bi-based catalyst for electroreduction of CO₂ to formic acid under the background of double carbon[J]. Electric Power Technology and Environmental Protection, 2025, 41(3):357-372. DOI: 10.19944/j.eptep.1674-8069.2025.03.002. DOI：

摘要

目的

为提高火电行业排放的CO

电催化还原制甲酸（HCOOH）的效率，降低CO

在大气环境中的排放水平，

方法

本文通过分析电催化CO

还原反应（electrochemical carbon dioxide reduction reaction，ECO2RR）的途径和不同调控策略下的Bi金属基电催化效果，提出高效Bi基催化剂的改进方向。

结果

研究表明，在电解池中稳定运行时间大于100 h的情况下，Bi基催化剂可实现大于85%的法拉第效率；Bi基ECO2RR催化剂可以从表面形貌设计、表面改性、缺陷工程、组分调控4个方面进行改进。表面形貌设计可以提供更多的活性位点，但不能满足商业规模HCOOH生产的实际应用需求；表面改性可以在选择性和活性方面产生有益影响，但存在稳定性、成本、机理等问题；缺陷工程可以优化反应中电荷转移和中间体的结合强度，但缺陷的可控性和机理需要进行研究；组分调控可以从元素掺杂、合金化、异质结构构建3个方面进行，是目前优化Bi基ECO2RR反应的重要途径，但还需要补充更加贴合工业开发的检验和计算。

结论

Bi基催化剂在电还原CO

制HCOOH的工业化应用中具有突出潜力，更加深入的改进和机理研究可以加速CO

衍生化学品的工业化。

Abstract

Objective

In order to improve the efficiency of electrocatalytic reduction of CO

emitted by the thermal power industry to formic acid (HCOOH) and reduce the emission level of CO

in the atmospheric environment

Methods

In this paper

the improvement direction of high-efficiency Bi-based catalysts was proposed by analyzing the pathways of electrochemical carbon dioxide reduction reaction (ECO2RR) and the electrocatalytic effects of Bi metal-based catalysts under different control strategies.

Results

Studies have shown that Bi-based catalysts can achieve a Faraday efficiency greater than 85% when the stable operation time in the electrolytic cell is greater than 100 h. Bi-based ECO2RR catalysts can be regulated from four aspects : surface morphology design

surface modification

defect engineering and component regulation. The surface morphology design can provide more active sites

but it cannot meet the practical application requirements of commercial scale HCOOH production. Surface modification can have beneficial effects on selectivity and activity

but there are problems such as stability

cost and mechanism. Defect engineering can optimize the charge transfer in the reaction and the bonding strength of the intermediate

but the controllability and mechanism of defects need to be studied. Component regulation can be carried out from three aspects: Element doping

alloying

and heterostructure construction. It is an important way to optimize the Bi-based ECO2RR reaction

but it also needs to supplement the test and calculation that are more in line with industrial development.

Conclusion

Bi-based catalysts have outstanding potential in the industrial application of electroreduction of CO

to HCOOH.More in-depth improvement and mechanism research can accelerate the industrialization of CO

-derived chemicals.

关键词

Keywords

references

International Energy Agency . CO 2 Emissions in 2023 [R ] . 2024 .

LI L , LI X D , SUN Y F , et al . Rational design of electrocatalytic carbon dioxide reduction for a zero-carbon network [J ] . Chemical Society Reviews , 2022 , 51 ( 4 ): 1234 - 1252 .

KORTLEVER R , SHEN J , SCHOUTEN K J P , et al . Catalysts and reaction pathways for the electrochemical reduction of carbon dioxide [J ] . Journal of Physical Chemistry Letters , 2015 , 6 ( 20 ): 4073 - 4082 .

SHE X J , WANG Y F , XU H , et al . Challenges and opportunities in electrocatalytic CO 2 reduction to chemicals and fuels [J ] . Angewandte Chemie-International Edition , 2022 , 61 ( 49 ): e202211396 .

YANG F , ELNABAWY A O , SCHIMMENTI R , et al . Bismuthene for highly efficient carbon dioxide electroreduction reaction [J ] . Nature Communications , 2020 , 11 ( 1 ): 2352 .

WANG G X , CHEN J X , DING Y C , et al . Electrocatalysis for CO 2 conversion: From fundamentals to value-added products [J ] . Chemical Society Reviews , 2021 , 50 ( 8 ): 4993 - 5061 .

JIANG M H , WANG H Z , ZHU M F , et al . Review on strategies for improving the added value and expanding the scope of CO 2 electroreduction products [J ] . Chemical Society Reviews , 2024 , 53 ( 10 ): 5149 - 5189 .

FERNÁNDEZ-CASO K , DÍAZ-SAINZ G , ALVAREZ-GUERRA M , et al . Electroreduction of CO 2 : Advances in the continuous production of formic acid and formate [J ] . ACS Energy Letters , 2023 , 8 ( 4 ): 1992 - 2024 .

TAYLOR H S . A theory of the catalytic surface [J ] . Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences , 1925 , 108 : 105 - 11 .

ZHU X W , XU Y , RAN L , et al . Tuning strategies of indium-based catalysts for electrocatalytic carbon dioxide reduction [J ] . Small Structures , 2024 : 2400548 .

TIAN Y , LI D , WU J , et al . Electroreduction of CO 2 to formate with excellent selectivity and stability on nano-dendrite Bi film electrode [J ] . Journal of CO 2 Utilization , 2021 , 43 : 101360 .

LIU C , WU Z L , LI Y H , et al . In situ transformation of a Bi-based MOF to a highly active catalyst for CO 2 reduction [J ] . New Journal of Chemistry , 2024 , 48 : 15112 - 15119 .

ZHANG J H , ZHAO K , MA Y M , et al . High-yield electrosynthesis of formic acid from CO 2 reduction on single-bismuth catalyst loaded on N-doped hollow carbon nanospheress [J ] . Small Structures , 2024 , 5 : 2300323 .

MA S C , WU K , FAN S J , et al . Lattice-dislocated bismuth nanowires formed by in-situ chemical etching on copper foam for enhanced electrocatalytic CO 2 reduction [J ] . Separation and Purification Technology , 2024 , 349 : 127926 .

PANG Y Y , XIE R K , XIE H , et al . Porous Bi nanosheets derived from β-Bi 2 O 3 for efficient electrocatalytic CO 2 reduction to formate [J ] . ACS Applied Materials & Interfaces , 2024 , 16 ( 32 ): 42109 - 42117 .

CHEN Z P , ZHANG D D , LI Q Z , et al . In-situ reconstruction of Bi 60 In 2 O 93 nanotube for stable electroreduction of CO 2 at ampere-current densities [J ] . Applied Catalysis B: Environment , 2024 , 341 : 123342 .

CAO L L , HUANG J , WU X Y , et al . Boosting and stabilizing the electrocatalytic reduction of carbon dioxide on Bi 2 O 2 CO 3 via surface modification with p-aminobenzoic acid [J ] . Applied Catalysis B: Environment and Energy , 2024 , 358 : 124451 .

WU W B , TONG Y , YE Y T , et al . In-situ electrochemical transformation of F-modified metallic bismuth for highly-efficient CO 2 electroreduction and Zn-CO 2 battery [J ] . Chemical Engineering Journal , 2024 , 494 : 153105 .

NATARAJAN T , ARUMUGAM S , TSAI Y F , et al . Unveiling the enhanced electrochemical CO 2 conversion: The role of 3D porous BiOCl with defects and CTAB-mediated nanosheets [J ] . Journal of CO 2 Utilization , 2024 , 85 : 102888 .

WANG Y H , GONG H , WANG Y Y , et al . Lattice-dislocated Bi nanosheets for electrocatalytic reduction of carbon dioxide to formate over a wide potential window [J ] . Journal of Colloid and Interface Science , 2021 , 611 : 246 - 254 .

WU K , YANG P W , FAN S J , et al . Formation of bismuth nanosheets on copper foam coupled with nanobubble technology for enhanced electrocatalytic CO 2 reduction [J ] . Journal of Materials Chemistry A , 2024 , 12 ( 48 ): 33972 - 33983 .

ZHANG Y C , ZHANG Z J , WANG M , et al . Boosting electroreduction CO 2 reduction to formate at ampere level over La doped Bi catalyst [J ] . Sustainable Chemistry and Pharmacy , 2025 , 44 : 101973 .

YANG Z Y , AN X W , FENG Z B , et al . Fabrication of indium doped Bi/Bi 2 O 3 catalyst for efficiently selective electror eduction of carbon dioxide to formate [J ] . Separation and Purification Technology , 2025 , 354 : 129205 .

NING R Q , LIU F , GENG S , et al . Tuning microenvironment of Bi 2 O 3 nanosheets via Ce doping for promoting CO 2 electrolysis to formate [J ] . Journal of Environmental Chemical Engineering , 2024 , 12 ( 6 ): 114951 .

LIU M X , ZHOU A N , XU Z S , et al . Ordered PdBi alloys for high-performance CO 2 electroreduction and enhanced formic acid selectivity [J ] . Advanced Sustainable Systems , 2024 : 2400562 .

SUN J M , YANG W F , YU B , et al . Mechanistic understanding of the antimony-bismuth alloy promoted electrocatalytic CO 2 reduction to formate [J ] . Journal of Materials Chemistry A , 2025 , 13 : 5661 - 5669 .

LI Y M , JIN Y M , ZONG X , et al . In-Bi bimetallic nanofibers with controllable crystal facets for high-rate electrochemical reduction of CO 2 to formate [J ] . Journal of Materials Chemistry A , 2023 , 11 : 11445 - 11453 .

FENG X Z , ZOU H Y , ZHENG R J , et al . Bi 2 O 3 /BiO 2 Nanoheterojunction for Highly Efficient Electrocatalytic CO 2 Reduction to Formate [J ] . Nano Letters , 2022 , 22 ( 4 ): 1656 - 1664 .

XU Q Q , SU K X , CHEN J Y , et al . Bismuth oxycarbonates loaded on nitrogen-doped carbon: an efficient nanocomposite catalyst for electrochemical reduction of CO 2 to formate [J ] . Nanoscale , 2025 , 17 : 9588 - 9598 .

SONG C Z , JIANG K Y , SHI P F , et al . Interfacial engineering of bismuth sulfide/oxychloride heterostructure for boosting the conversion from CO 2 to formate at large current densities [J ] . Chemical Engineering Science , 2023 , 277 : 118838 .

YE R Z , ZHU J Y , TONG Y , et al . Metal oxides heterojunction derived Bi-In hybrid electrocatalyst for robust electroreduction of CO 2 to formate [J ] . Journal of Energy Chemistry , 2023 , 83 : 180 - 188 .

LAI D Z , XIE M Y , ZHAO H W , et al . High catalytic activity of tin oxide antimony supported bismuth heterogeneous catalyst with stable Bi-O structure for the electroreduction of CO 2 to formic acid [J ] . Electrochimica Acta , 2023 , 464 : 142893 .

WANG D N , SUN T T , XU L B , et al . Interfacial engineering of SnO 2 /Bi 2 O 2 CO 3 heterojunction on heteroatoms-doped carbon for high-performance CO 2 electroreduction to formate [J ] . Nano Research , 2022 , 16 : 2278 - 2285 .

ZHAI J R , HU Y , SU M F , et al . One-step phase separation for core-shell carbon@indium oxide@Bismuth microspheres with enh anced activity for CO 2 electroreduction to formate [J ] . Small , 2023 , 19 ( 10 ): 2206440 .

XU X , WEI Y , MI L H , et al . Interstitial Sn-doping promotes electrocatalytic CO 2 -to-formate conversion on bismuth [J ] . Science China Materials , 2023 , 66 ( 9 ): 3539 - 3546 .

REN X X , LIU F , WU H , et al . Reconstructed bismuth oxide through in situ carbonation by carbonate-containing electrolyte for highly active electrocatalytic CO 2 reduction to formate [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 9 ): e202316640 .

DENG C J , QI C F , XUE Z P , et al . A nanosheet CH 3 COO(BiO) topotactically converted into nanocomposite of bismuth clusters and Bi 2 O 2 CO 3 for highly efficient electrocatalytic reduction of CO 2 to formate [J ] . Fuel , 2024 , 373 : 132280 .

LIU S J , WANG H B , WANG X , et al . Bi 2 S 3 /In(OH) 3 heterojunction for enhanced CO2 electroreduction to formic acid [J ] . Progress in Natural Science-Materials International , 2024 , 34 ( 6 ): 1167 - 1172 .

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