改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究

李延吉; 宋朝辉; 王磊; 于想; 吴雨桐

doi:10.19912/j.0254-0096.tynxb.2025-0262

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改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究

更新时间：2026-07-22

- 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究
- 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究
- 太阳能学报 2026年47卷第6期页码：482-488
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- DOI：10.19912/j.0254-0096.tynxb.2025-0262
  中图分类号： S216
- 网络首发：2026-07-08，
  
  纸质出版：2026
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李延吉, 宋朝辉, 王磊, 等. 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究[J]. 太阳能学报, 2026,47(6):482-488.

李延吉, 宋朝辉, 王磊, et al. 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究[J]. 2026, 47(6): 482-488.
李延吉, 宋朝辉, 王磊, 等. 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究[J]. 太阳能学报, 2026,47(6):482-488. DOI： 10.19912/j.0254-0096.tynxb.2025-0262.

李延吉, 宋朝辉, 王磊, et al. 改性MCM-41催化纤维素木质素与聚丙烯共热解制生物油模拟研究[J]. 2026, 47(6): 482-488. DOI： 10.19912/j.0254-0096.tynxb.2025-0262.

摘要

利用浸渍法制备Cu、Fe、Co和Ni元素改性的MCM-41介孔分子筛催化剂

并对改性后的催化剂进行X射线衍射（XRD）和比表面积（BET）表征分析

探究不同金属改性催化剂的物理化学结构等特性。通过热重-傅里叶变换红外光谱联用（TG-FTIR）、热解-气相色谱/质谱联用（Py-GC/MS）等实验体系探究对催化共热解中纤维素及木质素与聚丙烯（PP）间协同反应及热解产物分布的影响。结果表明

在MCM-41的催化共热解中

MCM-41可促进生物质与PP之间的相互反应

芳烃和轻烃产率增加。相比MCM-41

改性MCM-41可促进轻烯烃、C5~C11脂肪烃和芳烃的析出。Cu、Fe和Co改性可促进单环芳烃的形成。相较于MCM-41

MP-M/Fe中烯烃析出占比最高

达到59.68%; XP-M/Fe中轻质烯烃析出占比最高

达到32.84%; XP-M/Co中烷烃析出占比最高

达到34.22%; 其他各组烯烃烷烃在热解产物析出占比中均有提高。

Abstract

In this paper

MCM-41 mesoporous molecular sieve catalysts modified by Cu

Co and Ni elements were prepared by impregnation method. XRD and BET characterization analyses were carried out on the modified catalysts to explore the physicochemical structures and other characteristics of catalysts modified by different metals.The effects of co-pyrolysis of cellulose

lignin and polypropylene （PP） on the synergistic reaction and the distribution of pyrolysis products were investigated by TG-FTIR and Py-GC/MS. The results show that MCM-41 can promote the reaction between biomass and PP

and the yields of aromatics and light hydrocarbons are increased. Compared with MCM-41

modified MCM-41 can promote the precipitation of light olefins

C~C aliphatic hydrocarbons and aromatics. Cu

Fe and Co modification can promote the formation of monocyclic aromatics. Compared with MCM-41

MP-M/Fe has the highest proportion of olefin precipitation

reaching 59.68%

and XP-M/Fe has the highest proportion of light olefin precipitation

reaching 32.84%. XP-M/Co has the highest proportion of alkane precipitation

reaching 34.22%. The proportion of other groups of alkenes and alkanes in the pyrolysis products increases.

关键词

Keywords

references

SHELDON R A.Green and sustainable manufacture of chemicals from biomass: state of the art[J]. Green chemistry, 2014, 16(3): 950-963.

CHEN X, CHE Q F, LI S J, et al.Recent developments in lignocellulosic biomass catalytic fast pyrolysis: strategies for the optimization of bio-oil quality and yield[J]. Fuel processing technology, 2019, 196: 106180.

TORO-TROCHEZ J L, DE HARO DEL RÍO D A, SANDOVAL-RANGEL L, et al. Catalytic fast pyrolysis of soybean hulls: focus on the products[J]. Journal of analytical and applied pyrolysis, 2022, 163: 105492.

ANSARI K B, KAMAL B, BEG S, et al.Recent developments in investigating reaction chemistry and transport effects in biomass fast pyrolysis: a review[J]. Renewable and sustainable energy reviews, 2021, 150: 111454.

LIZA M T, MELV X J W, JIUAN J C, et al. Co-pyrolysis of oil palm trunk and polypropylene: pyrolysis oil composition and formation mechanism[J]. South African journal of chemical engineering, 2023: 348-358.

LIU P Q, HUANG J H, YANG K, et al.Exploring the reaction chemistry of biomass upgrading over HZSM-5 catalyst through model compounds[J]. Fuel, 2022, 312: 122874.

WANG K G, KIM K H, BROWN R C.Catalytic pyrolysis of individual components of lignocellulosic biomass[J]. Green chemistry, 2014, 16(2): 727-735.

马中青, 丁紫霞, 李逍然, 等. 纤维素生物质与废塑料共催化热解制取富烃液体燃料的研究进展[J]. 燃料化学学报(中英文), 2024, 52(3): 438-451.

GRAMS J, JANKOWSKA A, GOSCIANSKA J.Advances in design of heterogeneous catalysts for pyrolysis of lignocellulosic biomass and bio-oil upgrading[J]. Microporous and mesoporous materials, 2023, 362: 112761.

DHAL J P, DASH T, HOTA G.Iron oxide impregnated mesoporous MCM-41: synthesis, characterization and adsorption studies[J]. Journal of porous materials, 2020, 27(1): 205-216.

CHI Y C, XUE J J, ZHUO J K, et al.Catalytic co-pyrolysis of cellulose and polypropylene over all-silica mesoporous catalyst MCM-41 and Al-MCM-41[J]. Science of the total environment, 2018, 633: 1105-1113.

ZHAO Y R, LI H, CHEN G Q, et al.Catalytic depolymerization of lignin by metal and metal oxide: a review[J]. Environmental pollutants and bioavailability, 2023, 35(1): 2263168.

LI K, WANG B, BOLATIBIEKE D, et al.Catalytic fast pyrolysis of biomass with Ni-P-MCM-41 to selectively produce levoglucosenone[J]. Journal of analytical and applied pyrolysis, 2020, 148: 104824.

HERTZOG J, GARNIER C, MASE C, et al.Fractionation by flash chromatography and molecular characterization of bio-oil by ultra-high-resolution mass spectrometry and NMR spectroscopy[J]. Journal of analytical and applied pyrolysis, 2022, 166: 105611.

YANG H P, YAN R, CHEN H P, et al.In-depth investigation of biomass pyrolysis based on three major components: ? hemicellulose, cellulose and lignin[J]. Energy & fuels, 2006, 20(1): 388-393.

MCKENDRY P.Energy production from biomass (part 1): overview of biomass[J]. Bioresource technology, 2002, 83(1): 37-46.

RAO T R, SHARMA A.Pyrolysis rates of biomass materials[J]. Energy, 1998, 23(11): 973-978.

CHEN W H, HO K Y, ANIZA R, et al.A review of noncatalytic and catalytic pyrolysis and co-pyrolysis products from lignocellulosic and algal biomass using Py-GC/MS[J]. Journal of industrial and engineering chemistry, 2024, 134: 51-64.

BREBU M, SPIRIDON I.Co-pyrolysis of LignoBoost® lignin with synthetic polymers[J]. Polymer degradation and stability, 2012, 97(11): 2104-2109.

LI X Y, SU L, WANG Y J, et al.Catalytic fast pyrolysis of Kraft lignin with HZSM-5 zeolite for producing aromatic hydrocarbons[J]. Frontiers of environmental science & engineering, 2012, 6(3): 295-303.

李延吉, 赵明, 李明泽, 等. 改性HZSM-5催化玉米秸秆与HDPE共热解制轻质芳烃[J]. 太阳能学报, 2023, 44(4): 238-246.

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