面向浓海水综合利用的电解海水制氢工艺

辛慧军; 刘威; 周道金; 孙晓明

doi:10.19912/j.0254-0096.tynxb.2023-1754

欢迎来到能源电力期刊网！

English Version 读者登录期刊登录

您当前的位置：

首页 >

文章列表页 >

面向浓海水综合利用的电解海水制氢工艺

更新时间：2025-12-07

- 面向浓海水综合利用的电解海水制氢工艺
- SEAWATER ELECTROLYSIS HYDROGEN PRODUCTION PROCESS FOR COMPREHENSIVE UTILIZATION OF CONCENTRATED SEAWATER
- 太阳能学报 2025年46卷第5期页码：15-20
- 作者机构：
  
  1. 深圳氢致能源有限公司,深圳,518000
  2. 北京化工大学化学学院,北京,100029
- 作者简介：
- 基金信息：
- DOI：10.19912/j.0254-0096.tynxb.2023-1754
  中图分类号： K91
- 网络出版：2025-06-04，
  
  纸质出版：2025
- 稿件说明：
移动端阅览
辛慧军, 刘威, 周道金, 孙晓明. 面向浓海水综合利用的电解海水制氢工艺[J]. 太阳能学报, 2025, 46(5): 15-20.

Xin Huijun, Liu Wei, Zhou Daojin, et al. SEAWATER ELECTROLYSIS HYDROGEN PRODUCTION PROCESS FOR COMPREHENSIVE UTILIZATION OF CONCENTRATED SEAWATER[J]. 2025, 46(5): 15-20.
辛慧军, 刘威, 周道金, 孙晓明. 面向浓海水综合利用的电解海水制氢工艺[J]. 太阳能学报, 2025, 46(5): 15-20. DOI： 10.19912/j.0254-0096.tynxb.2023-1754.

Xin Huijun, Liu Wei, Zhou Daojin, et al. SEAWATER ELECTROLYSIS HYDROGEN PRODUCTION PROCESS FOR COMPREHENSIVE UTILIZATION OF CONCENTRATED SEAWATER[J]. 2025, 46(5): 15-20. DOI： 10.19912/j.0254-0096.tynxb.2023-1754.

摘要

该文首先回顾当前海水电解进展

并针对连续海水电解、浓缩海水电解中存在的阳极催化剂选择性不足、阴极催化剂易毒化、海水资源难以得到充分利用等桎梏

从电极材料组分、结构优化、阳极耦合反应的拓展和钙镁离子的综合利用等角度对高效稳定电解海水工艺进行展望。

Abstract

This work first reviews recent progress in seawater electrolysis and then discusses key challenges in continuous and concentrated seawater electrolysis

such as insufficient anodic catalyst selectivity

cathodic catalyst poisoning

and inefficient utilization of seawater resources. It further provides prospects for developing efficient and stable seawater electrolysis systems by focusing on electrode composition

structural optimization

anodic coupling reactions

and the comprehensive utilization of calcium and magnesium ions.

关键词

Keywords

references

TURNER J A.Sustainable hydrogen production[J]. Science, 2004, 305(5686): 972-974.

程建荣, 谢素美, 曹艳, 等. 中国海上风电发展现状及对策建议研究[J]. 科技导报, 2025, 43(3): 115-128.

王轶文, 单衍雪, 刘丙萍. 膜分离技术研究进展[J]. 山东化工, 2021, 50(24): 62-63.

CIPOLLINA A, MICALE G, RIZZUTI L.Seawater desalination: conventional and renewable energy processes[M]. Heidelberg: Springer, 2009.

ELIMELECH M, PHILLIP W A.The future of seawater desalination: energy, technology, and the environment[J]. Science, 2011, 333(6043): 712-717.

American Water Works Association. Desalination of seawater-Manual of water supply practices M61[M]. United States: American water works association, 2011.

DIONIGI F, REIER T, PAWOLEK Z, et al.Design criteria, operating conditions, and nickel-iron hydroxide catalyst materials for selective seawater electrolysis[J]. ChemSusChem, 2016, 9(9): 962-972.

ZHANG F H, YU L, WU L B, et al.Rational design of oxygen evolution reaction catalysts for seawater electrolysis[J]. Trends in chemistry, 2021, 3(6): 485-498.

GENG S K, ZHENG Y, LI S Q, et al.Nickel ferrocyanide as a high-performance urea oxidation electrocatalyst[J]. Nature energy, 2021, 6(9): 904-912.

LINDQUIST G A, XU Q C, OENER S Z, et al.Membrane electrolyzers for impure-water splitting[J]. Joule, 2020, 4(12): 2549-2561.

GUO J X, ZHENG Y, HU Z P, et al.Direct seawater electrolysis by adjusting the local reaction environment of a catalyst[J]. Nature energy, 2023, 8(3): 264-272.

ZHAO Z, LIU H, GAO W, et al.Surface-engineered PtNi-O nanostructure with record-high performance for electrocatalytic hydrogen evolution reaction[J]. Journal of the American Chemical Society, 2018, 140(29): 9046-9050.

WAN R D, LUO M, WEN J B, et al.Pt-Co single atom alloy catalysts: Accelerated water dissociation and hydrogen evolution by strain regulation[J]. Journal of energy chemistry, 2022, 69: 44-53.

WANG Y D, WU W, CHEN R Z, et al.Reduced water dissociation barrier on constructing Pt-Co/CoOx interface for alkaline hydrogen evolution[J]. Nano research, 2022, 15(6): 4958-4964.

BALAJI R, KANNAN B S, LAKSHMI J, et al.An alternative approach to selective sea water oxidation for hydrogen production[J]. Electrochemistry communications, 2009, 11(8): 1700-1702.

FUJIMURA K, IZUMIYA K, KAWASHIMA A, et al.Anodically deposited manganese-molybdenum oxide anodes with high selectivity for evolving oxygen in electrolysis of seawater[J]. Journal of applied electrochemistry, 1999, 29(6): 769-775.

KUANG Y, KENNEY M J, MENG Y, et al.Solar-driven, highly sustained splitting of seawater into hydrogen and oxygen fuels[J]. Proceedings of the Natioral Acadeng of Sciences of the United States of America, 2019, 116(14): 6624-6629.

YU L, WU L B, MCELHENNY B, et al.Ultrafast room-temperature synthesis of porous S-doped Ni/Fe (oxy)hydroxide electrodes for oxygen evolution catalysis in seawater splitting[J]. Energy & environmental science, 2020, 13(10): 3439-3446.

ZHANG S, WANG Y, LI S, et al.Concerning the stability of seawater electrolysis: a corrosion mechanism study of halide on Ni-based anode[J]. Nature communications, 2023, 14(1): 4822.

XU W, WANG Z, LIU P, et al.Ag nanoparticle-induced surface chloride immobilization strategy enables stable seawater electrolysis[J]. Advanced materials, 2024, 36(2): e2306062.

[J]. Angew. Chem. Int. Ed. Engl., 2023, 62(40): e202309882.

SUN F, QIN J, WANG Z, et al.Energy-saving hydrogen production by chlorine-free hybrid seawater splitting coupling hydrazine degradation[J]. Nature communications, 2021, 12(1): 4182.

MAO Q Q, DENG K, YU H J, et al.In situ reconstruction of partially hydroxylated porous Rh metallene for ethylene glycol-assisted seawater splitting[J]. Advanced functional materials, 2022, 32(31): 2201081.

XIE H, ZHAO Z, LIU T, et al.A membrane-based seawater electrolyser for hydrogen generation[J]. Nature, 2022, 612(7941): 673-678.

SHI H, WANG T, LIU J, et al.A sodium-ion-conducted asymmetric electrolyzer to lower the operation voltage for direct seawater electrolysis[J]. Nature communications, 2023, 14(1): 3934.

LI P, WANG S, SAMO I A, et al.Common-ion effect triggered highly sustained seawater electrolysis with additional NaCl production[J]. Research (wash D C), 2020, 2020: 2872141.

刘国永, 任永锋, 薛宇, 等. 基于PEM电解槽的风氢耦合系统能量管理研究[J]. 太阳能学报, 2024, 45(7): 240-248.

胡鹏, 李志川, 李子航, 等. 深远海原位电解海水制氢的战略及技术研究[J]. 太阳能学报, 2024, 45(8): 63-70.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

甲烷与太阳能互补利用零碳排放制氢系统

考虑动态掺氢和灵活碳捕集的综合能源系统源荷协同优化

氢能发电技术的研究（Ⅰ）——铂碳复合电极材料对离子交换膜燃料电池放电性能的影响

Hg修饰Pt/C电极在水电解制氢-有机物储氢复合过程中的应用

银汞合金电极的制备及苯加氢性能的研究