长沙理工大学 能源与动力工程学院,湖南,长沙,410114
邓朝轩(2003—),男,湖南邵阳人,硕士研究生,研究方向为热化学储热。李传常(通信作者),男,教授,博士,E-mail:chuanchangli@csust.edu.cn。
纸质出版:2026
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邓朝轩, 谢宝珊, 李传常. 中高温热化学储热关键技术研究[J]. 动力工程学报, 2026, 46(9): 119-132.
邓朝轩, 谢宝珊, 李传常. 中高温热化学储热关键技术研究[J]. 动力工程学报, 2026, 46(9): 119-132. DOI: 10.19805/j.cnki.jcspe.2026.250815.
DOI: 10.19805/j.cnki.jcspe.2026.250815
热化学储热因其高储能密度和低热损失的特性,是实现长时热能存储的优选方式。本文总结了气-固和气-气中高温热化学储热体系的反应物,综述了多种热化学储能材料的特性,深入探讨了反应物改性、新材料开发与催化剂优化等研究难点;对比分析固定床、移动床和流化床等热化学反应器的性能,针对不同反应体系提出了适配的反应器;全面分析了热化学反应系统中的开式和闭式系统,探讨了这2类系统在变工况下的性能和实际应用中的优缺点;对热化学储热系统进行经济性分析,评估了系统的商业化潜力,分析了不同技术成熟度下的成本。
Thermochemical energy storage (TCES) is a preferred approach for long duration thermal energy storage due to its high energy storage density and low heat loss. The reactants used in gas-solid and gas-gas medium and high temperature TCES systems were summarized
the characteristics of various thermochemical storage materials were reviewed
and the research challenges including reactant modification
development of novel materials
and catalyst optimization were discussed in depth. The performances of fixed bed
moving bed
and fluidized bed thermochemical reactors were comparatively analyzed
and suitable reactor types were proposed for different reaction systems. Open and closed thermochemical reaction systems were comprehensively analyzed
with their performance under variable operating conditions and the advantages and disadvantages in practical applications evaluated. An economic analysis of TCES systems was conducted to assess their commercialization potential
and the costs at different technology readiness levels were estimated.
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