化学链技术中铁基载氧体掺杂改性的研究进展

梁志永; 周浩哲

doi:10.19805/j.cnki.jcspe.2025.240563

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

化学链技术中铁基载氧体掺杂改性的研究进展

新能源与储能 | 更新时间：2026-10-10

- 化学链技术中铁基载氧体掺杂改性的研究进展
- Research Progress on Doping Modification of Iron-based Oxygen Carriers in Chemical Looping Technology
- 动力工程学报 2025年45卷第11期页码：1872-1880
- 作者机构：
  
  1. 陕西理工大学机械工程学院,陕西,汉中,723000
  2. 陕西理工大学陕西省工业自动化重点实验室,陕西,汉中,723000
- 作者简介：
  
  梁志永(1985—),男,山东德州人,讲师,博士,研究方向为化学链制氢,E-mail:junjinxing@163.com
- 基金信息：
  
  陕西省教育厅科学研究计划资助项目(21JK0573)。
- DOI：10.19805/j.cnki.jcspe.2025.240563
  中图分类号：
- 网络首发：2025-11-17，
  
  纸质出版：2025-11-17
- 稿件说明：
移动端阅览
梁志永,周浩哲. 化学链技术中铁基载氧体掺杂改性的研究进展动力工程学报, 2025, 45(11): 1872-1880 https://doi.

org/10.19805/j.cnki.jcspe.2025.240563
梁志永,周浩哲. 化学链技术中铁基载氧体掺杂改性的研究进展动力工程学报, 2025, 45(11): 1872-1880 https://doi. DOI： 10.19805/j.cnki.jcspe.2025.240563.

org/10.19805/j.cnki.jcspe.2025.240563 DOI：

摘要

化学链技术是一种利用载氧体代替空气与燃料反应的新型能源利用技术

在碳减排和能源清洁高效利用方面具有发展潜力。基于载氧体性能改进方面的大量研究工作

深入分析了碱金属、碱土金属、过渡金属和稀土金属4类掺杂剂对铁基载氧体的改性作用

主要包括掺杂对于载氧体的反应活性、氧空位形成能、氧迁移速率、循环稳定性、表面活性位及抗积碳性能等;讨论了不同掺杂剂对铁基载氧体性能改性的侧重点;最后

总结并展望了铁基载氧体筛选和理论设计发展趋势

为化学链技术的进一步发展提供参考和借鉴。

Abstract

Chemical looping technology is a new energy utilization technology that uses oxygen carrier instead of air to react with fuel. It has development potential in carbon reduction and clean

efficient utilization of energy. Based on a lot of research work on the improvement of oxygen carrier properties

modification effects of alkali metal

alkaline earth metal

transition metal and rare earth metal on iron-based oxygen carrier were deeply analyzed

including reactivity

oxygen vacancy formation energy

oxygen migration rate

cycling stability

surface active sites and carbon resistance of iron-based oxygen carriers. The focus of different dopants on the modification of iron-based oxygen carrier properties was discussed. Finally

the development trend of screening and theoretical design of iron-based oxygen carriers in the future was systematically summarized and prospected

providing references and inspirations for the further development of chemical looping technology.

关键词

Keywords

references

程剑峰, 白秀佳, 徐强. 双碳目标下我国碳捕集技术研究进展[J]. 中国煤炭地质, 2023, 35(8): 26-31. CHENG Jianfeng, BAI Xiujia, XU Qiang. Research progress of carbon capture technology in China under carbon peaking and carbon neutrality goals[J]. Coal Geology of China, 2023, 35(8): 26-31.

LEWIS W K, GILLILAND E R. Production of pure carbon dioxide: US2665972A[P]. 1954-01-12.

RICHTER H J, KNOCHE K F. Reversibility of combustion processes[J]. ACS Symposium Series, 1983, 235: 71-85.

ISHIDA M, JIN H G. A new advanced power-generation system using chemical-looping combustion[J]. Energy, 1994, 19(4): 415-422.

ISHIDA M, JIN Hongguang. A novel combustor based on chemical-looping reactions and its reaction kinetics[J]. Energy, 1994, 27(3): 296-301.

金红光, 洪慧, 韩涛. 化学链燃烧的能源环境系统研究进展[J]. 科学通报, 2008, 53(24): 2994-3005. JIN Hongguang, HONG Hui, HAN Tao. Research progress on energy and environmental systems based on chemical looping combustion[J]. Chinese Science Bulletin, 2008, 53(24): 2994-3005.

郭磊, 董韦汝, 刘艇安, 等. 基于铜基的生物质化学链重整制备合成气实验研究[J]. 动力工程学报, 2024, 44(1): 56-61, 75. GUO Lei, DONG Weiru, LIU Tingan, et al. Study on Cu-based chemical-looping reforming of biomass for syngas production[J]. Journal of Chinese Society of Power Engineering, 2024, 44(1): 56-61, 75.

CHEN Jian, DUAN Lunbo, MA Yuxin, et al. Recent progress in calcium looping integrated with chemical looping combustion (CaL-CLC) using bifunctional CaO/CuO composites for CO 2 capture: a state-of-the-art review[J ] . Fuel, 2023, 334: 126630.

WEI Guoqiang, HE Fang, ZHAO Zengli, et al. Performance of Fe-Ni bimetallic oxygen carriers for chemical looping gasification of biomass in a 10 kW th interconnected circulating fluidized bed reactor[J ] . International Journal of Hydrogen Energy, 2015, 40(46): 16021-16032.

ARAUJO B D N R, DE MACEDO H P, MELO D M A, et al. Structure and reactivity of Brazilian iron ores as low-cost oxygen carriers for chemical looping combustion[J]. Industrial & Engineering Chemistry Research, 2022(6): 61.

赵一凡, 刘敦禹, 金晶. 化学链燃烧中载氧体结构设计对抗磨性的影响研究[J]. 动力工程学报, 2024, 44(4): 509-519. ZHAO Yifan, LIU Dunyu, JIN Jing. Study on effect of structure design of oxygen carriers in chemical looping combustion on abrasion resistance[J]. Journal of Chinese Society of Power Engineering, 2024, 44(4): 509-519.

WANG Chengrui, ZHENG Songming, LONG Mujun, et al. Enhanced reactivity over Ce 2 (SO 4 ) 3 /MgO with NiO modification for chemical looping partial oxidation of methane[J ] . International Journal of Hydrogen Energy, 2024, 71: 730-740.

BAI Yuting, BIAN Xue, WU Wenyuan. Catalytic properties of CuO/CeO 2 -Al 2 O 3 catalysts for low concentration NO reduction with CO[J ] . Applied Surface Science, 2019, 463: 435-444.

ELGARNI M M, TIJANI M M, MAHINPEY N. Characterization, kinetics and stability studies of Nio and CuO supported by Al 2 O 3 , ZrO 2 , CeO 2 and their combinations in chemical looping combustion[J ] . Catalysis Today, 2022, 397-399: 205-219.

龚陈俊, 梅道锋. 钨修饰对镍载氧体的沼气化学链重整制氢性能影响[J]. 化工进展, 2023, 42(4): 2130-2141. GONG Chenjun, MEI Daofeng. Effects of tungsten decoration on the performance of a Ni-based oxygen carrier during chemical looping reforming of biogas for hydrogen generation[J]. Chemical Industry and Engineering Progress, 2023, 42(4): 2130-2141.

CHEN Shubo, XIANG Wenguo, CHEN Shiyi. Modification of metal (Fe, Al) doping on reaction properties of a NiO oxygen carrier with co during chemical looping combustion[J]. ACS Omega, 2022, 7(5): 4381-4388.

GU Haiming, SHEN Laihong, ZHONG Zhaoping, et al. Potassium-modified iron ore as oxygen carrier for coal chemical looping combustion: continuous test in 1 kW reactor[J]. Industrial & Engineering Chemistry Research, 2014, 53(33): 13006-13015.

FENG Yuchuan, WANG Nana, GUO Xin. Density functional theory study on improved reactivity of alkali-doped Fe 2 O 3 oxygen carriers for chemical looping hydrogen production[J ] . Fuel, 2019, 236: 1057-1064.

FENG Yuchuan, WANG Nana, GUO Xin, et al. Characteristics of dopant distribution and surface oxygen vacancy formation for modified Fe 2 O 3 in chemical looping combustion[J ] . Fuel, 2020, 276: 117942.

胡晓雨, 金保昇, 王晓佳, 等. 草木灰水溶液改性的天然贫铁矿载氧体的反应性能[J]. 化工进展, 2017, 36(11): 4022-4029. HU Xiaoyu, JIN Baosheng, WANG Xiaojia, et al. Experimental study on plant-ash-water modified lean iron ore oxygen carrier in chemical looping combustion[J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4022-4029.

WANG Lulu, SHEN Laihong, LIU Weidong, et al. Chemical looping hydrogen generation using synthesized hematite-based oxygen carrier comodified by potassium and copper[J]. Energy & Fuel, 2017, 31(8): 8423-8433.

LIU Lu, ZACHARIAH M R. Enhanced performance of alkali metal doped Fe 2 O 3 and Fe 2 O 3 /Al 2 O 3 composites as oxygen carrier material in chemical looping combustion[J ] . Energy & Fuels, 2013, 27(8): 4977-4983.

LIN Yan, WANG Haitao, FANG Shiwen, et al. Chemical looping combustion of lignite using iron ore modified by foreign ions: alkaline-earth and transition metal ions[J]. Fuel, 2022, 327: 125079.

JIANG Hongming, HUO Ruiqiang, ZHANG Zhen, et al. Dechlorination performance in chemical looping conversion of polyvinyl chloride plastic waste using K/Na/Ca-modified iron ore oxygen carriers[J]. Journal of Environmental Chemical Engineering, 2022, 10(2): 107314.

MA Zhong, WANG Junfeng, LIU Guofu, et al. Regeneration of deactivated Fe 2 O 3 /Al 2 O 3 oxygen carrier via alkali metal doping in chemical looping combustion[J ] . Fuel Processing Technology, 2021, 220: 106902.

CHEN Lu, LI Ping, SONG Tao. Biomass ash chemistry in chemical looping combustion: interaction mechanism of potassium-ash and iron-based oxygen carriers[J]. Biomass and Bioenergy, 2024, 183: 107154.

魏泽华, 刘道诚, 王九占, 等. 碱金属掺杂对NiFeAlO 4 载氧体结构及反应特性的影响[J ] . 石油学报(石油加工), 2020, 36(6): 1178-1188. WEI Zehua, LIU Daocheng, WANG Jiuzhan, et al. Effects of alkali metal doping on NiFeAlO 4 oxygen carrier structures and its coal chemical looping combustion performance[J ] . Acta Petrolei Sinica (Petroleum Processing Section), 2020, 36(6): 1178-1188.

WANG Haiming, LIU Guicai, VEKSHA A, et al. Effective H 2 S control during chemical looping combustion by iron ore modified with alkaline earth metal oxides[J ] . Energy, 2021, 218: 119548.

WANG Haiming, LIU Guicai, VEKSHA A, et al. Iron ore modified with alkaline earth metals for the chemical looping combustion of municipal solid waste derived syngas[J]. Journal of Cleaner Production, 2021, 282: 124467.

MA Zhong, LU Yonggang, LIU Guofu. Enhanced cyclic redox reactivity of Fe 2 O 3 /Al 2 O 3 by Sr doping for chemical-looping combustion of solid fuels[J ] . Fuel, 2022, 324: 124625.

MA Zhong, LIU Guofu, LU Yonggang, et al. Improved redox performance of Fe 2 O 3 /Al 2 O 3 oxygen carrier via element doping in chemical looping combustion[J ] . Fuel Processing Technology, 2021, 224: 107030.

安阳, 袁思杰, 高振东, 等. Mg修饰Fe/Al载氧体煤化学链制氢[J]. 化工进展, 2022, 41(2): 648-654. AN Yang, YUAN Sijie, GAO Zhendong, et al. Chemical looping hydrogen generation of coal with oxygen carrier of Mg-modified Fe/Al[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 648-654.

SUN Rong, SHEN Laihong, WANG Shuang, et al. Co conversion over LaFeO 3 perovskite during chemical looping processes: influences of ca-doping and oxygen species[J ] . Applied Catalysis B: Environmental, 2022, 316: 121598.

ABDALAZEEZ A, LI Tianle, CAO Yongan, et al. Syngas production from chemical looping gasification of rice husk-derived biochar over iron-based oxygen carriers modified by different alkaline earth metals[J]. International Journal of Hydrogen Energy, 2022, 47(97): 40881-40894.

BLASCHKE F, BELE M, BITSCHNAU B, et al. Stabilizing effect of support materials on iron-based oxygen carrier pellets for chemical looping hydrogen in long-term operation[J]. Science Talks, 2024, 10: 100335.

YUAN Nini, HAN Ziheng, GUO Qingjie, et al. Chemical looping combustion characteristics and kinetic behaviour of Sr-doped perovskite-type CaFeO 3 oxygen carriers: theoretical and experimental investigations[J ] . The Canadian Journal of Chemical Engineering, 2023, 101(3): 1577-1590.

宋维锋, 武景丽, 孙德帅, 等. 助剂对ZnFe 2 O 4 氧载体化学链制氢反应性能的影响[J ] . 热力发电, 2024, 53(5): 19-27. SONG Weifeng, WU Jingli, SUN Deshuai, et al. Effect of additives on performance of ZnFe 2 O 4 oxygen carriers in chemical looping hydrogen generation reaction[J ] . Thermal Power Generation, 2024, 53(5): 19-27.

ZENG Zhiping, GAN Liyong, YANG Hongbin, et al. Orbital coupling of hetero-diatomic nickel-iron site for bifunctional electrocatalysis of CO 2 reduction and oxygen evolution[J ] . Nature Communications, 202 1, 12(1): 4088.

YAN Jin, TIAN Meng, SHI Ruhua, et al. Enhanced dual atomic Fe-Ni sites in N-doped carbon for bifunctional oxygen electrocatalysis[J]. Materials Today Energy, 2022, 30: 101171.

SHEN Xiaowen, WU Yujian, XU Xiwei, et al. Torrefaction enhanced biomass chemical-looping gasification coupled with CO 2 -splitting via half doped LaFe 0.5 M 0.5 O 3 perovskites[J ] . Fuel Processing Technology, 2022, 234: 107314.

LI Zhiyu, LI Jian, WANG Zhi, et al. Attempts of B-site doped LaFeO 3 oxygen carriers in high-moisture content biomass chemical looping gasification[J ] . Chemical Engineering Journal, 2024, 487: 150463.

ZHANG Huixin, YU Xiyang, SU Xue, et al. Dopant-enhanced harmonization of α-Fe 2 O 3 oxygen migration and surface catalytic reactions during chemical looping reforming of methane[J ] . Chemical Engineering Journal, 2024, 481: 148446.

王博, 郭庆杰. CuO修饰的赤泥载氧体废弃活性炭化学链燃烧[J]. 化工进展, 2018, 37(7): 2837-2845. WANG Bo, GUO Qingjie. Chemical looping combustion of waste activated carbon with oxygen carrier of CuO-modified red mud[J]. Chemical Industry and Engineering Progress, 2018, 37(7): 2837-2845.

YAN Beibei, LIU Zibiao, WANG Jian, et al. Mn-doped Ca 2 Fe 2 O 5 oxygen carrier for chemical looping gasification of biogas residue: effect of oxygen uncoupling[J ] . Chemical Engineering Journal, 2022, 446: 137086.

LIU Zibiao, WANG Jian, CAO Yan, et al. Mn-doping Ca 2 Fe 2 O 5 -based oxygen carriers in chemical looping gasification of biogas residue: a comprehensive study on the reaction mechanisms[J ] . Fuel, 2023, 332: 126207.

LI Yu, LIU Jing, LIU Feng, et al. Computational design and experimental validation of transition-metal doped CuFe 2 O 4 as oxygen carriers in chemical-looping combustion[J ] . Fuel, 2022, 330: 125584.

林德顺, 丁宁, 李炜光, 等. CuFe 2 O 4 氧载体与小麦秆-煤化学链共气化研究[J ] . 动力工程学报, 2024, 44(2): 188-195. LIN Deshun, DING Ning, LI Weiguang, et al. Research on chemical looping co-gasification of wheat straw-coal with CuFe 2 O 4 oxygen carrier[J ] . Journal of Chinese Society of Power Engineering, 2024, 44(2): 188-195.

ZHU Xiaolin, GUO Hongfei, LI Ruiying, et al. Regulating lattice oxygen mobility of FeO x redox catalyst via W-doping for enhanced chemical looping oxidative dehydrogenation of ethane[J ] . Chemical Engineering Journal, 2023, 470: 14 4219.

MORALES CORONA J J, SEDRANSK CAMPBELL K, FENNELL P S. Enhancement of iron-based oxygen carriers through alloying with tungsten oxide for chemical looping applications including water splitting[J]. Greenhouse Gases: Science and Technology, 2023, 13(4): 565-574.

MA Shiwei, CHEN Shiyi, GE Huijun, et al. Synergistic effects of the Zr and Sm co-doped Fe 2 O 3 /CeO 2 oxygen carrier for chemical looping hydrogen generation[J ] . Energy & Fuels, 2020, 34(8): 10256-10267.

LIN Chengqian, WANG Jun, HUANG Qunxing, et al. Chemical looping gasification of biomass using rare earth oxides doped ferric oxide oxygen carrier for hydrogen-rich syngas production[J]. The Canadian Journal of Chemical Engineering, 2024, 102(4): 1395-1407.

GAO Zhihua, FU Fengyan, ZHANG Zhaozhi, et al. Gd, La co-doped CeO 2 as an active support for Fe 2 O 3 to enhance hydrogen generation via chemical looping water gas shift[J ] . International Journal of Hydrogen Energy, 2022, 47(54): 22806-22818.

GAO Jie, PU Ge, WANG Pengcheng, et al. Study on the reaction performance of Ce-doped NiFe 2 O 4 oxygen carriers in the process of chemical looping hydrogen production[J ] . Inter national Journal of Energy Research, 2022, 46(3): 2810-2825.

GAO Jie, PU Ge, JIA Shuaihui, et al. Study on the redox performance of Cu and Ce-doped CoFe 2 O 4 as oxygen carriers for chemical looping hydrogen generation[J ] . International Journal of Energy Research, 2022, 46(6): 7424-7440.

MA S, CHEN S, ZHAO Z, et al. Enhanced hydrogen generation for Fe 2 O 3 /CeO 2 oxygen carrier via rare-earth (Y, Sm, and La) doping in chemical looping process[J ] . Energy & Fuels, 2018, 32(11): 11362-11374.

ZHAO Jun, XIONG Yingwei, GAO Zhihua, et al. A La, Sm co-doped CeO 2 support for Fe 2 O 3 to promote chemical looping splitting of CO 2 at moderate temperature[J ] . Sustainable Energy & Fuels, 2022, 6(5): 1448-1457.

DU Jun, WU Mudi, CHEN Shiyi, et al. Interactions of Mg-Fe-Al-O oxygen carriers with rare earth dopants (Ce, Y, Sm, La, and Pr) in chemical looping steam reforming[J]. Fuel, 2024, 361: 130606.

CHENG Fang, YAN Aijing, MA Shiwei, et al. Evolution of Sm-doped Fe 2 O 3 /CeO 2 oxygen carriers in chemical looping hydrogen generation[J ] . Energy Technology, 2021, 9(11): 2100535.

GAO Jie, PU Ge, YUAN Cong, et al. Performance evaluation of rare earth (La, Ce and Y) modified CoFe 2 O 4 oxygen carriers in chemical looping hydrogen generation from hydrogen-rich syngas[J ] . Fuel, 2022, 326: 124933.

GU Haiming, CUI Xiaobo, WANG Jianqiang, et al. Natural iron ore as oxygen carrier modified with rare earth metal for chemical looping hydrogen production[J]. Energy & Fuels, 2021, 35(18): 15234-15242.

LIU Chenlong, CHEN Dong, ASHOK J, et al. Chemical looping steam reforming of bio-oil for hydrogen-rich syngas production: effect of doping on LaNi 0.8 Fe 0.2 O 3 perovskite[J ] . International Journal of Hydrogen Energy, 2020, 45(41): 21123-21137.

浏览量

469

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于全流道冷却集热器的PVT系统热电性能研究

基于TDLAS的二维温度场与H2O浓度场重建研究

基于WOA的循环流化床锅炉SO2排放浓度VMD-Transformer预测模型

基于多通道特征提取与深度交互融合网络的IES多元负荷短期预测

融合长短期依赖的双通道短期风电功率预测