化学链技术中铁基载氧体掺杂改性的研究进展

梁志永; 周浩哲

doi:10.19805/j.cnki.jcspe.2025.240563

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化学链技术中铁基载氧体掺杂改性的研究进展

新能源与储能 | 更新时间：2025-11-28

- 化学链技术中铁基载氧体掺杂改性的研究进展
- Research Progress on Doping Modification of Iron-based Oxygen Carriers in Chemical Looping Technology
- 动力工程学报 2025年45卷第11期页码：1872-1880
- 作者机构：
  
  1. 陕西理工大学机械工程学院,陕西,汉中,723000
  2. 陕西理工大学陕西省工业自动化重点实验室,陕西,汉中,723000
- 作者简介：
  
  [ "梁志永(1985—),男,山东德州人,讲师,博士,研究方向为化学链制氢,E-mail:junjinxing@163.com" ]
- 基金信息：
  
  陕西省教育厅科学研究计划资助项目(21JK0573)。
- DOI：10.19805/j.cnki.jcspe.2025.240563
  中图分类号：
- 网络出版：2025-11-17，
  
  纸质出版：2025-11-17
- 稿件说明：
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梁志永,周浩哲. 化学链技术中铁基载氧体掺杂改性的研究进展动力工程学报, 2025, 45(11): 1872-1880 https://doi.

org/10.19805/j.cnki.jcspe.2025.240563
梁志永,周浩哲. 化学链技术中铁基载氧体掺杂改性的研究进展动力工程学报, 2025, 45(11): 1872-1880 https://doi. DOI： 10.19805/j.cnki.jcspe.2025.240563.

org/10.19805/j.cnki.jcspe.2025.240563 DOI：

摘要

化学链技术是一种利用载氧体代替空气与燃料反应的新型能源利用技术

在碳减排和能源清洁高效利用方面具有发展潜力。基于载氧体性能改进方面的大量研究工作

深入分析了碱金属、碱土金属、过渡金属和稀土金属4类掺杂剂对铁基载氧体的改性作用

主要包括掺杂对于载氧体的反应活性、氧空位形成能、氧迁移速率、循环稳定性、表面活性位及抗积碳性能等;讨论了不同掺杂剂对铁基载氧体性能改性的侧重点;最后

总结并展望了铁基载氧体筛选和理论设计发展趋势

为化学链技术的进一步发展提供参考和借鉴。

Abstract

Chemical looping technology is a new energy utilization technology that uses oxygen carrier instead of air to react with fuel. It has development potential in carbon reduction and clean

efficient utilization of energy. Based on a lot of research work on the improvement of oxygen carrier properties

modification effects of alkali metal

alkaline earth metal

transition metal and rare earth metal on iron-based oxygen carrier were deeply analyzed

including reactivity

oxygen vacancy formation energy

oxygen migration rate

cycling stability

surface active sites and carbon resistance of iron-based oxygen carriers. The focus of different dopants on the modification of iron-based oxygen carrier properties was discussed. Finally

the development trend of screening and theoretical design of iron-based oxygen carriers in the future was systematically summarized and prospected

providing references and inspirations for the further development of chemical looping technology.

关键词

Keywords

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