溴化钙对市政污泥焚烧烟气中汞的脱除研究

叶志榕; 王丽花; 陆峥嵘; 董宇航; 王飞; 池涌

doi:10.19805/j.cnki.jcspe.2025.240129

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

溴化钙对市政污泥焚烧烟气中汞的脱除研究

绿色低碳 | 更新时间：2026-10-10

- 溴化钙对市政污泥焚烧烟气中汞的脱除研究
- Study on the Removal of Mercury from Municipal Sludge Incineration Flue Gas by Calcium Bromide
- 动力工程学报 2025年45卷第6期页码：924-930
- 作者机构：
  
  1. 浙江大学能源工程学院,浙江,杭州,310027
  2. 上海城投污水处理有限公司,上海,201203
- 作者简介：
  
  叶志榕(1998—),男,福建福州人,硕士研究生,研究方向为焚烧烟气中汞的控制原理和技术
- 基金信息：
  
  国家重点研发计划资助项目(2019YFC1907000);国家自然科学基金资助项目(51976188);浙江省科技计划资助项目(2022C03092)
- DOI：10.19805/j.cnki.jcspe.2025.240129
  中图分类号：
- 网络首发：2025-06-16，
  
  纸质出版：2025
- 稿件说明：
移动端阅览
叶志榕,王丽花,陆峥嵘,董宇航,王飞,池涌. 溴化钙对市政污泥焚烧烟气中汞的脱除研究动力工程学报, 2025, 45(6): 924-930 https://doi.

org/10.19805/j.cnki.jcspe.2025.240129
叶志榕,王丽花,陆峥嵘,董宇航,王飞,池涌. 溴化钙对市政污泥焚烧烟气中汞的脱除研究动力工程学报, 2025, 45(6): 924-930 https://doi. DOI： 10.19805/j.cnki.jcspe.2025.240129.

org/10.19805/j.cnki.jcspe.2025.240129 DOI：

摘要

为探究溴化钙在市政污泥焚烧烟气中的脱汞效果

在实验室和工程现场开展了溴化钙脱汞试验。结果表明:添加溴化钙能有效氧化烟气中的单质汞

在800、900和1 000 ℃下

当溴汞化学当量比为2 000时

单质汞氧化率能达到80%

并且添加溴化钙对NO

和SO

排放特性影响较小

但添加溴化钙会使HCl排放量有所上升

特别是在溴汞化学当量比超过2 000时

HCl转化率急剧上升;当溴汞化学当量比为1 000和2 000时

烟气中气态汞脱除率能达到60%和73%

且添加溴化钙对常规污染物排放(NO

、SO

、HCl和烟尘)和锅炉运行状态没有影响。

Abstract

To investigate the mercury removal effect of calcium bromide in municipal sludge incineration flue gas

mercury removal experiments using calcium bromide were conducted both in the laboratory and at the engineering site. Results show that the addition of calcium bromide can effectively oxidize elemental mercury in the flue gas. At 800

900 and 1 000 ℃

when the chemical equivalence ratio of bromine to mercury is 2 000

the oxidation rate of elemental mercury can reach 80%. Moreover

the addition of calcium bromide has a minor effect on the emission characteristics of NO

and SO

but it causes the increase in HCl emissions

especially when the chemical equivalence ratio of bromine to mercury exceeds 2 000

the conversion rate of HCl

rises sharply. When the chemical equivalence ratio of bromine to mercury is 1 000 and 2 000

the removal rate of gaseous mercury in the flue gas can reach 60% and 73% respectively

and the addition of calcium bromide has no effect on the emission of conventional pollutants (NO

HCl

and particulate matter) and the operation of the boiler.

关键词

Keywords

references

DONG Lu, WANG Hai, HUANG Yaji, et al. Elemental mercury removal from coal-fired flue gas using recyclable magnetic Mn-Fe based attapulgite sorbent[J]. Chemical Engineering Journal, 2021, 407: 127182.

LI Honghu, PENG Xiyan, AN Miao, et al. Negative effect of SO 2 on mercury removal over catalyst/sorbent from coal-fired flue gas and its coping strategies: a review[J ] . Chemical Engineering Journal, 2023, 455: 140751.

LIU Dongjing, LI Chaoen, WU Jiang, et al. Novel carbon-based sorbents for elemental mercury removal from gas streams: a review[J]. Chemical Engineering Journal, 2020, 391: 123514.

YANG Jianzhou, SUN Yanling, WANG Zhenliang, et al. Heavy metal pollution in agricultural soils of a typical volcanic area: risk assessment and source appointment[J]. Chemosphere, 2022, 304: 135340.

朱廷钰, 晏乃强, 徐文青. 工业烟气汞污染排放监测与控制技术[M]. 北京: 科学出版社, 2017.

SONKE J E, ANGOT H, ZHANG Yanxu, et al. Global change effects on biogeochemical mercury cycling[J]. Ambio, 2023, 52(5): 853-876.

SELIN H, KEANE S E, WANG Shuxiao, et al. Linking science and policy to support the implementation of the Minamata Convention on Mercury[J]. Ambio, 2018, 47(2): 198-215.

乐凡阁. 大气典型污染物硫酸盐和汞迁移转化关键过程研究[D]. 合肥: 中国科学技术大学, 2021.

王婷婷. 低氧对鱼体甲基汞生物富集的影响[D]. 武汉: 华中农业大学, 2022.

KIM H, LEE K, LIM D I, et al. Increase in anthropogenic mercury in marginal sea sediments of the Northwest Pacific Ocean[J]. Science of The Total Environment, 2019, 654: 801-810.

BASU N, BASTIANSZ A, DREA J G, et al. Our evolved understanding of the human health risks of mercury[J]. Ambio, 2023, 52(5): 877-896.

中华人民共和国住房和城乡建设部. 中国城市建设统计年鉴2022[M]. 北京: 中国统计出版社, 2022.

程柳. 市政污泥中汞的地球化学特征与生态风险研究[D]. 焦作: 河南理工大学, 2018.

赵毅, 韩立鹏. 超低排放燃煤电厂低低温电除尘器协同脱汞研究[J]. 动力工程学报, 2019, 39(4): 319-323, 330. ZHAO Yi, HAN Lipeng. Synergistic removal of mercury by low-low temperature ESP for ultra-low emission coal-fired power plants[J]. Journal of Chinese Society of Power Engineering, 2019, 39(4): 319-323, 330.

ZHOU Jinsong, LUO Zhongyang, ZHU Yanqun, et al. Mercury emission and its control in Chinese coal-fired power plants[M]. Heidelberg: Springer, 2013.

CHEN Lei, DUAN Yufeng, ZHUO Yuqun, et al. Mercury transformation across particulate control devices in six power plants of China: the co-effect of chlorine and ash composition[J]. Fuel, 2007, 86(4): 603-610.

GAO Zhengyang, SUN Liwei, LV Shaokun, et al. Research on the effect of additives on mercury speciation in coal-fired derived flue gas[J]. Environmental Progress & Sustainable Energy, 2016, 35(6): 1566-1574.

张永强, 贾里, 乔晓磊, 等. 锰铈改性铁基生物焦单质汞吸附特性研究[J]. 动力工程学报, 2021, 41(9): 778-785. ZHANG Yongqiang, JIA Li, QIAO Xiaolei, et al. Adsorption performance study of elemental mercury on iron-based biochar modified by Mn-Ce[J]. Journal of Chinese Society of Power Engineering, 2021, 41(9): 778-785.

高正阳, 吕少昆. 二氧化锰改性活性炭吸附汞的机理研究[J ] . 动力工程学报, 2015, 35(11): 923-928, 933. GAO Zhengyang, L Shaokun. Mechanism study on Hg adsorption by MnO 2 -modified activated carbons[J ] . Journal of Chinese Society of Power Engineering, 2015, 35(11): 923-928, 933.

LI Ying, YU Jianglong, LIU Yangxian, et al. A review on removal of mercury from flue gas utilizing existing air pollutant control devices (APCDs)[J]. Journal of Hazardous Materials, 2022, 427: 128132.

LIU Yan, BISSON T M, YANG Hongqun, et al. Recent developments in novel sorbents for flue gas clean up[J]. Fuel Processing Technology, 2010, 91(10): 1175-1197.

BERRY M S. Full scale calcium bromide injection with subsequent mercury oxidation and removal within wet flue gas desulphurization system: experience at a 700 MW coal-fired power facility[D]. Birmingham: University of Alabama at Birmingham, 2012.

JIANG Xinyu, WANG Fei. Experimental study and reaction mechanism on the process of Br addition for mercury emission control[J]. Chemical Engineering Journal, 2022, 435: 134776.

YANG Yang, XU Wenqing, WU Yinghong, et al. Effect of HBr formation on mercury oxidation via CaBr 2 addition to coal during combustion[J ] . RSC Advances, 2016, 6(64): 59009-59015.

WANG Xiyue, MAO Yuxiang. Mercury in municipal sewage and sewage sludge[J]. Bulletin of Environmental Contamination and Toxicology, 2019, 102(5): 643-649.

唐翠梅. 我国煤中汞含量水平及洗选过程汞流向分析[J]. 能源环境保护, 2020, 34(2): 82-86. TANG Cuimei. Analysis of mercury content level in coal and mercury migration during washing process in China[J]. Energy Environmental Protection, 2020, 34(2): 82-86.

方欣. 溴化物对燃煤汞与NO联合脱除的实验研究[D]. 武汉: 华中科技大学, 2012.

蒋鑫宇. 溴化钙对固废焚烧烟气中汞的氧化反应机理研究[D]. 杭州: 浙江大学, 2022.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

基于多通道特征提取与深度交互融合网络的IES多元负荷短期预测

考虑风光不确定性的风电光伏与燃气电站联合参与日前-实时市场的交易决策研究

基于BKA-Transformer-BiGRU的垃圾焚烧炉SNCR脱硝系统动态建模

中高温热化学储热关键技术研究

大型能源基地经济-实时双层协同调度策略