1. 上海发电设备成套设计研究院有限责任公司,上海,200240
2. 上海交通大学 材料科学与工程学院,上海,200240
[ "田根起(1988—),男,河南驻马店人,博士,高级工程师,主要从事金属材料蠕变及疲劳试验、耐热钢组织性能演变及安全性评价方面的研究,E-mail:tiangenqi@speri.com.cn" ]
网络出版:2025-03-15,
纸质出版:2025
移动端阅览
田根起,崔正强,史宸伊,毛博,赵双群,付立铭,王延峰,单爱党. 锅炉用铁素体耐热钢研究与应用进展动力工程学报, 2025, 45(3): 334-346 https://doi.
org/10.19805/j.cnki.jcspe.2025.240008
田根起,崔正强,史宸伊,毛博,赵双群,付立铭,王延峰,单爱党. 锅炉用铁素体耐热钢研究与应用进展动力工程学报, 2025, 45(3): 334-346 https://doi. DOI: 10.19805/j.cnki.jcspe.2025.240008.
org/10.19805/j.cnki.jcspe.2025.240008 DOI:
对锅炉用2%~12%Cr铁素体耐热钢的发展历程、强化机制和服役过程中组织性能退化规律进行了梳理
并对国内外开发的5种新型9%~12%Cr铁素体耐热钢以及加工工艺进行了总结。结合工程应用
详细介绍了美国、日本和欧洲对9%~12%Cr铁素体耐热钢蠕变强度和许用应力下调情况
并就低硬度P91钢、焊接接头IV型裂纹开裂和氧化腐蚀等问题进行了讨论。建议深入研究C、N、B和稀土元素对耐热钢组织性能的影响
同时对机组深度调峰和长时服役后铁素体耐热钢的性能退化和损伤机制进行分析
为机组运行、设备安全性评价和新材料开发提供支撑。
The development history
strengthening mechanisms
and the degradation laws of microstructural properties during service of 2%-12%Cr ferritic heat-resistant steels for boilers were reviewed. A summary was provided on five newly developed 9%-12%Cr ferritic heat-resistant steels at home and abroad
as well as their processing techniques. Combined with engineering applications
a detailed introduction was given to the reduction adjustment in creep strength and allowable stress for 9%-12%Cr ferritic heat-resistant steels in the United States
Japan
and Europe. Discussions were conducted on issues such as the low hardness of P91 steel
type IV cracking in welded joints
and oxidation corrosion. It is suggested that in-depth research should be carried out on the effects of C
N
B
and rare earth elements on the microstructural properties of heat-resistant steels. Additionally
an analysis should be conducted on the performance degradation and damage mechanism of ferritic heat-resistant steels after deep peak shaving of the unit and long-term service
providing support for unit operation
equipment safety evaluation
and the development of new materials.
林富生, 王治政, 王宝忠, 等. 中国电站用耐热钢及合金的研制、应用与发展[J]. 动力工程学报, 2010, 30(4): 235-244. LIN Fusheng, WANG Zhizheng, WANG Baozhong, et al. Research, application and development of domestic heat-resistant steels and alloys for power plants[J]. Journal of Chinese Society of Power Engineering, 2010, 30(4): 235-244.
ABE F. Precipitate design for creep strengthening of 9% Cr tempered martensitic steel for ultra-supercritical power plants[J]. Science and Technology of Advanced Materials, 2008, 9(1): 013002.
陆燕荪, 刘吉臻, 周鹤良. 电力强国崛起——中国电力技术创新与发展[M]. 北京: 中国电力出版社, 2021.
杨富, 李为民, 任永宁. 超临界、超超临界锅炉用钢[J]. 电力设备, 2004, 5(10): 41-46. YANG Fu, LI Weimin, REN Yongning. Alloy steel used for supercritical and ultra supercritical pressure boiler[J]. Electrical Equipment, 2004, 5(10): 41-46.
MASUYAMA F. History of power plants and progress in heat resistant steels[J].ISIJ International, 2001, 41(6): 612-625.
CHRISTI W, RAHMEL A, SCHVTZE M. Behavior of oxide scales on 2.25Cr-1Mo steel during thermal cycling. I. scales formed in oxygen and air[J]. Oxidation of Metals, 1989, 31(1): 1-34.
ORLOV A, BUR K J, KUCHAOV K, et al. Microstructural development during high temperature creep of 9% Cr steel[J].Materials Science and Engineering: A, 1998, 245(1): 39-48.
VAILLANT J C, VANDENBERGHE B, HAHN B, et al. T/P23, 24, 911 and 92: new grades for advanced coal-fired power plants—Properties and experience[J]. International Journal of Pressure Vessels and Piping, 2008, 85(1/2): 38-46.
张红军, 周荣灿, 范长信. Laves相对P92钢冲击韧性影响的试验研究[J]. 动力工程学报, 2012, 32(1): 84-88. ZHANG Hongjun, ZHOU Rongcan, FAN Changxin. Influence of laves phase on impact toughness of P92 steel[J]. Journal of Chinese Society of Power Engineering, 2012, 32(1): 84-88.
KIMURA K, YAGUCHI M. Re-evaluation of long-term creep strength of base metal of ASME grade 91 type steel[C]//ASME 2016 Pressure Vessels and Piping Conference.Vancouver,Canada:ASME, 2016.
YOSHIZAWA M, IGARASHI M. Long-term creep deformation characteristics of advanced ferritic steels for USC power plants[J]. International Journal of Pressure Vessels and Piping, 2007, 84(1/2): 37-43.
ABE F, TABUCHI M, TSUKAMOTO S. Alloy design of MARBN for boiler and turbine applications at 650 ℃[J]. Materials at High Temperatures, 2021, 38(5): 306-321.
YOSHIZAWA M, IGARASHI M, MORIGUCHI K, et al. Effect of precipitates on long-term creep deformation properties of P92 and P122 type advanced ferritic steels for USC power plants[J]. Materials Science and Engineering: A, 2009, 510-511: 162-168.
MARUYAMA K, SAWADA K, KOIKE J I.Strengthening mechanisms of creep resistant tempered martensitic steel[J].ISIJ International, 2001, 41(6): 641-653.
BHADESHIAHK D H. Design of ferritic creep-resistant steels[J].ISIJ International, 2001, 41(6): 626-640.
EGGELER G. The effect of long-term creep on particle coarsening in tempered martensite ferritic steels[J]. Acta Metallurgica, 1989, 37(12): 3225-3234.
ISIKM I, KOSTKA A, EGGELER G. On the nucleation of Laves phase particles during high-temperature exposure and creep of tempered martensite ferritic steels[J]. Acta Materialia, 2014, 81: 230-240.
TANEIKE M, ABE F, SAWADA K. Creep-strengthening of steel at high temperatures using nano-sized carbonitride dispersions[J]. Nature, 2003, 424(6946): 294-296.
AGHAJANI A. Evolution of microstructure during long-term creep of a tempered martensite ferritic steel[D]. Bochum, Germany: Ruhr-University Bochum, 2009.
FEDOROVA I, BELYAKOV A, KOZLOV P, et al. Laves-phase precipitates in a low-carbon 9% Cr martensitic steel during aging and creep at 923 K[J]. Materials Science and Engineering: A, 2014, 615: 153-163.
TIAN Genqi, MAO Bo, XU Yuantao, et al. Investigation on gradual degradation of mechanical property and microstructure in 9% Cr heat-resistant steels via interrupted creep test[J]. Journal of Materials Science, 2023, 58(10): 4637-4656.
LEE JS, ARMAKI HG, MARUYAM AK, et al. Causes of breakdown of creep strength in 9Cr-1.8W-0.5Mo-VNb steel[J]. Materials Science and Engineering: A, 2006, 428(1/2): 270-275.
PANAIT C G, BENDIC K W, FUCHSMAN N A, et al. Study of the microstructure of the Grade 91 steel after more than 100 000 h of creep exposure at 600 ℃[J]. International Journal of Pressure Vessels and Piping, 2010, 87(6): 326-335.
CIPOLLA L, CAMINAD A S, VENDITT I D, et al. Microstructural evolution of ASTM P91 after 100 000 h exposure at 550 ℃ and 600 ℃[C]//9th Liege Conference on Materials for Advanced Power Engineering.Belgium: DTU, 2010.
PANAIT C G, ZIELISKA-LIPIECA, KOZIE L T, et al. Evolution of dislocation density, size of subgrains and MX-type precipitates in a P91 steel during creep and during thermal ageing at 600 ℃ for more than 100 000 h[J]. Materials Science and Engineering: A, 2010, 527(16/17): 4062-4069.
SAWADA K, KUSHIM A H, TABUCH I M, et al. Microstructural degradation of Gr.91 steel during creep under low stress[J]. Materials Science and Engineering: A, 2011, 528(16/17): 5511-5518.
CHEN R P, GHASSEMI ARMAK I H, MARUYAM A K, et al. Long-term microstructural degradation and creep strength in Gr.91 steel[J]. Materials Science and Engineering: A, 2011, 528(13/14): 4390-4394.
AGHAJANI A, SOMSEN C, EGGELER G. On the effect of long-term creep on the microstructure of a 12% chromium tempered martensite ferritic steel[J]. Acta Materialia, 2009, 57(17): 5093-5106.
PAYTON EJ, AGHAJANI A, OTTO F, et al. On the nature of internal interfaces in a tempered martensite ferritic steel and their evolution during long-term creep[J]. Scripta Materialia, 2012, 66(12): 1045-1048.
XIA Xianxi, ZHU Baoyin, JIN Xiao, et al. Analysis on microstructure and properties evolution and life prediction of P92 steel in high temperature service[J]. International Journal of Pressure Vessels and Piping, 2021, 194: 104482.
ZIELISKI A,GOLASKI G, SROKA M. Assessment of microstructure stability and mechanical properties of X10CrWMo-VNb9-2 (P92) steel after long-term thermal ageing for high temperature applications[J]. Kovove Materialy, 2016, 54(1): 1-10.
YAMAMOTO Y, ORTOLANI M. Micrograin structure evolution associated with grain boundary characteristics in grade 91 steel during long-term creep exposure[J]. Materials Science and Engineering: A, 2021, 826: 141993.
胡正飞, 吴细毛, 张斌, 等. 长期服役的12%Cr马氏体耐热钢中的碳化物及其变化[J]. 动力工程学报, 2010, 30(4): 269-274. HU Zhengfei, WU Ximao, ZHANG Bin, et al. Evolution of carbides in 12%Cr heat-resistant steels after long-term services[J]. Journal of Chinese Society of Power Engineering, 2010, 30(4): 269-274.
BAEK JH, KIM SH, LEE CB, et al. Mechanical properties and microstructural evolution of modified 9Cr-1Mo steel after long-term aging for 50 000 h[J]. Metals and Materials International, 2009, 15(4): 565-573.
张红军, 周荣灿, 于在松. P92钢时效过程中冲击性能和硬度变化的试验[J]. 动力工程学报, 2010, 30(7): 550-553. ZHANG Hongjun, ZHOU Rongcan, YU Zaisong. Evolution of impact energy and hardness of P92 steels during high-temperature aging tests[J]. Journal of Chinese Society of Power Engineering, 2010, 30(7): 550-553.
PANAIT C. Metallurgical evolution and creep strength of 9-12% Cr heat resistant steels at 600 ℃ and 650 ℃[D]. Paris, France: cole Nationale Suprieure des Mines de Paris, 2010.
SKLENICKA V, KUCHAROVA K, SVOBODOVA M, et al. The effect of a prior short-term ageing on mechanical and creep properties of P92 steel[J]. Materials Characterization, 2018, 136: 388-397.
HAMAGUCHI T, OKADA H, KURIHARA S, et al. Microstructural evaluation of 9Cr-3W-3Co-Nd-B heat-resistant steel (SAVE12AD) after long-term creep deformation[C]//ASME 2017 Pressure Vessels and Piping Conference.Waikoloa, USA: ASME, 2017.
彭建强. 650 ℃等级超超临界汽轮机关键部件选材[J]. 热力透平, 2016, 45(1): 51-56. PENG Jianqiang. Selection of materials for critical parts of 650 ℃ USC steam turbines[J]. Thermal Turbine, 2016, 45(1): 51-56.
MINAMI Y, YAMAMOTO Y, ORTOLANI M, et al. Tenaris new high steam oxidation resistant, creep strength enhanced ferritic steel THOR 115[C]//8th International Conference on Advances in Materials Technology For Fossil Power Plants.Oak Ridge, USA: Oak Ridge National Laboratory, 2016.
SUBANOVI M,PIRN J, ZELLER F, et al. Development of a new high-performance martensitic heat-resistant steel for boiler applications[C]//ASME 2018 Symposium on Elevated Temperature Application of Materials for Fossil, Nuclear, and Petrochemical Industries.Seattle, USA: ASME, 2018.
KLUEH RL, HASHIMOTO N, MAZIASZ PJ. New nano-particle-strengthened ferritic/martensitic steels by conventional thermo-mechanical treatment[J]. Journal of Nuclear Materials, 2007, 367-370: 48-53.
LI Shengzhi, ELINIYAZ Z, SUN Feng, et al. Effect of thermo-mechanical treatment on microstructure and mechanical properties of P92 heat resistant steel[J]. Materials Science and Engineering: A, 2013, 559: 882-888.
BENJAMIN JS. Dispersion strengthened superalloys by mechanical alloying[J]. Metallurgical Transactions, 1970, 1(10): 2943-2951.
UKAI S, HARADA M, OKADA H, et al. Tube manufacturing and mechanical properties of oxide dispersion strengthened ferritic steel[J]. Journal of Nuclear Materials, 1993, 204: 74-80.
马志宝, 蔡文河, 李炜丽, 等. 低硬度P91钢现场安全性评价及更换技术[J]. 焊接, 2022(3): 58-64. MA Zhibao, CAI Wenhe, LI Weili, et al. Safety assessment and replacement technology of low-hardness P91 steel in site[J].Welding & Joining, 2022(3): 58-64.
杨超, 汤淳坡, 龚宏强, 等. 低硬度P91管件的安全性评价及寿命预测[J]. 中国电力, 2017, 50(8): 82-86, 128. YANG Chao, TANG Chunpo, GONG Hongqiang, et al. Safety evaluation and lifespan prediction of low hardness P91 pipes[J]. Electric Power, 2017, 50(8): 82-86, 128.
赵彦芬, 张路, 刘艳, 等. 低硬度P91钢组织与性能研究[C]//中国电机工程学会金属材料专委会第一届学术年会论文集.太原: 中国电机工程学会, 2015:103.
杜晋峰, 蔡文河, 王斌, 等. 火力发电厂在役P91钢持久性能的快速评价技术[J]. 机械工程材料, 2020, 44(9): 42-46, 51. DU Jinfeng, CAI Wenhe, WANG Bin, et al. Rapid evaluation technique on stress-rupture property of in-service P91 steel of coal-fired power plants[J]. Materials for Mechanical Engineering, 2020, 44(9): 42-46, 51.
乔亚霞, 武英利, 徐联勇. 9%~12%Cr高等级耐热钢的IV型裂研究进展[J]. 中国电力, 2008, 41(5): 33-36. QIAO Yaxia, WU Yingli, XU Lianyong. Research progress on type IV cracking of 9%~12%Cr high-grade heat-resisting steel[J]. Electric Power, 2008, 41(5): 33-36.
马崇. P92钢焊接接头IV型蠕变开裂机理及预测方法研究[D]. 天津:天津大学, 2010.
ALBERT SK, KONDO M, TABUCHI M, et al. Improving the creep properties of 9Cr-3W-3Co-NbV steels and their weld joints by the addition of boron[J]. Metallurgical and Materials Transactions A, 2005, 36(2): 333-343.
白银. 电站锅炉用G115钢高温蒸汽氧化行为研究[D]. 北京: 北京科技大学, 2021.
TAN Lizhen, REN Xiao, ALLEN TR. Corrosion behavior of 9-12% Cr ferritic-martensitic steels in supercritical water[J]. Corrosion Science, 2010, 52(4): 1520-1528.
BISCHOFF J, MOTTAA T, EICHFELD C, et al. Corrosion of ferritic-martensitic steels in steam and supercritical water[J]. Journal of Nuclear Materials, 2013, 441(1/3): 604-611.
马云海, 王延峰, 张作贵. 新型铁素体耐热钢抗蒸汽氧化性能对比研究[J]. 动力工程学报, 2022, 42(5): 484-491. MA Yunhai, WANG Yanfeng, ZHANG Zuogui. Comparative study of steam oxidation resistance of new ferritic heat-resistant steels[J]. Journal of Chinese Society of Power Engineering, 2022, 42(5): 484-491.
马云海, 郑开云. 四种锅炉管材料650 ℃/26 MPa的蒸汽氧化研究[J]. 动力工程学报, 2015, 35(6): 509-516. MA Yunhai, ZHENG Kaiyun. Study on steam oxidation of 4 boiler tube materials at 650 ℃/26 MPa[J]. Journal of Chinese Society of Power Engineering, 2015, 35(6): 509-516.
马云海, 王延峰. 耐热钢蒸汽氧化膜生长和剥落的预测方法研究[J]. 动力工程学报, 2022, 42(7): 604-611. MA Yunhai, WANG Yanfeng. Research on prediction method for growth and exfoliation of steam oxide of heat-resistant steels[J]. Journal of Chinese Society of Power Engineering, 2022, 42(7): 604-611.
ABANG R, WEIB S, KRAUTZ H J. Impact of increased power plant cycling on the oxidation and corrosion of coal-fired superheater materials[J]. Fuel, 2018, 220: 521-534.
ABE F, KUTSUMI H, HARUYAMA H, et al. Improvement of oxidation resistance of 9 mass% chromium steel for advanced-ultra supercritical power plant boilers by pre-oxidation treatment[J]. Corrosion Science, 2017, 114: 1-9.
李玉, 何思凡, 刘光明, 等. 喷丸处理对S31035奥氏体耐热钢抗高温水蒸气氧化行为的影响[J]. 机械工程材料, 2023, 47(8): 65-71. LI Yu, HE Sifan, LIU Guangming, et al. Effect of shot peening on high temperature steam oxidation resistance of S31035 austenitic heat resistant steel[J].Materials for Mechanical Engineering, 2023, 47(8): 65-71.
张骏, 蔡文河, 杜双明, 等. 喷丸奥氏体耐热钢抗蒸汽氧化性的研究与使用现状[J]. 表面技术, 2020, 49(9): 133-140. ZHANG Jun, CAI Wenhe, DU Shuangming, et al. Research and application status of steam oxidation resistance of shot peening austenitic heat-resistant steel[J]. Surface Technology, 2020, 49(9): 133-140.
谌康, 蔡文河, 杜双明, 等. 喷丸对马氏体耐热钢高温蒸汽氧化行为的影响[J]. 金属热处理, 2021, 46(2): 66-73. SHEN Kang, CAI Wenhe, DU Shuangming, et al. Effect of shot peening on high-temperature steam oxidation behavior of martensitic heat-resistant steel[J]. Heat Treatment of Metals, 2021, 46(2): 66-73.
0
浏览量
224
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621