1. 中国电力工程顾问集团华东电力设计院有限公司,上海,200063
2. 上海电力大学 能源与机械工程学院,上海,201306
3. 上海非碳基能源转换与利用研究院,上海,200240
[ "姚向昱(1978—),男,正高级工程师,工程硕士,研究方向为火电厂热机设计、烟气污染物治理" ]
网络出版:2025-02-15,
纸质出版:2025
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姚向昱,蒋慧卿,王宁泽,李芳芹,曾卓雄,潘卫国. 650 MW电站燃煤机组氨煤混燃模拟研究动力工程学报, 2025, 45(2): 182-189 https://doi.
org/10.19805/j.cnki.jcspe.2025.230735
姚向昱,蒋慧卿,王宁泽,李芳芹,曾卓雄,潘卫国. 650 MW电站燃煤机组氨煤混燃模拟研究动力工程学报, 2025, 45(2): 182-189 https://doi. DOI: 10.19805/j.cnki.jcspe.2025.230735.
org/10.19805/j.cnki.jcspe.2025.230735 DOI:
以某600 ℃超超临界650 MW电站燃煤机组为研究对象
结合650~700 ℃超超临界电站煤粉锅炉的总体方案
以NH
3
替代部分燃煤
对NH
3
与煤在锅炉中混合燃烧进行了模拟研究。探究了不同NH
3
混燃比下炉膛内温度、物质分布规律
以及不同混燃比和NH
3
喷入方式对NO
x
排放的影响。结果表明:随着NH
3
混燃比增加
炉膛中心火焰温度明显降低
高温区域减少
炉膛内火焰温度整体呈下降趋势
这主要是因为NH
3
理论火焰温度较低
因此会延长低温射流
着火延迟;在NH
3
喷口位置NH
3
浓度达到峰值
随着燃烧进行
NH
3
基本被消耗完
在炉膛出口不会出现氨逃逸现象;在空气分级燃烧下
炉膛主燃区域O
2
浓度低
有利于NH
3
还原反应的发生;随着NH
3
混燃比增加
炉膛出口NO
x
排放浓度降低
这是由于炉膛内NH
3
会和NO发生还原反应
抑制了NO的生成;在NH
3
以不同方式喷入炉膛时
发现使用油枪喷口喷入时炉膛出口NO
x
浓度较低
这是因为油枪喷口位置更靠近主燃区。
Taking a coal-fired unit of a 600 ℃ ultra supercritical 650 MW power plant as the research object
combined with the overall plan of the coal-fired boiler of the 650-700 ℃ ultra supercritical power plant
the simulation study was conducted on the mixed combustion of NH
3
and coal in the boiler by replacing part of the coal with NH
3
.The temperature and mate
rial distribution of NH
3
in the furnace at different mixing ratios
as well as the effects of different mixing ratios and NH
3
injection ways on NO
x
emissions were explored. Results show that as the NH
3
mixing ratio increases
the flame temperature at the center of the furnace decreases significantly
the high-temperature area reduces
and the flame temperature inside the furnace shows an overall downward trend
this is mainly due to the lower theoretical flame temperature of NH
3
which prolongs the low-temperature jet and causes the delay of ignition. At the NH
3
nozzle position
the NH
3
concentration reaches its peak. As combustion progresses
NH
3
is basically consumed
and there will be no ammonia escape at the furnace outlet. Under air staged combustion
the low oxygen concentration in the main combustion zone of the furnace is conducive to the occurrence of NH
3
reduction reaction. As the NH
3
mixed fuel ratio increases
the NO
x
emission concentration at the furnace outlet decreases
which results from the reduction reaction between NH
3
and NO in the furnace
inhibiting the generation of NO.When NH
3
is sprayed into the furnace in different ways
the NO
x
concentration at the furnace outlet is lower when using the oil gun nozzle for injection. This is because the position of the oil gun nozzle is closer to the main combustion zone.
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