太原理工大学电气与动力工程学院
纸质出版:2026
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韩宇斌, 刘海玉, 牛俊天, 等. 660MW燃煤锅炉掺烧甲醇的模拟研究[J]. 热力发电, 2026,(10).
韩宇斌, 刘海玉, 牛俊天, et al. 660MW燃煤锅炉掺烧甲醇的模拟研究[J]. Thermal Power Generation, 2026, (10).
韩宇斌, 刘海玉, 牛俊天, 等. 660MW燃煤锅炉掺烧甲醇的模拟研究[J]. 热力发电, 2026,(10). DOI: 10.19666/j.rlfd.202602042.
韩宇斌, 刘海玉, 牛俊天, et al. 660MW燃煤锅炉掺烧甲醇的模拟研究[J]. Thermal Power Generation, 2026, (10). DOI: 10.19666/j.rlfd.202602042.
【目的】为实现大型燃煤电站锅炉低碳清洁燃烧,本文以甲醇作为替代燃料,对某660 MW超临界四角切圆燃煤机组锅炉开展甲醇掺烧数值模拟研究。【方法】论文探究了甲醇掺烧比例(0~30%)及喷入位置对炉内燃烧特性、烟气组分分布、污染物排放特性的影响规律。【结果】受甲醇高汽化潜热及燃烧产物中水蒸气增加烟气比热容的影响,炉膛温度随掺烧比例的增加而降低,30%掺烧比下温度下降96 K,煤粉着火延迟,燃烧不充分,燃尽率下降,甲醇的无氮特性及对热力型NO的抑制作用使NO排放显著减少,甲醇燃烧会生成少量非常规污染物甲醛(CH_2O);随甲醇喷入位置的上移,甲醇与氧气充分接触,燃烧更完全,燃烧中心集中于主燃区,主燃区温度上升约81 K,燃尽风区域的温度下降约70 K,同时主燃区上部的强还原区导致NO和CH_2O出口浓度显著降低。【结论】综合考虑燃烧和排放特性,15%为甲醇最佳掺烧比例,此时燃尽率为97.51%
NO出口质量浓度由270.6 mg/m
3
(标准工况下,下同)降至216.5 mg/m
3
(减排20%)
CH_2O峰值质量浓度为1.34 mg/m
3
,出口质量浓度为1.95×10
–4
mg/m
3
;在上层喷油口处喷入甲醇最佳,此时燃尽率为97.52%
NO出口质量浓度为199.96 mg/m
3
CH_2O峰值质量浓度为2.13 mg/m
3
,出口质量浓度为1.2×10
–4
mg/m
3
。
[Objective
]
To achieve low-carbon and clean combustion in large-scale coal-fired power plant boilers
this paper takes methanol as an alternative fuel and conducts numerical simulation on methanol co-firing in a 660 MW supercritical tangentially-fired coal-fired boiler. [Methods
]
A comprehensive numerical simulation method was adopted to systematically investigate the influence of different methanol blending ratios and injection positions on the combustion and emission performance of the boiler. Specifically
the methanol blending ratio was set in the range of 0~30%(with 0 as the pure coal combustion re
ference group)
and multiple typical injection positions(lower layer
middle layer
upper layer) were selected along the height of the furnace to simulate the co-combustion process. The simulation focused on analyzing the changes of in-furnace combustion characteristics(including furnace temperature distribution and burnout rate)
flue gas component distribution(including the content of H_2O
CO and CO
2
)
and pollutant emission characteristics(including NO and CH_2O). [Results
]
The overall furnace temperature decreases with the increase of the co-firing ratio due to the combined effects of the high latent heat of vaporization of methanol and the increased specific heat capacity of the flue gas caused by water vapor in the combustion products. Specifically
the temperature drops by 96 K at a 30% co-firing ratio
resulting in delayed ignition of pulverized coal
insufficient combustion
and a decrease in burnout rate. NO emissions are significantly reduced owing to the nitrogen-free nature of methanol and its inhibitory effect on thermal NO. Methanol combustion produces a small amount of formaldehyde(CH_2O)
an unconventional pollutant. As the methanol injection position moves upward
methanol comes into full contact with oxygen
leading to more complete combustion
and the combustion center is concentrated in the main combustion zone. The temperature in the primary combustion zone rises by approximately 81 K
while the temperature in the overfire air zone decreases by about 70 K. Concurrently
the strong reducing zone in the upper part of the main combustion zone leads to a significant decrease in the outlet mass concentrations of NO and CH_2O. [Conclusion
]
Considering both combustion and emission characteristics
15% is identified as the optimal co-firing ratio. At this ratio
the burnout rate is 97.51%
the outlet NO mass concentration decreases from 270.6 mg/m
3
to 216.5 mg/m
3
(a 20% reduction)
the peak CH_2O mass concentration is 1.34 mg/m
3
with an outlet mass concent
ration of 1.95×10
–4
mg/m
3
. Injecting methanol at the upper oil nozzle is the optimal configuration
where the burnout rate is 97.52%
the NO outlet mass concentration is 199.96 mg/m
3
the peak CH_2O mass concentration is 2.13 mg/m
3
and the outlet mass concentration is 1.2×10
–4
mg/m
3
.
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