工业固废复合储热材料制备及应用研究进展

何苗; 熊亚选; 闫京; 苏娅楠; 李萌; 尹美超; 张艾桐露; 李想; 樊颜搏; 李烁; 杨洋; 田曦; 吴玉庭

doi:10.19666/j.rlfd.202507129

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工业固废复合储热材料制备及应用研究进展

储能技术 | 更新时间：2026-06-12

- 工业固废复合储热材料制备及应用研究进展
- 工业固废复合储热材料制备及应用研究进展
- 热力发电 2026年55卷第4期页码：41-52
- 作者机构：
  
  1. 北京建筑大学供热供燃气通风及空调工程北京市重点实验室
  2. 北京天岳恒房屋经营管理有限公司
  3. 中闻印务投资集团有限公司
  4. 中铁电气化局有限公司上海电气化工程分公司
  5. 北京工业大学传热与能源利用北京市重点实验室
- 作者简介：
- 基金信息：
  
  国家重点研发计划项目（2022YFB2405202）;北京市教委科技一般项目（KM202210005016）;内蒙古科技重大专项（2021SZD0036）;北京市自然科学基金项目（3242015）~~
- DOI：10.19666/j.rlfd.202507129
  中图分类号： TB34;X705
- 纸质出版：2026
- 稿件说明：
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[1]何苗,熊亚选,闫京,等.工业固废复合储热材料制备及应用研究进展[J].热力发电,2026,55(04):41-52.
[1]何苗,熊亚选,闫京,等.工业固废复合储热材料制备及应用研究进展[J].热力发电,2026,55(04):41-52. DOI： 10.19666/j.rlfd.202507129.

DOI：10.19666/j.rlfd.202507129.

摘要

利用工业固体废弃物（固废）进行热能储存，代表了一种在解决环境挑战的同时推动储能技术发展的创新路径。系统考察了粉煤灰、赤泥、污泥、石膏、冶金渣及废弃混凝土等工业固废作为复合储热材料的潜力，全面探讨了其在复合储热系统中的材料特性、制备工艺及应用实践。研究揭示了此类材料在高温稳定性、导热性强化及相变材料整合方面的优势，可显著提升系统能量密度。同时，指出材料异质性与长期热循环稳定性等关键挑战，并深入分析工业固废改性策略、相变材料封装技术及创新复合设计方法，以增强其在可持续储热系统中的适用性。

Abstract

The utilization of industrial solid waste for thermal energy storage represents an innovative approach to address environmental challenges while advancing energy storage technologies. This study comprehensively examines the potential of industrial solid wastes

including coal fly ash

red mud

sewage sludge

gypsum

metallurgical slag

and waste concrete

as composite thermal energy storage materials. The discussion encompasses the material properties

preparation methods

and applications of industrial solid wastes in composite heat storage systems. The study highlights their capacity for high-temperature stability

enhanced thermal conductivity

and phase change material integration

offering significant energy density improvements. Moreover

the review identifies challenges such as material heterogeneity and long-term thermal cycling performance. Strategies for industrial solid waste modification

encapsulation of phase change materials

and innovative composite designs are analyzed to enhance their applicability in sustainable thermal energy storage systems.

关键词

Keywords

references

LIANG W, NING X, WANG G, ZHANG J, et al.Influence mechanism and kinetic analysis of cogasification of biomass char and semi-coke[J]. Renewable Energy, 2021, 163:331-341.

TENG W, YOU Z, LIAO Y, et al. Characteristics of heavy metal migration in the gasification-combustion process of rural solid waste:influencing factors and mechanisms[J].Waste Management, 2024, 190:350-359.

SONI K, PANWAR N L. Revolutionizing thermal energy storage:an overview of porous support materials for advanced composite phase change materials(PCMs)[J].Progress in Engineering Science, 2024, 1(4):100023.

CHEN Y, FAN Y, HUANG Y, et al. A comprehensive review of toxicity of coal fly ash and its leachate in the ecosystem[J]. Ecotoxicol Environ Saf, 2024, 269:115905.

XIONG Y, YAO C, REN J, et al. Waste semicoke ash utilized to fabricate shape-stable phase change composites for building heating and cooling[J]. Construction and Building Materials, 2022, 361:129638.

WANG A, LIU P, MO L, et al. Mechanism of thermal activation on granular coal gangue and its impact on the performance of cement mortars[J]. Journal of Building Engineering, 2022, 45:103616.

LIU Y, LI W, ZHANG Z, et al. Preparation of non-sintered building materials with a high content of red mud using magnesium oxychloride cement[J]. Construction and Building Materials, 2023, 408:133501.

RAM K, RAMAKRISHNA G. Performance evaluation of red mud as a construction material:a review[J]. Materials Today:Proceedings, 2023, 4:43.

CHEN K, LAN R, HE T, et al. Evaluation on reactivity of fly ash from different sources in alkali activated systemprogressing environmentally construction through waste utilization[J]. Construction and Building Materials, 2024,454:139118.

PEI C, ZHANG L. Resource utilization of sulfidic copper tailings in calcium aluminate cement:mechanical property, hydration process and environmental impact[J].Journal of Building Engineering, 2024, 96:110440.

KONG Y, ZHANG X, ZHANG L, et al. Investigation on utilization and microstructure of fine iron tailing slag in road subbase construction[J]. Construction and Building Materials, 2024, 447:138019.

LIU H, AN B, LIU L, et al. Recycling of graphite tailings:Effect of graphite tailings on property asphalt mortar and environmental impact evaluation[J]. Construction and Building Materials, 2024, 452:138859.

LI S, CHEN J, GAO W, et al. Current situation and prospects for the clean utilization of gold tailings[J].Waste Management, 2024, 180:149-161.

BARANI K, KALANTARI M. Recovery of kaolinite from tailings of Zonouz kaolin-washing plant by flotationflocculation method[J]. Journal of Materials Research and Technology, 2018, 7(2):142-148.

SONG Y, FENG Q, QIAO H, et al. Study on mechanically activated ferrous extraction tailing of nickel slag as cementitious materials:Physical and chemical properties,mechanical properties and reaction mechanism[J].Construction and Building Materials, 2024, 422:135748.

XIONG Y, ZHANG A, YANG Y, et al. Effect of carbon capture on carbide slag-steel slag shape-stable phase change materials for thermal energy storage[J].Renewable Energy, 2024, 235:121251.

CHEN Z, WANG J, LI Y, et al. Effect of CO2 wet mineralized steel slag-granulated blast furnace slag composite admixture on mechanical properties and chloride corrosion resistance of mortar[J]. Journal of Building Engineering, 2024, 98:111361.

GAO H, WANG J, CHEN X, et al. Nanoconfinement effects on thermal properties of nanoporous shapestabilized composite PCMs:a review[J]. Nano Energy,2018, 53:769-797.

谢宝珊,李传常,张波,等.硅酸盐矿物储热特征及其复合相变材料[J].硅酸盐学报, 2019, 47(1):143-52.XIE Baoshan, LI Chuanchang, ZHANG Bo, et al. Thermal storage characteristics and composite phase change materials of silicate minerals[J]. Journal of the Chinese Ceramic Society, 2019, 47(1):143-152.

王顺风,马雪,张祖华,等.粉煤灰-偏高岭土基地质聚合物的孔结构及抗压强度[J].材料导报, 2018,32(16):2757-2762.WANG Shunfeng, MA Xue, ZHANG Zuhua, et al. Pore Sturcture and compressive strength of fly ash-metakaolin based geopolymer[J]. Material Reports, 2018, 32(16):2757-2762.

XIONG Y, TIAN X, HE M, et al. Effects of CO2 capture on waste concrete/sodium nitrate form-stable phase change composites for energy storage[J]. Journal of Cleaner Production, 2024, 440:140896.

XIONG Y, HE M, ZHANG A, et al. Municipal sludgebased low-carbon phase-change composite towards energy storage:fabrication and investigation[J]. Applied Thermal Engineering, 2024, 256:124073.

XIONG Y, FAN Y, WU Y, et al. Low-carbon shape-stable phase change composite utilizing semi-coke ash for building thermal energy storage[J]. Solar Energy Materials and Solar Cells, 2024, 270:112823.

XIONG Y, WANG H, REN J, et al. Carbide slag recycling to fabricate shape-stable phase change composites for thermal energy storage[J]. Journal of Energy Storage,2023, 60:106694.

陈智博,钱艳峰,高美玲,等.粉煤灰基复合相变材料储热性能的研究进展[J].赤峰学院学报(自然科学版),2021, 37(8):59-66.CHEN Zhibo, QIAN Yanfeng, GAO Meiling, et al.Research progress on heat storage performance of fly ashbased composite phase change materials[J]. Journal of Chifeng University(Natural Science Edition), 2021,37(8):59-66.

王晓宇,李健,张伟屹,等.黄金尾矿/粉煤灰制备相变储能材料及其性能研究[J].矿产保护与利用, 2023,43(6):72-78.WANG Xiaoyu, LI Jian, ZHANG Weiyi, et al. Preparation and properties of phase change energy storage materials with gold tailings/fly ash[J]. Conservation and Utilization of Mineral Resources, 2023, 43(6):72-78.

杨俊杰,朱桂花,吕硕,等.球形高温复合定形相变材料性能及干压成型工艺的设计与研究[J].硅酸盐通报,2020, 39(2):621-630.YANG Juejie, ZHU Guihua, LYU Shuo, et al. Research on properties of spherical high temperature form-stable composite phase change materials and design of dry pressing technology[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(2):621-630.

NARESH R, PARAMESHWARAN R, RAM V V, et al.Study on thermal energy storage properties of bio-based n-dodecanoic acid/fly ash as a novel shape-stabilized phase change material[J]. Case Studies in Thermal Engineering, 2022, 30:101707.

ZHANG X, ZHANG H, LIANG Q, et al. Resource utilization of solid waste in the field of phase change thermal energy storage[J]. Journal of Energy Storage,2023, 58:106362.

CHEN P, JIANG D, CHEN Y, et al. Preparation and thermal properties of phase change energy storage composite material based on modified fly ash[J].Ceramics International, 2023, 49(22):35651-35664.

肖天烈,郁青春,刘治平,等.改性粉煤灰基高温定形相变材料的制备及性能研究[J].储能科学与技术,2023, 12(12):3699-3708.XIAO Tianlie, YU Qingchun, LIU Zhiping, et al.Preparation and properties of modified fly ash-based high temperature-shaped composite phase change materials[J].Energy Storage Science and Technology, 2023, 12(12):3699-3708.

赖榕永,王温馨,谢雯倩,等. MA-PA-SA/改性粉煤灰复合相变储能材料的制备与性能[J].材料导报, 2019,33(增刊1):219-222.LAI Rongyong, WANG Wenxin, XIE Wenqian, et al.Preparation and properties of composite phase change energy storage material MA-PA-SA/modified fly ash[J].Material Reports, 2019, 33(Suppl.1):219-222.

WANG T, WANG K, YE F, et al. Characterization and thermal properties of a shape-stable Na2CO3-K2CO3/coal fly ash/expanded graphite composite phase change materials for high-temperature thermal energy storage[J].Journal of Energy Storage, 2021, 33:102123.

LIU W, WANG Y, LI J, et al. Porous ceramics derived from steel slag/coal gangue mixtures using cigarette butts as the pore-forming agent[J]. International Journal of Applied Ceramic Technology, 2023, 20(6):3584-3595.

LIU X, HAN Y, HE F, et al. Characteristic, hazard and iron recovery technology of red mud:a critical review[J].Journal of Hazardous Materials, 2021, 420:126542.

YU K, JIA M, TIAN W, et al. Enhanced thermomechanical properties of cementitious composites via red mud-based microencapsulated phase change material:Towards energy conservation in building[J]. Energy,2024, 290:130301.

ANAGNOSTOPOULOS A, NAVARRO M E,STEFANIDOU M, et al. Red mud-molten salt composites for medium-high temperature thermal energy storage and waste heat recovery applications[J]. Journal of hazardous Materials, 2021, 413:125407.

ANAGNOSTOPOULOS A, NAVARRO M E,STEFANIDOU M, et al. Effect of carbon on the performance of red mud-molten salt composites for thermal management and waste heat recovery applications[J]. Journal of Energy Storage, 2021, 44:103363.

LI X, LIU L, ZHANG X, et al. Aging and mitigation of microplastics during sewage sludge treatments:An overview[J]. Science of the Total Environment, 2024, 922:171338.

TIAN H, AN Z, CUI W, et al. Effect of surface modification of sludge hydropyrolysis residue on the heat storage performance of composite hydrated salt[J].Journal of Energy Storage, 2024, 78:109928.

XIONG Y, SONG C, REN J, et al. Sludge-incinerated ash based shape-stable phase change composites for heavy metal fixation and building thermal energy storage[J].Process Safety and Environmental Protection, 2022, 162:346-356.

汤建伟,王续,刘咏,等.石膏基复合相变储能材料的研究进展[J].精细化工, 2024, 41(7):1424-1434.TANG Jianwei, WANG Xu, LIU Yong, et al. Research progress on gypsum-based composite phase change energy storage materials[J]. Fine Chemicals, 2024, 41(7):1424-1434.

张建武,朱建平,管学茂,等.相变储能石膏板的制备及储热性能分析[J].化工新型材料, 2015, 43(5):197-198.ZHANG Jianwu, ZHU Jianping, GUAN Xuemao, et al.Preparation and thermal property of gypsum-based phase change energy storage wallboards[J]. New Chemical Materials, 2015, 43(5):197-198.

曾令可,王慧,程小苏,等.相变储能石膏板制备和性能的研究[J].新型建筑材料, 2012, 39(12):27-29.ZENG Lingke, WANG Hui, CHENG Xiaosu, et al.Research on the preparation and properties of phase change thermal storage plasterboard[J]. New Building Materials, 2012, 39(12):27-29.

LACHHEB M, YOUNSI Z, NAJI H, et al. Thermal behavior of a hybrid PCM/plaster:A numerical and experimental investigation[J]. Applied Thermal Engineering, 2017, 111:49-59.

JEONG S G, CHANG S J, WI S, et al. Energy performance evaluation of heat-storage gypsum board with hybrid SSPCM composite[J]. Journal of Industrial and Engineering Chemistry, 2017, 51:237-243.

BAKE M, SHUKLA A, LIU S. Development of gypsum plasterboard embodied with microencapsulated phase change material for energy efficient buildings[J].Materials Science for Energy Technologies, 2021, 4:166-176.

赵亮,方向晨,黄新露,等.相变储能材料的制备及其在石膏基体中的应用研究[J].新型建筑材料, 2020,47(3):135-138.ZHAO Liang, FANG Xiangchen, HUANG Xinlu, et al.Preparation of phase change storage materials and application in gypsum matrix[J]. New Building Materials,2020, 47(3):135-138.

GENCEL O, BAYRAM M, SUBASI S, et al.Microencapsulated phase change material incorporated light transmitting gypsum composite for thermal energy saving in buildings[J]. Journal of Energy Storage, 2023,67:107457.

LI C, YU H, SONG Y, et al. Novel hybrid microencapsulated phase change materials incorporated wallboard for year-long year energy storage in buildings[J]. Energy Conversion and Management, 2019, 183:791-802.

XU D, HUANG Y, LIU W, et al. Preparation of composite microencapsulated phase change material based on phosphogypsum for passive building applications[J].Construction and Building Materials, 2023, 378:131068.

ANAGNOSTOPOULOS A, NAVARRO M, AHMAD A,et al. Valorization of phosphogypsum as a thermal energy storage material for low temperature applications[J].Journal of Cleaner Production, 2022, 342:130839.

刘凤利,白建侠,刘俊华,等.微胶囊/脱硫石膏相变储能复合材料的制备与性能[J].复合材料学报, 2024,41(8):1-10.LIU Fengli, BAI Jianxia, LIU Junhua, et al. Preparation and properties of phase change energy storage composite with microcapsules and desulfurized gypsum[J]. Acta Materiae Compositae Sinica, 2024, 41(8):1-10.

XIONG Y, LI S, REN J, et al. Effect of ratio of desulfurization gypsum to carbide slag on low-carbon phase change composites for energy storage[J]. Journal of Energy Storage, 2024, 91:112086.

XIONG Y, LI S, REN J, et al. Effect of carbon capture on desulfurization gypsum/carbide slag phase-change composites for waste removal and renewable energy storage[J]. Journal of Environmental Chemical Engineering, 2024, 12:112484.

YANG Y, LU P, SHAO R, et al. A comprehensive review of multisource solid wastes in sustainable concrete:From material properties to engineering application[J].Construction and Building Materials, 2024, 435:136775.

ILLAMPAS R, RIGOPOULOS I, IOANNOU I. Influence of microencapsulated Phase Change Materials(PCMs)on the properties of polymer modified cementitious repair mortar[J]. Journal of Building Engineering, 2021, 40:102328.

CAO V D, PILEHVAR S, SALAS-BRINGAS C, et al.Microencapsulated phase change materials for enhancing the thermal performance of Portland cement concrete and geopolymer concrete for passive building applications[J].Energy Conversion and Management, 2017, 133:56-66.

CHANG H, JIN L. Preparation and heat transfer performance of steel ball phase change concrete[J].Journal of New Materials for Electrochemical Systems,2020, 23(3):204-212.

LI X, ZHOU Y, ZHANG G X, et al. Experimental investigation of thermal and mechanical properties of magnesium oxychloride cement with form-stable phase change material[J]. Construction and Building Materials,2018, 186:670-677.

SUTTAPHAKDEE P, PONGSA U, KASEMSIRI P, et al.Thermal energy storage properties of form-stable paraffin/recycle block concrete composite phase change material[J]. Journal of Engineering Science and Technology, 2017, 12(1):256-264.

ZHANG Y, LIU J, SU Z, et al. Preparation of lowtemperature composite phase change materials(C-PCMs)from modified blast furnace slag(MBFS)[J]. Construction and Building Materials, 2020, 238:117717.

邱明伟,龙跃,杜培培,等.高炉渣基低温相变复合材料的特性表征与分析[J].烧结球团, 2022, 47(6):154-160.QIU Mingwei, LONG Yue, DU Peipei, et al. Characterization and analysis of low-temperature composite phase change materials based on blast furnace slag[J]. Sintering and Pelletizing, 2022, 47(6):154-160.

张浩,杨刚,龙红明.改性钢渣基相变微粉的制备与性能[J].过程工程学报, 2017, 17(6):1304-1309.ZHANG Hao, YANG Gang, LONG Hongming.Preparation and performance of modified steel slag-based phase change powders[J]. The Chinese Journal of Process Engineering, 2017, 17(6):1304-1309.

YE C, ZHANG M, YANG S, et al. Application of copper slags in encapsulating high-temperature phase change thermal storage particles[J]. Solar Energy Materials and Solar Cells, 2023, 254:112257.

LIU J, SU Z, XU J, et al. Thermal storage performance of NaNO3/cordierite-mullite ceramic(CMC)composites deriving from metallurgical slag[J]. Ceramics International, 2023, 49(23):38094-38102.

PEREIRA M J, LIMA M M F, LIMA R M F. Calcination and characterisation studies of a Brazilian manganese ore tailing[J]. International Journal of Mineral Processing,2014, 131:26-30.

WANG X, ZHANG W, SHAO Y, et al. Gold tailings-solar salt shape-stabilized phase change materials for mediumhigh temperature thermal energy storage[J]. Journal of Energy Storage, 2024, 76:109810.

LIU P, WANG Y, LIANG Z, et al. Experimental study on a novel form-stable phase change material based on solid waste iron tailings as supporting material for thermal energy storage[J]. Energies, 2023, 16(20):7037.

ZHANG Y, ZHANG J, WU L, et al. Extraction of lithium and aluminium from bauxite mine tailings by mixed acid treatment without roasting[J]. Journal of Hazardous Materials, 2021, 404:124044.

PIAO R, LI X, ZHAO P. Preparation of high temperature sensible heat storage materials from reduced vanadium tailings and graphite[J]. Materials Research Express,2021, 8(8):85503.

LI R, ZHOU Y, DUAN X. A novel composite phase change material with paraffin wax in tailings porous ceramics[J]. Applied Thermal Engineering, 2019, 151:115-123.

WU S, ZHOU Y, GAO W, et al. Preparation and properties of shape-stable phase change material with enhanced thermal conductivity based on SiC porous ceramic carrier made of iron tailings[J]. Applied Energy, 2024, 355:122256.

JIANG Q, PAN D, AI T. Preparation and characterization of porous ceramic matrix for composite phase change energy storage materials using iron tailings and miningstripping waste rock[J]. Industrial Minerals&Processing,2023, 52(5):24-31.

MENG J, PENG J, SRINIVASAKANNAN C, et al.Preparation and properties of endothermic functional ceramics with iron tailings as raw materials[J]. Materials Research Express, 2020, 7(5):55501.

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