磷酸酯抗燃油成分分析及性能研究

高占阳; 王笑微; 张帆; 王娟; 崔锐; 龙国军; 王宇; 徐勇智; 王伦; 韩明睿; 刘杰

doi:10.19666/j.rlfd.202503067

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

磷酸酯抗燃油成分分析及性能研究

热能科学研究 | 更新时间：2026-06-12

- 磷酸酯抗燃油成分分析及性能研究
- 磷酸酯抗燃油成分分析及性能研究
- 热力发电 2026年55卷第3期页码：64-71
- 作者机构：
  
  1. 西安热工研究院有限公司
  2. 华能甘肃能源开发有限公司西固分公司
- 作者简介：
- 基金信息：
  
  中国华能集团有限公司总部科技项目（HNKJ23-H22）~~
- DOI：10.19666/j.rlfd.202503067
  中图分类号： TM621
- 纸质出版：2026
- 稿件说明：
移动端阅览
[1]高占阳,王笑微,张帆,等.磷酸酯抗燃油成分分析及性能研究[J].热力发电,2026,55(03):64-71.
[1]高占阳,王笑微,张帆,等.磷酸酯抗燃油成分分析及性能研究[J].热力发电,2026,55(03):64-71. DOI： 10.19666/j.rlfd.202503067.

DOI：10.19666/j.rlfd.202503067.

摘要

磷酸酯抗燃油作为电厂汽轮机调速系统的工作介质，对汽轮机的正常运转起着至关重要的作用。运行中因油质劣化可能出现油质酸值升高，体积电阻率下降，以及生成油泥的情况，不同油品分解劣化程度不一致。对不同种类磷酸酯抗燃油化学成分进行分析，模拟不同磷酸酯分子劣化过程，并检测其抗老化性能。结果表明：以三-（二甲基苯基）磷酸酯为主要组分的磷酸酯抗燃油稳定性能优于以叔丁基苯基磷酸酯为主要组分的磷酸酯抗燃油；在研制磷酸酯抗燃油过程中，应提高三芳基磷酸酯中二甲基苯基的含量，降低苯基和叔丁基苯基的含量。

Abstract

As the working medium of turbine speed-control systems in power plants

phosphate ester fire-resistant fluid(FRF) plays a vital role in the normal operation of steam turbines. During operation

the deterioration of FRF may result in an increase in acid value

a decrease in volume resistivity

and the formation of oil sludge

and the degree of decomposition and deterioration varies among different oils. The chemical composition of different kinds of FRF samples was analyzed

the deterioration process of different phosphate ester molecules was simulated

and their aging-resistance properties were tested. The results show that the performance of FRF with tris-(dimethylphenyl) phosphate as the main component is more stable than that of FRF with tert-butylphenyl phosphate as the main component. During the production of FRF

the content of dimethylphenyl in triaryl phosphate should be increased

and the content of phenyl and tert-butyl phenyl should be reduced.

关键词

Keywords

references

冯丽苹,刘永洛,许海生,等.磷酸酯抗燃油抗劣化措施与试验[J].热力发电, 2018, 47(1):125-129.FENG Liping, LIU Yongluo, XU Haisheng, et al.Experimental study on anti-degradation measures for phosphorester fire-resistant oil[J]. Thermal Power Generation, 2018, 47(1):125-129.

刘永洛.磷酸酯抗燃油在我国发电厂的应用[J].润滑油, 2006, 21(5):9-13.LIU Yongluo. The application of phosphate ester hydraulic fluid in Chinese power industry[J]. Lubricating Oil, 2006,21(5):9-13.

程金仓,高翠芳.电厂用磷酸酯抗燃油的科学监督和维护管理[J].中国建材科技, 2014(6):63.CHENG Jincang, GAO Cuifang. Suggestion for scientific supervision and management in maintenance of Phoaphate ester fire-resistant fluid used in power plants[J]. China Building Materials Science&Technology, 2014(6):63.

魏洁慧,唐伟贤.抗燃油性能及应用研究[J].中国电力, 2002, 35(2):31.WEI Jiehui, TANG Weixian. Properties and application study of fire resistant oil[J]. Electric Power, 2002, 35(2):31.

郑东东,郝玉杰,李春诚,等.抗燃液压液的技术发展现状[J].润滑油, 2012, 27(2):5-9.ZHENG Dongdong, HAO Yujie, LI Chuncheng, et al.Technology development of fire-resistant hydraulic fluids[J]. Lubricating Oil, 2012, 27(2):5-9.

焦林郁,于华,宁资慧,等.芳基、烷基磷酸混酯类化合物的合成方法研究进展[J].有机化学, 2021, 41(11):4180-4191.JIAO Linyu, YU Hua, NING Zihui, et al. Research progress in the preparation of aryl and alkyl mixed phosphates[J]. Chinese Journal of Organic Chemistry,2021, 41(11):4180-4191.

石延超,王国建.有机磷阻燃剂的合成及在阻燃高分子材料中的应用研究进展[J].高分子材料科学与工程,2016, 32(5):167-175.SHI Yanchao, WANG Guojian. Progress on synthesis of organophosphorus flame retardant and application in polymer materials[J]. Polymer Materials Science and Engineering, 2016, 32(5):167-175.

霍国洋,王媛.有机磷酸酯阻燃剂的合成及应用研究进展[J].塑料助剂, 2015(5):1-5.HUO Guoyang, WANG Yuan. Research progress on synthesis and application of organophosphate flame retardants[J]. Plastic Additives, 2015(5):1-5.

XU Y, ZHANG W, YIN R, et al. Novel aryl phosphate for improving fire safety and mechanical properties of epoxy resins[J]. Polymers, 2024, 16:3049.

LEVCHIK S V, BRIGHT D A. New halogen-free fire retardant for engineering plastic applications[J]. Journal of Vinyl&Additive Technology, 2001, 7(2):98-103.

PAWLOWSKI H, SCHARTEL B. Flame retardancy mechanisms of triphenyl phosphate, resorcinol bis(diphenyl phosphate)and bisphenol a bis(dipheyl phosphate)in polycarbonate/acrylonitrile-butadienestyrene blends[J]. Polymer International, 2007, 56:1404.

边金彩.芳基磷酸酯阻燃剂的合成研究及应用[D].南京:南京师范大学, 2021:2.BIAN Jincai. Synthesis and application of aryl phosphate flame retardants[D]. Nanjing:Nanjing Normal University,2021:2.

HUANG M , ZENG L , WANG C ,et al. A comprehensive and quantitative comparison of organophosphate esters:characteristics, applications, environmental occurrence,toxicity, and health risks[J]. Critical Reviews in Environmental Science and Technology, 2025, 55(5):310-333.

田芳,刘健,陆莉霞.磷酸酯抗燃油油质劣化原因分析及治理[J].东北电力技术, 2020, 41(2):50-52.TIAN Fang, LIU Jian, LU Lixia. Analysis and treatment of oil quality degradation cause of phosphate ester resists fuel oil[J]. Northeast Electric Power Technology, 2020,41(2):50-52.

王娟,胡军,李烨峰.抗燃油产生凝胶的原因分析及处理[J].热力发电, 2011, 40(11):87-90.WANG Juan, HU Jun, LI Yefeng. Cause analysis and treatment of gel formation in fire resistant oil used for unit NO.4 in one power plant[J]. Thermal Power Generation,2011, 40(11):87-90.

卢勇.磷酸酯抗燃油应用中存在的问题及对策[J].东北电力技术, 2003, 24(11):5-7.LU Yong. Problems and counter measures existing in the application of phosphates non-flammable oil[J]. Northeast Electric Power Technology, 2003, 24(11):5-7.

王娟,刘晓莹,李烨峰.抗燃油体积电阻率超标的原因分析及处理[J].热力发电, 2012, 41(11):83-85.WANG Juan, LIU Xiaoying, LI Yefeng. Analysis of overproof of volume resistivity for fire resistant oil and its treatment[J]. Thermal Power Generation, 2012, 41(11):83-85.

李瑞,原洁.磷酸酯抗燃油油泥析出问题分析及治理措施研究[J].现代制造技术与装备, 2023(12):79-81.LI Rui, YUAN Jie. Analysis of the problem of resistance of phosphate ester to fuel oil sludge precipitation and study on treatment measures[J]. Modern Manufacturing Technology and Equipment, 2023(12):79-81.

孙晓勃,迟红锋,陈彭真,等.磷酸酯抗燃液压油的发展及劣化机制综述[J].合成润滑材料, 2023,50(4):35-38.SUN Xiaobo, CHI Hongfeng, CHEN Pengzhen, et al.Review on the development and deterioration mechanism of phosphate ester flame-resistant hydraulic oils[J].Modern Manufacturing Technology and Equipment,2023, 50(4):35-38.

汪红梅.磷酸酯抗燃油劣化机理的研究[J].长沙电力学院学报, 2003, 18(3):80-82.WANG Hongmei. Study on the degradation mechanisms of phosphates ester fire-resistant hydraulic oil[J]. Journal of Changsha University of Electric Power, 2003, 18(3):80-82.

张贤明,袁健,陈彬,等.磷酸酯抗燃油劣化机理及脱水净化技术研究[J].环境科学与技术, 2012, 35(1):129-133.ZHANG Xianming, YUAN Jian, CHEN Bin, et al. Cause of quality degradation and dehydration purification technology of phosphate ester fire-resistant oil[J]. Environmental Science&Technology, 2012, 35(1):129-133.

高占阳,王笑微,龙国军,等.一种磷酸三芳基酯的水解分析方法:CN 202410294325.9[P]. 2024-03-14.GAO Zhanyang, WANG Xiaowei, LONG Guojun, et al.A method for hydrolysis analysis of triaryl phosphate:CN202410294325.9[P]. 2024-03-14.

HAI L, QUAN M, ZHANGXIA W, et al. Ester bond:chemically labile yet mechanically stable[J]. ACS Nano,2023, 17(17):16870-16878.

HORI K, IKENAGA Y, ARATA K, et al. Theoretical study on the reaction mechanism for the hydrolysis of esters and amides under acidic conditions[J]. Tetrahedron, 2007,63(5):1264-1269.

CHUN H J, KIM H K, YOON Y, et al. First-principles investigation of phosphate ester and carboxylic acid on Ba TiO3 surfaces with stoichiometric terminations[J].Surface Science, 2020, 703:121737.

GAO H, KE Z F, DEYONKER N J, et al. Dinuclear Zn(II)complex catalyzed phosphodiester cleavage proceeds via a concerted mechanism:a density functional theory study[J]. Journal of the American Chemical Society, 2011,133(9):2904-2915.

陈喜,湛昌国.环状磷酸酯碱性水解活化自由能的理论计算[J].华中师范大学学报, 2004, 38(2):207-208.CHEN Xi, ZHAN Changguo. First-principle determination of activation free energy for alkaline hydrolysis of cyclic phosphate in aqueous solution[J]. Journal of Central China Normal University, 2004, 38(2):207-208.

WU K, DOYLE A. Parameterization of phosphine ligands demonstrates enhancement of nickel catalysis via remote steric effects[J]. Nature Chemistry, 2017, 9:779-784.

DU X, REN C, HONG X, et al. Theoretical study on the high polymer molecular weight of heteroatom-substituted constrained geometry catalyst[J]. Polymers, 2024, 16(23):3251.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

面向低碳转型的不同类型燃煤机组碳排放强度对比研究

核电机组联合海水淡化调峰性能与经济性

氨氢燃烧-分解耦合体系中燃烧器结构对氮氧化物生成与分解效率的作用机理研究

大型风电机组多点特征风速选择及估计

横流外掠管束式换热器的流动换热局部熵产分布规律研究