CHEN Qiuyu, LI Wentao, LI Zhuyu, et al. Research progress on thermochemical heat storage materials for medium to high temperature applications[J]. Thermal power generation, 2024, 53(6): 12-20.
CHEN Qiuyu, LI Wentao, LI Zhuyu, et al. Research progress on thermochemical heat storage materials for medium to high temperature applications[J]. Thermal power generation, 2024, 53(6): 12-20. DOI: 10.19666/j.rlfd.202403033.
Renewable energy suffers some drawbacks such as instantaneity
instability
and the mismatch between supply and demand during the utilization. Thermochemical heat storage exhibits distinct advantages
including high heat storage density
elevated heat storage temperature
and negligible heat loss during the long-term storage.It has the capability to convert intermittent energy sources into stable moderate and high temperature heat energy to fulfill the needs of fluctuating output. The classification
basic mechanisms and characteristics of thermochemical heat storage within reaction temperature range of 400~1 100 ℃ are reviewed. Subsequently
the thermal storage performance of typical thermochemical heat storage materials
such as carbonates
hydroxides
oxides
metal hydrides
ammonia and methane are analyzed
and the structural targeted regulation and modification methods are investigated
alongside the introduction of typical demonstration projects. Following this
the reactor design and system integration of solid-gas and gas-gas reaction systems are discussed. In the last
the future research interests are deliberated and proposed in the development and industrial application of thermochemical energy storage materials.