MA Jun, ZHANG Guoshan, GAO Xianghu, et al. Study on anti-coking and corrosion-resistant of nano-high-entropy ceramic coating on an ultra supercritical 1 000 MW unit boiler[J]. Thermal power generation, 2024, 53(5): 28-36.
MA Jun, ZHANG Guoshan, GAO Xianghu, et al. Study on anti-coking and corrosion-resistant of nano-high-entropy ceramic coating on an ultra supercritical 1 000 MW unit boiler[J]. Thermal power generation, 2024, 53(5): 28-36. DOI: 10.19666/j.rlfd.202401003.
纳米高熵陶瓷涂层在超超临界1 000 MW机组锅炉的防结焦耐腐蚀应用研究
摘要
针对某台超超临界1 000 MW机组燃用准东煤锅炉水冷壁出现的沾污结渣、高温腐蚀问题,基于锅炉的燃烧煤种特性、结焦状况以及腐蚀类型,开展了纳米高熵陶瓷涂层在锅炉后墙水冷壁燃尽风区域的工程验证试验。采用宏观检查、扫描电子显微镜(scanning electron microscope
and high-temperature corrosion in an ultra supercritical 1 000 MW unit boiler fueled by Zhundong coal
engineering verification test of nano-high-entropy ceramic coating in separated over fire air(SOFA) area of the boiler rear water wall was carried out
based on the coal characteristics
slagging condition and corrosion type of the boiler. Several methods such as macrographic check
scanning electron microscope(SEM)
X-ray diffraction(XRD)
Raman spectrum
friction coefficient and surface energy test were applied to observe the change of nano-high-entropy ceramic coating before and after experiments
thus to reveal the possible slag resistance and corrosion resistance mechanisms of nano-high-entropy ceramic coating. The results show that
the coating remained intact after 11 months' boiler operation
with no obvious slagging and corrosion pits on the surface and no significantly thinning of the pipe wall. Nano-high-entropy ceramic coating can better solve the problems of fouling
slagging and high-temperature corrosion on the boiler water wall
which provides a guarantee for safe operation of the boiler fueled by Zhundong coal.