WANG Jinyi, NIU Hongwei, LIU Lianbo, et al. Development and engineering application of new absorption solvent for CO2 capture from flue gas of coal-fired power plant[J]. Thermal power generation, 2021, 50(1): 54-61.
WANG Jinyi, NIU Hongwei, LIU Lianbo, et al. Development and engineering application of new absorption solvent for CO2 capture from flue gas of coal-fired power plant[J]. Thermal power generation, 2021, 50(1): 54-61. DOI: 10.19666/j.rlfd.202007189.
燃煤电厂烟气新型CO2吸收剂开发与工程应用
摘要
化学吸收法是目前燃煤电厂CO_2捕集中最成熟和最具规模化应用潜力的技术
但该技术能耗和成本较高
吸收剂的革新是CO_2捕集技术性能提升的关键之一。本文从电厂烟气特点出发
结合对有机醇胺类吸收剂不同单体特性的分析和比较
优化设计了混合胺吸收剂的配方
利用实验室气液反应平衡和反应焓一体化测试
筛选出优选配方HNC-5吸收剂
吸收反应焓较乙醇胺(MEA)低约20%
且吸收速率更快。真实烟气条件下1 000 t/a CO_2捕集中试装置测试表明
HNC-5性能指标与实验室测试结果一致
CO_2捕集率高于90%
而再生热耗较MEA降低20%左右。12万t/a CO_2捕集示范系统连续运行结果表明
运行期间HNC-5再生热耗1 t CO_2约2.8 GJ
1 t CO_2捕集成本降低约63元
吸收剂使用寿命更长
更有利于提高捕集系统的可用性和可靠性。
Abstract
Chemical absorption is the most mature technology and has the most large-scale application potential in current CO_2 capture technologies for coal-fired power plants. However
the main obstacle of its commercial application is the high cost and high energy consumption
innovation of new absorption solvent is one of the keys to the performance improvement. Based on the characteristics of flue gas and combined with the characteristics of different monomers of organic amine absorbers
the formula of blended amines are developed. Through true-heat flow calorimetric test combined with vapor-liquid equilibrium test
HNC-5 absorbent is selected
of which the enthalpy of absorption reaction is about 20% lower than of the ethanolamine(MEA) and the absorption rate is higher. The test on a 1 000 t/a CO_2 capture pilot plant under real flue gas conditions shows that
the performance indexes of HNC-5 are consistent with the lab test results. The CO_2 capture rate is higher than 90%
and the heat consumption during regeneration reduces by about 20% compared with the MEA. The continuous operation results of the 120 000 t/a CO_2 capture unit show that
for per ton CO_2 captured
the heat consumption of regeneration of HNC-5 is about 2.8 GJ
and the capture cost reduces by about 63 yuan
the usage life becomes longer
which is helpful to improving the system availability and reliability.