WANG Huashan, WANG Yuekang, ZHANG Xinyue, et al. Co-pyrolysis process and kinetics of PVC, PS and brassica[J]. Thermal power generation, 2020, 49(7): 84-92.
WANG Huashan, WANG Yuekang, ZHANG Xinyue, et al. Co-pyrolysis process and kinetics of PVC, PS and brassica[J]. Thermal power generation, 2020, 49(7): 84-92. DOI: 10.19666/j.rlfd.201909178.
PVC、PS与浒苔共热解过程分析及动力学研究
摘要
为了更好地处置废塑料中主要典型组分聚氯乙烯(PVC)与聚苯乙烯(PS)
将其与浒苔在氮气气氛中进行了共热解研究。结果表明:提高升温速率
可以使主要热解温度区间朝着高温区移动
热解速度变大;随着浒苔质量分数的增加
PVC与浒苔共热解主要热解温度区间朝着低温区移动
PS与浒苔共热解主要热解温度区间朝着高温区移动;PVC与浒苔共热解具有较好的协同作用
PVC质量分数为75%时
相对值可达34.5%;PS与浒苔共热解具有一定的抑制作用
PS质量分数为50%时
其协同作用相对值可达28%;动力学分析表明
一级动力学模型可以很好地描述二者的共热解过程
二者存在动力学补偿效应。
Abstract
In order to better dispose the main typical components(polyvinyl chloride(PVC) and polystyrene(PS)) of waste plastics
co-pyrolysis of them with enteromorpha prolifra in nitrogen atmosphere was performed. The results show that
increasing the heating rate made the main pyrolysis temperature range move toward the high temperature zone
and the pyrolysis speed turned larger. With the increase of mass fraction of the enteromorpha prolifra
the main co-pyrolysis temperature interval of the PVC and enteromorpha prolifra moved toward the low temperature zone
while that of the PS and enteromorpha prolifra moved toward the high temperature zone. The PVC and enteromorpha prolifra co-pyrolysis had a good synergistic effect
when the mass fraction of PVC was 75%
the relative value can reach 34.5%. The PS and enteromorpha prolifra co-pyrolysis had a certain inhibitory effect
when the mass fraction of PS was 50%
the relative value can reach 28%. The kinetics analysis shows that
the first-order kinetic model can well describe the co-pyrolysis process of the two