太原理工大学煤科学与技术省部共建国家重点实验室培育基地
网络出版日期:2019-04-01,
纸质出版日期:2019
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鲁阳, 王影, 张静, 等. 新疆昌吉油页岩与煤混合燃烧特性研究[J]. 热力发电, 2019,48(4):21-26.
LU Yang, WANG Ying, ZHANG Jing, et al. Co-combustion characteristics of Changji oil shale and coal[J]. Thermal power generation, 2019, 48(4): 21-26.
鲁阳, 王影, 张静, 等. 新疆昌吉油页岩与煤混合燃烧特性研究[J]. 热力发电, 2019,48(4):21-26. DOI: 10.19666/j.rlfd.201809180.
LU Yang, WANG Ying, ZHANG Jing, et al. Co-combustion characteristics of Changji oil shale and coal[J]. Thermal power generation, 2019, 48(4): 21-26. DOI: 10.19666/j.rlfd.201809180.
为了充分利用新疆昌吉地区低热值的油页岩
将油页岩和准东煤进行混合燃烧
利用热重分析仪(TG)、灰熔点测定仪、电感耦合等离子体发射光谱仪(ICP-OES)等手段对其混合燃料的燃烧特性、灰熔点变化及Na的挥发进行充分研究。结果表明:随着灰中碱性氧化物和酸性氧化物质量比(B/A)的降低(油页岩比例升高)
混合燃料的着火温度和燃尽温度逐渐升高
可燃性和燃烧特性降低;随着B/A的降低
混合燃料的灰熔点先下降后上升
当B/A为1.67时
灰中各组分比例正好位于低温共融区域
导致灰熔点降低;随着B/A的降低
Na元素的挥发呈先快速下降后缓慢上升的趋势
当燃烧温度为850℃、B/A为1.44时
Na挥发降至最低;油页岩可将煤中的Na固定至灰中
有效地抑制了Na挥发
为油页岩的高效利用提供了新途径。
In order to make full use of the low calorific value oil shale in Changji area of Xinjiang
the oil shale and Zhundong coal were co-fired
and the combustion characteristics
ash fusion point and sodium volatilization were fully studied by means of thermogravimetric analyzer(TG)
ash melting point tester and inductively coupled plasma emission spectrometer(ICP-OES). The experimental results show that
with the decrease of mass ratio of basic oxides to acidic oxides(B/A) in the ash
namely with the increase of blending ratio of oil shale
the ignition temperature and burnout temperature of the mixed fuel increased gradually
so the flammability and combustion characteristics decreased.With the decrease of B/A
the ash melting point of the mixed fuel decreased at first and then rose
when the B/A reached 1.67
the proportion of each component in the ash was located in the low temperature co-melting region
which led to a decrease in ash melting point. With the decrease of B/A
the volatilization of sodium element decreased rapidly and then slowly rose. When the combustion temperature was850 ℃ and the B/A was 1.44
the sodium volatilization reached the minimal value. The oil shale can fix the sodium element into the ash
which effectively suppressed the volatilization of Na. The result provides a new way for utilization of Changji oil shale.
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