WU Huoqiang, MAO Jin, WANG Jing, et al. Water quality characteristics and reuse treatment process of flue gas condensate in lignite-fired boilers[J]. Thermal power generation, 2019, 48(1): 90-96.
WU Huoqiang, MAO Jin, WANG Jing, et al. Water quality characteristics and reuse treatment process of flue gas condensate in lignite-fired boilers[J]. Thermal power generation, 2019, 48(1): 90-96. DOI: 10.19666/j.rlfd.201809174.
褐煤烟气冷凝水水质特点及其回用工艺
摘要
依托某电厂褐煤烟气水分冷凝回收中试装置
重点研究了冷凝换热器冷却水温度、冷却水流量和烟气流量对冷凝回收水质的影响规律
总结了冷凝水水质特点
并在此基础上
提出了烟气冷凝水回用脱硫系统及锅炉补给水系统的技术路线
完成了烟气冷凝水超滤-反渗透双膜处理工艺试验。试验结果表明:冷凝换热器冷却水温度越高、流量越小
烟气流量越大
褐煤烟气冷凝水水质越差;冷凝水总体呈较强酸性
pH值为2.63~3.51
电导率为261~1 132μS/cm
钙镁硬度、有机物质量浓度等均较低
但全铁和氨氮质量浓度稍高;采用超滤-反渗透工艺处理烟气冷凝水
产水回收率可达85%以上
电导率低于15μS/cm
且运行稳定。该研究结果可为褐煤烟气冷凝水回用的处理工艺设计提供参考。
Abstract
By using a power plant's pilot device of lignite flue gas water condensation recovery
the effects of cooling water temperature
cooling water flow rate and flue gas flow rate on the quality of condensation recovery water of condensing heat exchanger were studied. The characteristics of condensate water quality were summarized. On this basis
the technical routes of flue gas condensate reuse desulfurization system and boiler water supply system were put forward
and the experiment of ultrafiltration-reverse osmosis dual membrane process for flue gas condensate was finished. The results show that
with an increase in the temperature and decrease in the cooling water flow rate
the flue gas flow rate increased and the water quality of the lignite flue gas condensate became worse. The condensate water is generally strong acidic
its pH value is 2.63~3.51
the conductivity is 261~1 132 μS/cm
the calcium and magnesium hardness and organic matter concentration are low
but the total iron and ammonia nitrogen content is slightly higher. After the reverse osmosis process was applied to treat the flue gas condensate
the recovery rate of the produced water reached over 85% with conductivity less than 15 μS/cm. The system ran stably. The research results can provide reference for treatment and reuse of the lignite flue gas condensate.