To evaluate field-diffusion charging models

a systematic comparative study is conducted in this paper. A field-diffusion charge quantity sum model (FDCQSM) and a field-diffusion charging rate sum model (FDCRSM) are introduced in which the Maxwell-Wagner relaxation model for unipolar field charging is proposed to extend to bipolar charging. The predictions of the two models are compared with the experimental results reported in literature over wide ranges of particle diameters and electric fields. The results show that the FDCQSM is in good consistency with the experiments

while the FDCRSM performs well only if either diffusion charging or field charging dominates. Moreover

the physical meaning of the FDCRSM

the effects of ion property and the particle's conductivity on the particle charge

and applicability of the FDCQSM are discussed. The outcome

in which FDCRSM works badly when field charging and diffusion charging are important

indicates that it is likely to be as factual as FDCQSM. And FDCQSM seems to be valid in the study of the effects of aerosols on the electrical environment around high voltage direct current (HVDC) transmission lines

while FDCRSM is not recommended.