HAN Shuang, TAN Yun-zhi, YANG Shu-han, et al. Pozzolanic activity effect of expanded perlite on enhancing strength
of solidified sludge soil[J]. 2026, 47(1): 130-139.
HAN Shuang, TAN Yun-zhi, YANG Shu-han, et al. Pozzolanic activity effect of expanded perlite on enhancing strength
of solidified sludge soil[J]. 2026, 47(1): 130-139.DOI: 10.16285/j.rsm.2025.0128.
膨胀珍珠岩(expanded perlite,简称EP)协同水泥等固化材料固化淤泥,兼具泥-水分离功能与火山灰活性作用。为验证EP的火山灰活性效应,首先提出将EP浸泡于饱和Ca(OH)溶液中,借助傅立叶红外光谱(Fourier transform infrared spectroscopy,简称FTIR)、X射线衍射(X-ray diffraction,简称XRD)等测试方法,研究碱性环境中EP的火山灰反应过程;发现生成以水化硅酸钙(C-S-H)为主的胶凝产物,同时EP的多孔结构形成较大的比表面,为水化产物提供了生长便利,其反应程度受浸泡龄期影响;随后,将EP与淤泥混合后,再掺入水泥固化,研究其强度变化规律;结合扫描电镜-能谱分析(scanning electron microscopy-energy dispersive spectroscopy,简称SEM-EDS),揭示EP增强固化土强度的微观机制。结果表明,固化土pH值变化规律可间接反映EP的火山灰反应进程;EP-水泥固化土的强度既源于水泥水化产物的胶结作用,亦得益于EP的火山灰反应,该反应进一步增强了水泥水化产物、淤泥和EP之间的界面摩擦力和抗变形能力。碱性环境下EP也可缓慢溶出硅、铝等活性成分,进而与Ca发生反应,生成更多的胶凝产物,如C-S-H等,增强淤泥、水泥水化产物和EP之间的联结作用。
Abstract
Expanded perlite (EP) synergistically solidifies sludge with cement and other binding agents
simultaneously achieving sludge-water separation and exhibiting pozzolanic activity. To verify the pozzolanic activity effect of EP
the initial approach was to immerse EP in a saturated Ca(OH)₂ solution. The pozzolanic reaction of EP in an alkaline environment was systematically examined using Fourier transform infrared spectroscopy (FTIR)
X-ray diffraction (XRD)
and other test methods. It is found that the main products resulting from the pozzolanic reaction of EP are calcium silicate hydrate (C-S-H) gels
and the porous architecture of EP provides a large specific surface area that promotes the growth of hydration products. The extent of pozzolanic reaction is affected by the duration of immersion. After mixing EP with sludge and using cement for solidification
an investigation would be conducted to study the changes in strength. Combined with Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) test
the microscopic mechanism by which EP enhanced the strength of solidified soil was revealed. The test results show that the pozzolanic reaction process of EP is indirectly reflected in the change of pH in solidified soil. The strength of EP-cement solidified soil derives from both the cementing effects of hydration products and the pozzolanic activity of EP. This reaction enhances frictional interactions between the cement hydration products
sludge
and EP
thus increasing the soil’s resistance to deformation. EP slowly leaches active silica and aluminum under alkaline conditions. These elements subsequently react with Ca to form gel-like substances
such as C-S-H
which enhance the bonding effect among sludge particles