1. 重庆大学 土木工程学院,重庆,400045
2. 河海大学 岩土力学与堤坝工程教育部重点实验室,江苏,南京,210098
3. 河南大学 建筑工程学院,河南,开封,475000
4. 苏州科技大学 土木工程学院,江苏,苏州,215011
5. 重庆市文物考古研究院,重庆,400013
6. 敦煌研究院 国家古代壁画与土遗址保护工程技术研究中心,甘肃 敦煌,736200
网络首发:2025-06-10,
纸质出版:2025
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杨阳, 张程, 何想, 等. 活性生物泥诱导碳酸钙修复仿真文物砖可行性研究[J]. 岩土力学, 2025,46(6):1777-1787.
YANG Yang, ZHANG Cheng, HE Xiang, et al. Feasibility study on repairing simulated heritage bricks using bioslurry induced calcium carbonate[J]. 2025, 46(6): 1777-1787.
杨阳, 张程, 何想, 等. 活性生物泥诱导碳酸钙修复仿真文物砖可行性研究[J]. 岩土力学, 2025,46(6):1777-1787. DOI: 10.16285/j.rsm.2024.1103.
YANG Yang, ZHANG Cheng, HE Xiang, et al. Feasibility study on repairing simulated heritage bricks using bioslurry induced calcium carbonate[J]. 2025, 46(6): 1777-1787. DOI: 10.16285/j.rsm.2024.1103.
活性生物泥是基于微生物诱导碳酸钙沉淀(microbial-induced calcium carbonate precipitation,简称MICP)技术生成,由碳酸钙和嵌入其中的脲酶菌组成的具备脲酶活性的泥状混合物。提出了活性生物泥修复破损文物砖的方法,开展了仿真文物砖缺口修复的室内试验和PFC数值模拟,研究了修复砖块的力学响应和微观结构,评估了该方法的可行性,并对修复机制和受荷破裂机制进行了分析。结果表明:活性生物泥能够对缺口仿真文物砖进行有效修复,其修复效果受养护时间和缺口深度影响。养护时间越长,缺口深度越浅,修复后试样的抗弯强度越高。修复后缺口处碳酸钙的结构分析表明:浸泡养护后的活性生物泥可形成外层和内层碳酸钙,外层碳酸钙以大小10~25 μm菱形颗粒为主,而内层以5 μm左右的球型颗粒为主,形成两层碳酸钙结构的原因可能由于扩散至活性生物泥内外层的钙离子和尿素浓度差异引起的。养护1、3、5 d后外层碳酸钙厚度分别为2~2.5、3~4、4~5 mm。PFC数值试验显示内层碳酸钙的细观力学参数约为外层的0.1倍。试验和数值模拟均表明修复后仿真砖的抗弯强度增长主要由外层碳酸钙贡献。PFC数值模拟进一步显示,修复仿真砖受弯折荷载时,裂缝从内层碳酸钙开始并逐渐扩展至整个碳酸钙层和未损伤砖体。研究不仅拓展了微生物加固技术的应用范围,也为文物砖修复提供了新的思路。
The active bioslurry
a urease-active slurry mixture composed of calcium carbonate and embedded urease-producing bacteria
is generated using microbial-induced calcium carbonate precipitation (MICP) technology. This study proposes a method for heritage bricks restoration using active bioslurry. Laboratory experiments and PFC numerical simulations were conducted on notched simulated bricks to examine the mechanical response and microstructure of the repaired bricks and evaluate the feasibility of this method. Additionally
the repair and failure mechanisms under load were analyzed. The results show that active bioslurry effectively repairs notched simulated heritage bricks
with effectiveness influenced by curing time and notch depth. Longer curing time and shallower notch result in higher flexural strength of repaired samples. Analysis of the structure of calcium carbonate in the repaired notches indicates that after immersion curing
active bioslurry forms two layers of calcium carbonate: an outer layer of rhombohedral particles (approximately 10−25 m)
and an inner layer of spherical particles (around 5 m). This two-layer structure likely results from differences in calcium ion and urea concentrations diffusing into the inner and outer layers of bioslurry. After 1
3
and 5 days of curing
the thickness of the outer calcium carbonate layer was 2−2.5 mm
3−4 mm
and 4−5 mm
respectively. PFC numerical simulations indicate that the micromechanical parameters of the inner calcium carbonate layer are approximately 0.1 times those of the outer layer. Experimental and numerical simulation results demonstrate that the increase in flexural strength of the repaired simulated bricks is primarily attributed to the outer calcium carbonate layer. PFC simulations further show that when the repaired bricks are subjected to bending loads
cracks initiate in the inner calcium carbonate layer and gradually propagate through the entire calcium carbonate layer and the undamaged brick body. This study not only expands the application scope of microbial reinforcement technology but also provides new insights for the restoration of heritage bricks.
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