Study on mechanical properties and curing mechanism of metakaolin
based geopolymer solidified soil activated by calcium
carbide slag under low temperature curing
LIU Feng-yun, LUO Huai-rui, WAN Xu-sheng, et al. Study on mechanical properties and curing mechanism of metakaolin
based geopolymer solidified soil activated by calcium
carbide slag under low temperature curing[J]. 2023, 44(11): 3151-3164.
LIU Feng-yun, LUO Huai-rui, WAN Xu-sheng, et al. Study on mechanical properties and curing mechanism of metakaolin
based geopolymer solidified soil activated by calcium
carbide slag under low temperature curing[J]. 2023, 44(11): 3151-3164.DOI: 10.16285/j.rsm.2023.1100.
In order to address the issues about significantthermal disruption and carbon emissions associated with the use of cement forsolidifying frozen soil
calcium carbide slag was used as an alkali activatorto activate metakaolin based geopolymer for soil solidification. In thisresearch
the impacts of metakaolin and calcium carbide slag contents
curingtemperature and curing age on the compressive strength of the solidified soilwere investigated. Geopolymer solidified soil and cement solidified soil werecompared in parallel. The curing mechanism was studied by X-ray diffraction andelectron microscope scanning. Test results indicate that there is an optimalcontent of metakaolin and calcium carbide slag. When the content is lower thanthe optimal content
it plays an active role. On the contrary
it will have anegative effect. The optimal content of metakaolin and calcium carbide slag is10% and 6%
respectively. The compressive strength of the optimal contentsample cured at 20 ℃
–2 ℃ and –10 ℃ for 28 days is 3.783 MPa
1.164 MPa and 0.901 MPa
respectively. The main products of metakaolin basedgeopolymer activated by calcium carbide slag are amorphous hydrated calciumsilicate and hydrated calcium aluminate gel
which contribute to theimprovement of compressive strength of solidified soil. The compressivestrength of geopolymer solidified soil cured at –2 ℃ and –10 ℃for 28 days is 69% and 76%lower than that cured at 20 ℃
respectively. Due to theexpansion of the pores in the frozen state which is related to the ice crystal
the growth of cracks is promoted
the efficiency of geological polymerizationreaction is reduced and the amount of polymerization products is reduced.Compressive strength of the samples increases with the increase of curing age
because of the more silicon-aluminum grid structures produced by the geologicalpolymerization reaction
the lower the porosity of the solidified soil and theinternal structure of the soil is intertwined to form a denser structure. Thegeopolymerization reaction is less affected by low temperature. Compressivestrength of geopolymer solidified soil cured at 20 ℃
–2 ℃ and –10 ℃ for 28 days is 1.07
1.13 and 1.19 times that ofcement solidified soil
respectively. The research results lay a theoreticalfoundation for the application of geopolymer in subgrade soil reinforcement infrozen soil area.