MIN Fan-lu, SHEN Zheng, LI Yan-cheng, et al. Solidification and carbonization experimental study on magnesium oxide
in shield waste soil and its carbonization mechanism[J]. 2024, 45(2): 364-374.
MIN Fan-lu, SHEN Zheng, LI Yan-cheng, et al. Solidification and carbonization experimental study on magnesium oxide
in shield waste soil and its carbonization mechanism[J]. 2024, 45(2): 364-374.DOI: 10.16285/j.rsm.2023.0268.
The waste soil generated during shield tunnel construction poses a challenge in terms of stacking
transportation
and treatment. One promising approach is the use of magnesium oxide (MgO) for the solidification treatment of waste soil
as it is abundant in raw materials
has low production energy consumption
and is eco-friendly. The limit moisture content w
unconfined compressive strength qu and modulus of elasticity E of MgO solidified and carbonized mucky waste soil were studied by changing the MgO content am
curing age T
and carbonization time H. The solidification and carbonization mechanism of MgO-treated mucky waste soil was discussed in combination with the microstructure and the change rule of mineral composition. The results demonstrate that MgO solidification and carbonization have a significant reinforcing effect on the soil. The reinforcement effect initially increases and then stabilizes with increasing am and T
while it shows an initial increase followed by a decrease with H. Carbonization for 4 hours reduces the soil plasticity index (IP) by more than 57% under different am and T conditions
leading to a significant reduction in soil plasticity. The qu of solidified and carbonized soils reaches a peak value at H of 4 hours
with values up to 1.4 MPa
which is 220%–350% higher than the strength before carbonization. The effect of solidification and carbonization reaction on the increase in E of the soil mass is greatly influenced by am. When am exceeds 9%
the E50 increase of the sample carbonized for 4 hours exceeds 500%. During the process of MgO solidification and carbonization
hydration products and carbonization products are continuously generated and developed. They form a network and flower-like microstructure
filling the pores between soil particles
enhancing cementation between soil particles
and densifying the soil structure. The research provides insights into the efficient and eco-friendly treatment and reuse of mucky waste soil produced by earth pressure shield in the Yangtze River Delta.