ZHANG Da-jin, XIAO Gui-yuan, WU Yue, et al. Compression deformation mechanisms of red clay
driven by heavy metal Cu[J]. 2023, 44(S1): 127-133.DOI: 10.16285/j.rsm.2022.0536.
采用浓度为0、2.5、5.0、10.0 g/L的CuSO溶液配制污染土,开展固结试验、热分析试验和扫描电镜(scanning electron microscopy,简称SEM)试验,分析红黏土受重金属Cu+污染后的压缩变形特性机制。结果表明:红黏土的压缩系数和总压缩变形量的变化与土中孔隙水(自由水、弱结合水、强结合水)含量的变化趋势相同,都随着Cu+浓度的增加呈现先降低后升高的趋势。黏土中土颗粒之间的结构连结主要以吸附水膜接触为主,Cu+改变了土中孔隙水的水膜厚度,导致孔隙水的含量发生变化;水膜变薄,土颗粒间的距离缩短,土体的结构强度越高,土体抵抗压缩变形的能力就越大。随着Cu+浓度的增加,土体微观结构由松散的块状、片状单元体逐渐演化为面-面接触的叠聚体;当Cu+浓度增至10.0 g/L,开始出现鳞片状的单元体,单元体间的接触方式以点-点接触和边-面接触为主,土颗粒间的凝聚力变差,土体结构稳定性降低。
Abstract
To investigate mechanism of compressive deformation of red clay contaminated by heavy metal Cu+
CuSO solutions with concentrations of 0
2.5
5.0
and 10.0 g/L were used to prepare the contaminated soil
and consolidation tests
thermal analysis tests
and scanning electron microscopy (SEM) tests were conducted. The results show that the changes of compression coefficient and total compressive deformation of red clay and the changes of pore water (free water
weakly bound water and strongly bound water) content in the clay show the same trend of decreasing first and then increasing with the increase of Cu+ concentration. The structural connection between soil particles in clay soil is mainly based on adsorption water film contact. Cu+ changes the water film thickness of pore water in soil
which leads to the change of pore water content. The water film becomes thinner
the distance between soil particles shortens
the higher the structural strength of soil body
and the greater the ability of soil body to resist compression deformation. With the increase of Cu+ concentration
the microstructure of soil body gradually evolves from loose block-like and flaky units to stacked aggregates with face-to-face contact. When the concentration of Cu+ increases to 10.0 g/L
scale-like units start to appear
the contact mode between units is mainly point-point contact and edge-face contact
the cohesion between soil particles becomes poor
and the structural stability of soil body decreases.