长安大学 公路学院,陕西,西安,710064
网络首发:2022-04-30,
纸质出版:2022
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陈锐, 张星, 郝若愚, 等. 干湿循环下地聚合物固化黄土强度劣化机制与模型研究[J]. 岩土力学, 2022,43(5):1164-1174.
CHEN Rui, ZHANG Xing, HAO Ruo-yu, et al. Shear strength deterioration of geopolymer stabilized loess under wet-dry cycles: mechanisms and prediction model[J]. 2022, 43(5): 1164-1174.
陈锐, 张星, 郝若愚, 等. 干湿循环下地聚合物固化黄土强度劣化机制与模型研究[J]. 岩土力学, 2022,43(5):1164-1174. DOI: 10.16285/j.rsm.2021.1355.
CHEN Rui, ZHANG Xing, HAO Ruo-yu, et al. Shear strength deterioration of geopolymer stabilized loess under wet-dry cycles: mechanisms and prediction model[J]. 2022, 43(5): 1164-1174. DOI: 10.16285/j.rsm.2021.1355.
采用地聚合物对黄土进行固化处理,通过三轴试验研究了干湿循环下不同掺量地聚合物固化黄土抗剪强度的劣化规律,提出了固化土强度劣化的经验公式。结合X射线衍射(X-ray diffraction,简称XRD)、电镜扫描(scanning electron microscopy,简称SEM)和压汞(mercury intrusion porosimetry,简称MIP)试验,分析了水化产物、固化土微观形貌演化与孔隙分布,探讨了地聚合物固化黄土的劣化机制。三轴试验结果表明:相较于素土,固化土的抗剪强度随地聚合物掺量增加而显著提高,黏聚力及内摩擦角最高提升260%和43%;固化土抗剪强度与孔隙率 对地聚合物体积含量 的比值 呈幂函数关系;地聚合物可有效提高固化土的抗干湿耐久性,在9次干湿循环后10%和15%的地聚合物固化土抗剪强度仍保持初始强度的75%以上,但5%的地聚合物固化土在干湿作用下劣化明显,经历9次干湿循环后其强度接近素土;干湿循环对固化土峰值偏应力与黏聚力影响较大,对内摩擦角影响较小。综合考虑地聚合物掺量、围压及干湿循环次数的影响,提出了地聚合物固化土强度劣化经验公式并验证了其准确性。XRD、SEM和MIP试验结果表明:地聚合物的主要水化产物是水化硅酸钙(calcium silicate hydrate,简称CSH)和水化硅铝酸钙(calcium aluminosilicate hydrate,简称CASH),其胶结和充填作用增强土体黏聚力并使土体形成致密的微观结构,从而提高固化土的强度;干湿循环使得土体孔隙扩张并产生新裂隙,导致土颗粒间的胶结破坏,进而劣化固化土宏观强度。
The loess was stabilized using geopolymer (GP). Triaxial compression tests were conducted on stabilized loess with varied GP contents subjected to wet-dry cycles. The degradation law of the shear strength of the stabilized loess after varied wet-dry cycles was evaluated and an empirical model for predicting the shear strength was proposed. The chemical composition of the hydration products
the microstructure and pore size distribution of stabilized loess were investigated by X-ray diffraction (XRD)
scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) tests. The degradation mechanisms of GP stabilized loess under wet-dry cycles were discussed based on the experimental results. The experimental results show that compared with untreated soil
the shear strength of stabilized soils is significantly improved with the increasing GP content
i.e. the cohesion and internal friction angle increase by 260% and 43%
respectively. The shear strength of stabilized loess decreases with the increasing ratio of porosity to GP volumetric fraction ( ) in a power function. It indicates that GP stabilization can remarkably improve the durability of loess under wet-dry cycles. The stabilized loess with 10% and 15% GP can maintain over 75% of their original shear strength
but those with 5% GP shows evident deterioration in shear strength after nine wet-dry cycles. The wet-dry cycling has greater impact on the degradation of peak deviatoric stress and cohesion than that of internal friction angle. An empirical model was proposed and validated for predicting the degradation in shear strength of the GP stabilized loess under wet-dry cycles
considering influence of the GP content
confining pressure and the number of wet-dry cycle. The experimental results of XRD
SEM and MIP show that the main hydration products of GP are calcium silicate hydrate (CSH) and calcium aluminosilicate hydrate (CASH)
which fill the soil pores and enhance the bonding between soil particles. Due to this reason
a denser microstructure develops and the cohesion of the stabilized loess increases
which consequently improves the shear strength of the GP stabilized loesses. Moreover
the wet-dry cycle results in the expansion of soil pores and the formation of new fissures
which destructs the bonding between soil particles and reduces the shear strength of the stabilized loess.
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