反应型复合无卤阻燃剂对EVA基复合材料性能的影响

王平; 田洪瑜; 姜越; 周意杨; 程龙恩; 陈龙

doi:10.16105/j.dxdl.1672-6901.20256048

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反应型复合无卤阻燃剂对EVA基复合材料性能的影响

阻燃电缆性能评价及机理研究 | 更新时间：2025-12-08

- 反应型复合无卤阻燃剂对EVA基复合材料性能的影响
- 反应型复合无卤阻燃剂对EVA基复合材料性能的影响
- 电线电缆 2025年第3期页码：10-17
- 作者机构：
  
  1. 安徽建筑大学安徽省先进建筑材料国际联合研究中心
  2. 特种电线电缆国家地方联合工程研究中心
  3. 安徽华菱电缆集团有限公司
- 作者简介：
- 基金信息：
  
  国家自然科学基金（51903002）;安徽省科技重大专项项目（2021e03020008、202103a05020031）;安徽省芜湖市重点研发项目（2022yf27）;安徽省自然科学基金优青项目（2308085Y34）;安徽省高校自然科学杰出青年科研项目（2022AH020024）;安徽建筑大学博士启动基金（2023QDZ23）;安徽高校协同创新项目（GXXT-2023-098、GXXT-2023-040）
- DOI：10.16105/j.dxdl.1672-6901.20256048
  中图分类号： TQ314.248;TB332
- 纸质出版：2025
- 稿件说明：
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王平, 田洪瑜, 姜越, 等. 反应型复合无卤阻燃剂对EVA基复合材料性能的影响[J]. 电线电缆, 2025,(3):10-17.

王平, 田洪瑜, 姜越, et al. 反应型复合无卤阻燃剂对EVA基复合材料性能的影响[J]. 2025, (3): 10-17.
王平, 田洪瑜, 姜越, 等. 反应型复合无卤阻燃剂对EVA基复合材料性能的影响[J]. 电线电缆, 2025,(3):10-17. DOI： 10.16105/j.dxdl.1672-6901.20256048.

王平, 田洪瑜, 姜越, et al. 反应型复合无卤阻燃剂对EVA基复合材料性能的影响[J]. 2025, (3): 10-17. DOI： 10.16105/j.dxdl.1672-6901.20256048.

摘要

将不饱和磷酸酯齐聚物（unsaturated polyester oligomer

UPEO）与无机阻燃剂复配，制备了反应型复合无卤阻燃剂（OP-FRC），通过熔融共混法将其引入乙烯-醋酸乙烯共聚物（ethylene-vinyl acetate copolymer

EVA）基低烟无卤阻燃线缆护套材料中，采用热重分析仪、差示扫描量热仪、平行板流变仪、电子万能试验机、扫描电子显微镜、极限氧指数测定仪等研究UPEO对复合材料结构和性能的影响。结果表明，OP-FRC中UPEO的引入可以改善无机阻燃剂在EVA基体中的分散性，增强两者间的相互作用，促进无机填料网络的形成，并提高分子链段的运动能力，促进基体缠结结构的松弛，从而改善复合材料的耐疲劳性能、热稳定性和结晶能力。当UPEO质量分数为4%时，复合材料的断裂伸长率为215.5%，疲劳寿命为26 354次，极限氧指数为31.5%。

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