聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强

张新宇; 张旗; 李鹏程

doi:10.16056/j.2096-7705.2023.04.018

欢迎来到能源电力期刊网！

English Version 读者登录期刊登录

您当前的位置：

首页 >

文章列表页 >

聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强

研究与探讨 | 更新时间：2026-01-19

- 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强
- 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强
- 能源研究与管理 2023年15卷第4期页码：120-126
- 作者机构：
  
  武汉工程大学材料科学与工程学院
- 作者简介：
- 基金信息：
  
  国家自然科学基金项目（NSFC51903194）;湖北省自然科学基金计划项目（2023AFB781）;武汉工程大学研究生教育创新基金项目（CX2022251）
- DOI：10.16056/j.2096-7705.2023.04.018
  中图分类号： TB34
- 纸质出版：2023
- 稿件说明：
移动端阅览
张新宇, 张旗, 李鹏程. 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强[J]. 能源研究与管理, 2023,15(4):120-126.

张新宇, 张旗, 李鹏程. 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强[J]. 2023, 15(4): 120-126.
张新宇, 张旗, 李鹏程. 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强[J]. 能源研究与管理, 2023,15(4):120-126. DOI： 10.16056/j.2096-7705.2023.04.018.

张新宇, 张旗, 李鹏程. 聚乙烯醇对PEDOT:PSS纤维热电性能和拉伸性能的协同增强[J]. 2023, 15(4): 120-126. DOI： 10.16056/j.2096-7705.2023.04.018.

摘要

聚（3

4-乙烯二氧噻吩）：聚苯乙烯磺酸盐（PEDOT:PSS）纤维通常通过湿法纺丝制得，但其电导率较低，且拉伸性较差，限制了其在可穿戴热电器件中的应用。为提升PEDOT:PSS纤维的导电和拉伸性能，通过在PEDOT:PSS溶液中加入不同质量分数的聚乙烯醇（PVA）制备PEDOT:PSS/PVA复合纤维，研究其导电性能、热电性能和拉伸性能。结果表明，PVA的加入可显著提升复合纤维的导电性，但其塞贝克系数未发生明显变化。当ω(PVA)为9.1%时，复合纤维的电导率最高，可达到257.3 S/cm，其热电功率因子为8.27μW/(m·K2)。同时，复合纤维的断裂伸长率随ω(PVA)增加而增加，而抗拉强度随ω(PVA)增加先增加后减小，在ω(PVA)为33.3%时达到最高。研究表明，PVA可协同增强PEDOT:PSS纤维的热电性能和拉伸性能，在柔性可穿戴设备和智能织物等领域具有较大的应用潜力。

Abstract

关键词

Keywords

references

易英,罗甜,胡康迪,樊李红.聚（3,4-乙撑二氧噻吩）/聚苯乙烯磺酸钠（PEDOT/PSS）水性抗静电分散体稳定性研究[J].涂料工业,2023(10).

罗一凡,岳子静,张墨苇,王莞珏,蒋书涵,丰米宁.中国碳达峰、碳中和能源控制目标及供给侧清洁化进程[J].能源研究与管理,2022(03).

徐超,张旗,李鹏程.离子液体增强PEDOT:PSS薄膜的热电性能[J].能源研究与管理,2022(01).

Xiaojuan Dai,Qing Meng,Fengjiao Zhang,Ye Zou,Chong-an Di,Daoben Zhu.Electronic structure engineering in organic thermoelectric materials[J].Journal of Energy Chemistry,2021(11).

刘祎,张荔.聚3,4-乙烯二氧噻吩:聚苯乙烯磺酸盐基柔性复合热电材料研究进展[J].复合材料学报,2021(02).

林敏,万斌,桂双林,付尹宣,石金明.国内外能源消费现状[J].能源研究与管理,2015(03).

Yang Jiaji,Jia Yanhua,Liu Youfa,Liu Peipei,Wang Yeye,Li Meng,Jiang Fengxing,Lan Xiaoqi,Xu Jingkun.PEDOT:PSS/PVA/Te ternary composite fibers toward flexible thermoelectric generator[J].Composites Communications,2021.

Shi Xiao-Lei,Zou Jin,Chen Zhi-Gang.Advanced Thermoelectric Design: From Materials and Structures to Devices.[J].Chemical reviews,2020.

grid.222754.4, 0000 0001 0840 2678, Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, 02841, Seoul, Korea,grid.91443.3b, 0000 0001 0788 9816, School of Advanced Materials Engineering, Kookmin Univ., Jeongneung-ro 77, Seongbuk-gu, 02707, Seoul, Korea,grid.222754.4, 0000 0001 0840 2678, Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, 02841, Seoul, Korea,grid.222754.4, 0000 0001 0840 2678, Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, 02841, Seoul, Korea,grid.91443.3b, 0000 0001 0788 9816, School of Advanced Materials Engineering, Kookmin Univ., Jeongneung-ro 77, Seongbuk-gu, 02707, Seoul, Korea,grid.222754.4, 0000 0001 0840 2678, Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, 02841, Seoul, Korea,grid.91443.3b, 0000 0001 0788 9816, School of Advanced Materials Engineering, Kookmin Univ., Jeongneung-ro 77, Seongbuk-gu, 02707, Seoul, Korea,grid.222754.4, 0000 0001 0840 2678, Department of Chemistry, College of Science, Korea University, 145 Anam-ro, Seongbuk-gu, 02841, Seoul, Korea.Recent Progress in Organic Thermoelectric Materials and Devices[J].Macromolecular Research,2020.

Qiang Gao,Mingxu Wang,Xinyuan Kang,Chunhong Zhu,Mingqiao Ge.Continuous wet-spinning of flexible and water-stable conductive PEDOT: PSS/PVA composite fibers for wearable sensors[J].Composites Communications,2020.

Key Laboratory of Science and Technology of Eco-Textiles, Ministry of Education, Jiangnan University, 214122, Wuxi, China,College of Textile and Clothing, Jiangnan University, 214122, Wuxi, China,Key Laboratory of Science and Technology of Eco-Textiles, Ministry of Education, Jiangnan University, 214122, Wuxi, China,College of Textile and Clothing, Jiangnan University, 214122, Wuxi, China,Key Laboratory of Science and Technology of Eco-Textiles, Ministry of Education, Jiangnan University, 214122, Wuxi, China,College of Textile and Clothing, Jiangnan University, 214122, Wuxi, China,Key Laboratory of Science and Technology of Eco-Textiles, Ministry of Education, Jiangnan University, 214122, Wuxi, China,College of Textile and Clothing, Jiangnan University, 214122, Wuxi, China.On the mechanism of conductivity enhancement in PEDOT:PSS/PVA blend fiber induced by UV-light irradiation[J].Applied Physics A: Materials Science & Processing,2020.

Ningxuan Wen,Zeng Fan,Shuaitao Yang,Yongpeng Zhao,Tianze Cong,Shihong Xu,Hao Zhang,Jianzhen Wang,Hui Huang,Chengwei Li,Lujun Pan.Highly conductive, ultra-flexible and continuously processable PEDOT:PSS fibers with high thermoelectric properties for wearable energy harvesting[J].Nano Energy,2020.

Xin-yue Wang,Gu-yu Feng,Meng-juan Li,Ming-qiao Ge.Effect of PEDOT:PSS content on structure and properties of PEDOT:PSS/poly(vinyl alcohol) composite fiber[J].Polymer Bulletin,2019.

Kayser Laure V,Lipomi Darren J.Stretchable Conductive Polymers and Composites Based on PEDOT and PEDOT:PSS.[J].Advanced materials (Deerfield Beach, Fla.),2019.

Yanhua Jia,Lanlan Shen,Jing Liu,Weiqiang Zhou,Yukou Du,Jingkun Xu,Congcong Liu,Ge Zhang,Zishan Zhang,Fengxing Jiang.An efficient PEDOT-coated textile for wearable thermoelectric generators and strain sensors[J].Journal of Materials Chemistry C,2019.

Yao Hongyan,Fan Zeng,Cheng Hanlin,Guan Xin,Wang Chen,Sun Kuan,Ouyang Jianyong.Recent Development of Thermoelectric Polymers and Composites.[J].Macromolecular rapid communications,2018.

Lisha Zhang,Shuping Lin,Tao Hua,Baoling Huang,Shiri Liu,Xiaoming Tao.Fiber‐Based Thermoelectric Generators: Materials, Device Structures, Fabrication, Characterization, and Applications[J].Advanced Energy Materials,2018.

Xinyue Wang,Gu-yu Feng,Ming-qiao Ge.Influence of ethylene glycol vapor annealing on structure and property of wet-spun PVA/PEDOT:PSS blend fiber[J].Journal of Materials Science,2017.

Fan Zeng,Du Donghe,Yu Zhimeng,Li Pengcheng,Xia Yijie,Ouyang Jianyong.Significant Enhancement in the Thermoelectric Properties of PEDOT:PSS Films through a Treatment with Organic Solutions of Inorganic Salts.[J].ACS applied materials & interfaces,2016.

grid.454856.e, 0000 0001 1957 6294, Xun Shi and Lidong Chen are at the State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China,grid.454856.e, 0000 0001 1957 6294, Xun Shi and Lidong Chen are at the State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China.Thermoelectric materials step up.[J].Nature materials,2016.

Xinyue Wang,Ming-qiao Ge,Gu-yu Feng.The effects of DMSO on structure and properties of PVA/PEDOT:PSS blended fiber[J].Fibers and Polymers,2015.

Zhang, Li,Deng, Hua,Liu, Siyao,Zhang, Qin,Chen, Feng,Fu, Qiang.Enhanced thermoelectric properties of PEDOT:PSS films via a novel two-step treatment[J].RSC Advances,2015.

Siyao Liu,Hua Deng,Yun Zhao,Shijie Ren,Qiang Fu.The optimization of thermoelectric properties in a PEDOT:PSS thin film through post-treatment[J].RSC Advances,2014.

Xin Li,Yin Liu,Zhenghao Shi,Congju Li,Guangming Chen.Influence of draw ratio on the structure and properties of PEDOT-PSS/PAN composite conductive fibers[J].RSC Advances,2014.

Mohammad Ziabari Seyedin,Joselito M. Razal,Peter C. Innis,Gordon G. Wallace.Strain‐Responsive Polyurethane/PEDOT:PSS Elastomeric Composite Fibers with High Electrical Conductivity[J].Advanced Functional Materials,2014.

Bubnova Olga,Khan Zia Ullah,Malti Abdellah,Braun Slawomir,Fahlman Mats,Berggren Magnus,Crispin Xavier.Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene).[J].Nature materials,2011.

grid.20861.3d, 0000000107068890, Materials Science, California Institute of Technology, 1200 East California Boulevard, 91125, Pasadena, California, USA,grid.20861.3d, 0000000107068890, Materials Science, California Institute of Technology, 1200 East California Boulevard, 91125, Pasadena, California, USA.Complex thermoelectric materials.[J].Nature materials,2008.

A. M. Nardes,M. Kemerink,R. A. J. Janssen,J. A. M. Bastiaansen,N. M. M. Kiggen,B. M. W. Langeveld,A. J. J. M. van Breemen,M. M. de Kok.Microscopic Understanding of the Anisotropic Conductivity of PEDOT:PSS Thin Films[J].Advanced Materials,2007.

Hidenori Okuzaki,Masayoshi Ishihara.Spinning and Characterization of Conducting Microfibers[J].Macromolecular Rapid Communications,2003.

浏览量

237

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据