武汉工程大学材料科学与工程学院
纸质出版:2023
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阚然, 舒永俊, 杨俊锋, 等. 氮化硼负载MOF纳米复合物的制备及其对水性膨胀型防火涂料的性能影响[J]. 能源研究与管理, 2023,15(1):126-133.
阚然, 舒永俊, 杨俊锋, et al. 氮化硼负载MOF纳米复合物的制备及其对水性膨胀型防火涂料的性能影响[J]. 2023, 15(1): 126-133.
阚然, 舒永俊, 杨俊锋, 等. 氮化硼负载MOF纳米复合物的制备及其对水性膨胀型防火涂料的性能影响[J]. 能源研究与管理, 2023,15(1):126-133. DOI: 10.16056/j.2096-7705.2023.01.018.
阚然, 舒永俊, 杨俊锋, et al. 氮化硼负载MOF纳米复合物的制备及其对水性膨胀型防火涂料的性能影响[J]. 2023, 15(1): 126-133. DOI: 10.16056/j.2096-7705.2023.01.018.
为了提高常规膨胀型防火涂料的综合性能,在球磨剥离的氮化硼纳米片(S-BN)表面通过溶液合成法负载金属有机框架(MOF),制备了氮化硼负载2-甲基咪唑锌MOF (ZIF-8)纳米复合物(S-BN@ZIF-8),并采用红外光谱分析、扫描电子显微镜表征了其结构。同时将S-BN@ZIF-8作为协效阻燃剂应用于钢结构水性膨胀型防火涂料中,通过模拟大板燃烧测试、热失重分析、炭层形貌分析、耐水性测试,研究S-BN@ZIF-8协效阻燃剂对防火涂料性能的影响。与其他样品相比,加入质量分数5%S-BN@ZIF-8的涂料样品在防火测试中表现出了最低的背温,且在防水测试中表现出最低的质量损失率。研究表明S-BN@ZIF-8能在涂料中分散均匀,并且能有效提升涂料的防火和防水性能。ZIF-8的催化成碳作用有利于早期炭层的形成,片层氮化硼能有效阻隔涂料与氧气的接触,从而抑制热量的释放。S-BN@ZIF-8产生的“迷宫效应”延长了水分进入涂料的路径。进而提升了涂料的耐水性能。本研究制备的杂化阻燃剂为纳米材料的改性提供了新策略,扩大了其运用。
唐红梅,陈北海,况皓,黎建刚.MOFs基材料催化电解水展望研究[J].能源研究与管理,2022(04).
唐红梅,李琴,黄振雄,邓同辉,詹聪,黎建刚.二氧化铈纳米结构的制备方法研究进展[J].能源研究与管理,2021(03).
黎建刚,李琴,唐红梅,詹聪,邓同辉.MOFs衍生结构在新型二次电池电极材料中的应用[J].能源研究与管理,2021(01).
孙赛武,杨朝晖,曹姣,王玥,童设华.一种在室温下原位合成铜掺杂ZIF-8的方法[J].石化技术,2019(08).
Yin Lian,Gong Kaili,Zhou Keqing,Qian Xiaodong,Shi Congling,Gui Zhou,Qian Lijun.Flame-retardant activity of ternary integrated modified boron nitride nanosheets to epoxy resin[J].Journal of Colloid And Interface Science,2022.
Wang Zhi Guo,Wei Xin,Bai Meng Han,Lei Jun,Xu Ling,Huang Hua Dong,Du Jiguang,Dai Kun,Xu Jia Zhuang,Li Zhong Ming.Green Production of Covalently Functionalized Boron Nitride Nanosheets via Saccharide-Assisted Mechanochemical Exfoliation[J].ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021.
Wang Cheng,Huo Siqi,Liu Shi,Zhang Qi,Liu Zhitian.Exfoliated and functionalized boron nitride nanosheets towards improved fire resistance and water tolerance of intumescent fire retardant coating[J].Journal of Applied Polymer Science,2020.
Farzad Seidi,Maryam Jouyandeh,Mohsen Taghizadeh,Ali Taghizadeh,Henri Vahabi,Sajjad Habibzadeh,Krzysztof Formela,Mohammad Reza Saeb.Metal-Organic Framework (MOF)/Epoxy Coatings: A Review[J].Materials,2020.
Vaishali Sharma,Hardik L. Kagdada,Prafulla K. Jha,Piotr Śpiewak,Krzysztof J. Kurzydłowski.Thermal transport properties of boron nitride based materials: A review[J].Renewable and Sustainable Energy Reviews,2020.
Huifeng Zhang,Man Zhao,Yang Yang,Y.S. Lin.Hydrolysis and condensation of ZIF-8 in water[J].Microporous and Mesoporous Materials,2019.
Chen Shaohua,Xu Runzhang,Liu Jiaman,Zou Xiaolong,Qiu Ling,Kang Feiyu,Liu Bilu,Cheng Hui-Ming.Simultaneous Production and Functionalization of Boron Nitride Nanosheets by Sugar-Assisted Mechanochemical Exfoliation.[J].Advanced materials (Deerfield Beach, Fla.),2019.
Hanan B. Ahmed,Ahmed M. Ramadan,Mohamed A. Nour,Shenouda S. Abd el-Malak,Abd El Aziz Z. Gomaa.Innovative precursor for manufacturing of superior enhancer of intumescence for paint: Thermal insulative coating for steel structures[J].Progress in Organic Coatings,2018.
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Zhitian Liu,Mengqin Dai,Yunfei Zhang,Xiang Gao,Qi Zhang.Preparation and performances of novel waterborne intumescent fire retardant coatings[J].Progress in Organic Coatings,2016.
Ram Kumar,Devraj Raut,Irshad Ahmad,Upadrasta Ramamurty,Tapas Kumar Maji,C. N. R. Rao.Functionality preservation with enhanced mechanical integrity in the nanocomposites of the metal-organic framework, ZIF-8, with BN nanosheets?[J].Materials Horizons,2014.
Farid Alfawakhiri,Mohamed A. Sultan,David H. MacKinnon.Fire Resistance of Loadbearing Steel-Stud Wall Protected with Gypsum Board: A Review[J].Fire Technology,1999(4).
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