MOFs基材料催化电解水展望研究

唐红梅; 陈北海; 况皓; 黎建刚

doi:10.16056/j.2096-7705.2022.04.010

欢迎来到能源电力期刊网！

English Version 读者登录期刊登录

您当前的位置：

首页 >

文章列表页 >

MOFs基材料催化电解水展望研究

综合论述 | 更新时间：2026-01-19

- MOFs基材料催化电解水展望研究
- Prospect Research of MOFs Application on Electrocatalytic Water Splitting
- 能源研究与管理 2022年第4期页码：53-61
- 作者机构：
  
  1. 江西省科学院能源研究所
  2. 江西省碳中和研究中心 3. 江西省碳中和技术创新中心
  3. 中国电子新能源(武汉)研究院有限责任公司
- 作者简介：
- 基金信息：
- DOI：10.16056/j.2096-7705.2022.04.010
  中图分类号： TQ116.21;TQ426
- 纸质出版：2022
- 稿件说明：
移动端阅览
唐红梅, 陈北海, 况皓, 等. MOFs基材料催化电解水展望研究[J]. 能源研究与管理, 2022,(4):53-61.

唐红梅, 陈北海, 况皓, et al. Prospect Research of MOFs Application on Electrocatalytic Water Splitting[J]. 2022, (4): 53-61.
唐红梅, 陈北海, 况皓, 等. MOFs基材料催化电解水展望研究[J]. 能源研究与管理, 2022,(4):53-61. DOI： 10.16056/j.2096-7705.2022.04.010.

唐红梅, 陈北海, 况皓, et al. Prospect Research of MOFs Application on Electrocatalytic Water Splitting[J]. 2022, (4): 53-61. DOI： 10.16056/j.2096-7705.2022.04.010.

摘要

金属-有机框架化合物（metal organic frameworks

MOFs）具有孔隙率高、比表面积大、尺寸可调、易功能化、衍生结构多样性等特点，在催化电解水制氢领域具有广阔应用前景。梳理MOFs的起源、发展历程、结构特点、种类划分以及国内外主要研究团队，归纳MOFs基材料发展所面临的科学技术问题并提出展望，不仅有助于理解MOFs结构与催化电解水之间的“构-效关系”微观作用机制，也为开发新型高效MOFs基催化材料提供科学指导。现阶段，MOFs发展面临精准设计与可控制备困难，催化微观作用机制不明确，大规模量产化工艺不成熟等问题。因此需从MOFs的晶体生长机制及催化应用等方面所涉及的基础理论进行深入研究，并辅助先进材料表征与理论计算技术，指导MOFs基高效电解水催化剂的开发，从而推动低能耗电解水制氢产业的发展。

Abstract

Metal organic frameworks（MOFs） are characterized by high porosity

large specific surface area

adjustable size

easy functionalization

and diverse derivative structures

which shown broad application prospects in the field of water to hydrogen production. Through sorting out the origin

development history

structural characteristics and classification of MOFs

as well as introduction of major research teams around world

and summarize the faced problems by the development of MOFs based materials and put forward their prospects

which not only helpful to understand the "structure-effect relationship" of MOFs catalytic of water

but also provides scientific guidance to develop novated and efficient MOFs. At this stage

to develop MOFs facing the difficulties of precise design and controllable preparation

unclear catalytic mechanism

as well as immature large-scale modulus production process. Therefore

it is necessary to conduct in-depth research on the basic theories involved in the preparation and application of MOFs. It would be significant to guide the precise design and development of high-efficiency MOFs based electrolytic by adopting the assistance of advanced material characterization and chemical computational chemistry technology

which to promote the technology development of low energy consumption catalytic of water to hydrogen production.

关键词

Keywords

references

“碳达峰、碳中和”目标下混氢天然气技术应用前景分析[J]. 邱玥;周苏洋;顾伟;潘光胜;陈晓刚.中国电机工程学报,2022(04)

Sulfur dioxide sensing properties of MOF-derived ZnFe_2O_4 functionalized with reduced graphene oxide at room temperature[J]. Lan-Juan Zhou;Xi-Xi Zhang;Wen-Yuan Zhang.Rare Metals,2021(06)

超声波-光催化脱色和降解染料普施安蓝MX-R协同作用的研究[J]. 黄维佳;江立文.能源研究与管理,2011(03)

Microwave assisted post-synthetic modification of IRMOF-3 and MIL-68-NH2 onto cotton for Fuel purification with computational explanation[J]. Emam Hossam E.;El-Shahat Mahmoud;Taha Mohamed;Abdelhameed Reda M..Surfaces and Interfaces,2022

Large-Scale Production of Hierarchically Porous Metal-Organic Frameworks by a Reflux-Assisted Post-Synthetic Ligand Substitution Strategy.[J]. Cai Guorui;Ma Xing;Kassymova Meruyert;Sun Kang;Ding Meili;Jiang HaiLong.ACS central science,2021(8)

Metal-Organic Frameworks for Electrocatalysis: Catalyst or Precatalyst?[J]. Zheng Weiran;Lee Lawrence Yoon Suk.ACS ENERGY LETTERS,2021(8)

Three-step nucleation of metal-organic framework nanocrystals.[J]. Liu Xiangwen;Chee See Wee;Raj Sanoj;Sawczyk Michal;Král Petr;Mirsaidov Utkur.Proceedings of the National Academy of Sciences of the United States of America,2021(10)

Industrializing metal–organic frameworks: Scalable synthetic means and their transformation into functional materials[J]. Teo Wei Liang;Zhou Weiqiang;Qian Cheng;Zhao Yanli.Materials Today,2021

Docking of Cu(I) and Ag(I) in Metal-Organic Frameworks for Adsorption and Separation of Xenon.[J]. Wang Haoze;Shi Zhaolin;Yang Jingjing;Sun Tu;Rungtaweevoranit Bunyarat;Lyu Hao;Zhang YueBiao;Yaghi Omar M.Angewandte Chemie (International ed. in English),2020

Design of higher valency in covalent organic frameworks.[J]. Gropp Cornelius;Ma Tianqiong;Hanikel Nikita;Yaghi Omar M.Science (New York, N.Y.),2020(6515)

Sequencing of metals in multivariate metal-organic frameworks.[J]. Zhe Ji;Tong Li;Omar M Yaghi.Science,2020(6504)

Kinetically Controlled Reticular Assembly of a Chemically Stable Mesoporous Ni(II)-Pyrazolate Metal-Organic Framework.[J]. He Tao;Huang Zhehao;Yuan Shuai;Lv Xiu-Liang;Kong Xiang-Jing;Zou Xiaodong;Zhou Hong-Cai;Li Jian-Rong.Journal of the American Chemical Society,2020(31)

Metal-Organic Frameworks for Water Harvesting from Air, Anywhere, Anytime.[J]. Xu Wentao;Yaghi Omar M.ACS central science,2020(8)

Lattice Strain Induced by Linker Scission in Metal–Organic Framework Nanosheets for Oxygen Evolution Reaction[J]. Qianqian Ji;Yuan Kong;Chao Wang;Hao Tan;Hengli Duan;Wei Hu;Guinan Li;Ying Lu;Na Li;Yao Wang;Jie Tian;Zeming Qi;Zhihu Sun;Fengchun Hu;Wensheng Yan.ACS Catalysis,2020(10)

Balancing volumetric and gravimetric uptake in highly porous materials for clean energy.[J]. Chen Zhijie;Li Penghao;Anderson Ryther;Wang Xingjie;Zhang Xuan;Robison Lee;Redfern Louis R;Moribe Shinya;Islamoglu Timur;GómezGualdrón Diego A;Yildirim Taner;Stoddart J Fraser;Farha Omar K.Science (New York, N.Y.),2020(6488)

Neutron diffraction structural study of CO 2 binding in mixed-metal CPM-200 metal-organic frameworks.[J ] . Campanella Anthony J;Trump Benjamin A;Gosselin Eric J;Bloch Eric D;Brown Craig M.Chemical communications (Cambridge, England),2020(17)

Hydrophobic Metal-Organic Frameworks: Assessment, Construction, and Diverse Applications.[J]. Xie Lin-Hua;Xu Ming-Ming;Liu Xiao-Min;Zhao Min-Jian;Li Jian-Rong.Advanced science (Weinheim, Baden-Wurttemberg, Germany),2020(4)

Reticulating 1D Ribbons into 2D Covalent Organic Frameworks by Imine and Imide Linkages.[J]. Nguyen Ha L;Gropp Cornelius;Yaghi Omar M.Journal of the American Chemical Society,2020(6)

Ultralong UV/mechano-excited room temperature phosphorescence from purely organic cluster excitons.[J]. Zhang Xuepeng;Du Lili;Zhao Weijun;Zhao Zheng;Xiong Yu;He Xuewen;Gao Peng Fei;Alam Parvej;Wang Can;Li Zhen;Leng Jing;Liu Junxue;Zhou Chuanyao;Lam Jacky W Y;Phillips David Lee;Zhang Guoqing;Tang Ben Zhong.Nature communications,2019(1)

Exposing {001} Crystal Plane on Hexagonal Ni-MOF with Surface-Grown Cross-Linked Mesh-Structures for Electrochemical Energy Storage.[J]. Li Yan;Xu Yuxia;Liu Yong;Pang Huan.Small (Weinheim an der Bergstrasse, Germany),2019(36)

Facile one-pot generation of metal oxide/hydroxide@metal-organic framework composites: highly efficient bifunctional electrocatalysts for overall water splitting.[J]. Zheng Shasha;Guo Xiaotian;Xue Huaiguo;Pan Kunming;Liu Chunsen;Pang Huan.Chemical communications (Cambridge, England),2019(73)

A metal–organic framework for efficient water-based ultra-low-temperature-driven cooling[J]. Dirk Lenzen;Jingjing Zhao;Sebastian-Johannes Ernst;Mohammad Wahiduzzaman;A. Ken Inge;Dominik Fr?hlich;Hongyi Xu;Hans-J?rg Bart;Christoph Janiak;Stefan Henninger;Guillaume Maurin;Xiaodong Zou;Norbert Stock.Nature Communications,2019(1)

Solvent‐Induced Control over Breathing Behavior in Flexible Metal–Organic Frameworks for Natural‐Gas Delivery[J]. Kundu Tanay;Wahiduzzaman Mohammad;Shah Bhuvan B.;Maurin Guillaume;Zhao Dan.Angewandte Chemie,2019(24)

Applications of Metal-Organic-Framework-Derived Carbon Materials.[J]. Yang Wenping;Li Xiaxia;Li Yan;Zhu Rongmei;Pang Huan.Advanced materials (Deerfield Beach, Fla.),2019(6)

Efficient Electrocatalytic Proton Reduction with Carbon Nanotube-Supported Metal-Organic Frameworks.[J]. Micheroni Daniel;Lan Guangxu;Lin Wenbin.Journal of the American Chemical Society,2018(46)

Modulating Electronic Structure of Metal‐Organic Framework for Efficient Electrocatalytic Oxygen Evolution[J]. Ziqian Xue;Yinle Li;Yawei Zhang;Wei Geng;Baoming Jia;Jia Tang;Shixiong Bao;Hai‐Ping Wang;Yanan Fan;Zhang‐wen Wei;Zishou Zhang;Zhuofeng Ke;Guangqin Li;Cheng‐Yong Su.Advanced Energy Materials,2018(29)

Visualization of Anisotropic and Stepwise Piezofluorochromism in an MOF Single Crystal[J]. Cheng-Xia Chen;Zhang-Wen Wei;Ya-Nan Fan;Pei-Yang Su;Ye-Ye Ai;Qian-Feng Qiu;Kai Wu;Shao-Yun Yin;Mei Pan;Cheng-Yong Su.Chem,2018

Nanoparticles of Metal-Organic Frameworks: On the Road to In Vivo Efficacy in Biomedicine.[J]. Simon-Yarza Teresa;Mielcarek Angelika;Couvreur Patrick;Serre Christian.Advanced materials (Deerfield Beach, Fla.),2018(37)

Metal-organic framework derived coralline-like non-precious metal catalyst for highly efficient oxygen reduction reaction[J]. Linlin Chen;Yanyan Li;Ning Xu;Guoan Zhang.Carbon,2018

Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels.[J]. Mochizuki Shuto;Ogiwara Naoki;Takayanagi Masayoshi;Nagaoka Masataka;Kitagawa Susumu;Uemura Takashi.Nature communications,2018(1)

Ordered macro-microporous metal-organic framework single crystals[J]. Kui Shen;Lei Zhang;Xiaodong Chen;Lingmei Liu;Daliang Zhang;Yu Han;Junying Chen;Jilan Long;Rafael Luque;Yingwei Li;Banglin Chen.Science,2018(6372)

Flexible Zirconium MOFs as Bromine‐Nanocontainers for Bromination Reactions under Ambient Conditions[J]. Dr. Jiandong Pang;Shuai Yuan;Dr. Dongying Du;Christina Lollar;Dr. Liangliang Zhang;Dr. Mingyan Wu;Dr. Daqiang Yuan;Prof. Dr. Hong‐Cai Zhou;Prof. Dr. Maochun Hong.Angewandte Chemie,2017(46)

Multifunctional Mo–N/C@MoS2 Electrocatalysts for HER, OER, ORR, and Zn–Air Batteries[J]. Ibrahim Saana Amiinu;Zonghua Pu;Xiaobo Liu;Kwadwo Asare Owusu;Hellen Gabriela Rivera Monestel;Felix Ofori Boakye;Haining Zhang;Shichun Mu.Advanced Functional Materials,2017(44)

Controlling Cooperative CO 2 Adsorption in Diamine-Appended Mg 2 (dobpdc) Metal-Organic Frameworks.[J ] . Siegelman Rebecca L;McDonald Thomas M;Gonzalez Miguel I;Martell Jeffrey D;Milner Phillip J;Mason Jarad A;Berger Adam H;Bhown Abhoyjit S; Long Jeffrey R.Journal of the American Chemical Society,2017(30)

Carbon-Incorporated Nickel-Cobalt Mixed Metal Phosphide Nanoboxes with Enhanced Electrocatalytic Activity for Oxygen Evolution.[J]. He Peilei;Yu Xin-Yao;Lou Xiong Wen David.Angewandte Chemie (International ed. in English),2017(14)

Influence of Surface Adsorption on the Oxygen Evolution Reaction on IrO 2 (110).[J ] . Kuo Ding-Yuan;Kawasaki Jason K;Nelson Jocienne N;Kloppenburg Jan;Hautier Geoffroy;Shen Kyle M;Schlom Darrell G;Suntivich Jin.Journal of the American Chemical Society,2017(9)

The Reaction Mechanism with Free Energy Barriers at Constant Potentials for the Oxygen Evolution Reaction at the IrO(2) (110) Surface.[J]. Ping Yuan;Nielsen Robert J;Goddard William A.Journal of the American Chemical Society,2017(1)

Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution[J]. Shenlong Zhao;Yun Wang;Juncai Dong;Chun-Ting He;Huajie Yin;Pengfei An;Kun Zhao;Xiaofei Zhang;Chao Gao;Lijuan Zhang;Jiawei Lv;Jinxin Wang;Jianqi Zhang;Abdul Muqsit Khattak;Niaz Ali Khan;Zhixiang Wei;Jing Zhang;Shaoqin Liu;Huijun Zhao;Zhiyong Tang.Nature Energy,2016(12)

Chlorin-Based Nanoscale Metal-Organic Framework Systemically Rejects Colorectal Cancers via Synergistic Photodynamic Therapy and Checkpoint Blockade Immunotherapy.[J]. Lu Kuangda;He Chunbai;Guo Nining;Chan Christina;Ni Kaiyuan;Weichselbaum Ralph R;Lin Wenbin.Journal of the American Chemical Society,2016(38)

Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework.[J]. Comito Robert J;Fritzsching Keith J;Sundell Benjamin J;Schmidt-Rohr Klaus;Dinc? Mircea.Journal of the American Chemical Society,2016(32)

High and Reversible Ammonia Uptake in Mesoporous Azolate Metal-Organic Frameworks with Open Mn, Co, and Ni Sites.[J]. Rieth Adam J;Tulchinsky Yuri;Dinc? Mircea.Journal of the American Chemical Society,2016(30)

Postsynthetic Inner-Surface Functionalization of the Highly Stable Zirconium-Based Metal-Organic Framework DUT-67.[J]. Drache Franziska;Bon Volodymyr;Senkovska Irena;Marschelke Claudia;Synytska Alla;Kaskel Stefan.Inorganic chemistry,2016(15)

A cobalt-based hybrid electrocatalyst derived from a carbon nanotube inserted metal-organic framework for efficient water-splitting[J]. Yang, Fulin;Zhao, Pingping;Hua, Xing;Luo, Wei;Cheng, Gongzhen;Xing, Wei;Chen, Shengli.Journal of Materials Chemistry, A. Materials for energy and sustainability,2016(41)

Cooperative electrochemical water oxidation by Zr nodes and Ni-porphyrin linkers of a PCN-224 MOF thin film[J]. Usov, P. M.;Ahrenholtz, S. R.;Maza, W. A.;Stratakes, B.;Epley, C. C.;Kessinger, M. C.;Zhu, J.;Morris, A. J..Journal of Materials Chemistry, A. Materials for energy and sustainability,2016(43)

Chiral Metal-Organic Framework as a Platform for Cooperative Catalysis in Asymmetric Cyanosilylation of Aldehydes[J]. Zhu, Chengfeng;Xia, Qingchun;Chen, Xu;Liu, Yan;Du, Xia;Cui, Yong.ACS catalysis,2016(11)

Core-Shell Upconversion Nanoparticle@Metal-Organic Framework Nanoprobes for Luminescent/Magnetic Dual-Mode Targeted Imaging.[J]. Li Yantao;Tang Jinglong;He Liangcan;Liu Yong;Liu Yaling;Chen Chunying;Tang Zhiyong.Advanced materials (Deerfield Beach, Fla.),2015(27)

Facile synthesis of new, highly efficient SnO2/carbon nitride composite photocatalysts for the hydrogen evolution reaction[J]. Fettkenhauer, Ch.;Clavel, G.;Kailasam, K.;Antoniettia, M.;Dontsova, D..Green chemistry,2015(6)

M2(m-dobdc) (M = Mg, Mn, Fe, Co, Ni) metal-organic frameworks exhibiting increased charge density and enhanced H2 binding at the open metal sites.[J]. Kapelewski Matthew T;Geier Stephen J;Hudson Matthew R;Stück David;Mason Jarad A;Nelson Jocienne N;Xiao Dianne J;Hulvey Zeric;Gilmour Elizabeth;FitzGerald Stephen A;Head-Gordon Martin;Brown Craig M;Long Jeffrey R.Journal of the American Chemical Society,2014(34)

Tuned to Perfection: ironing Out the Defects in Metal-Organic Framework UiO-66[J]. Greig C. Shearer;Sachin Chavan;Jayashree Ethiraj.Chemistry of Materials: A Publication of the American Chemistry Society,2014(14)

High pressure, high temperature electrochemical synthesis of metal-organic frameworks: films of MIL-100 (Fe) and HKUST-1 in different morphologies[J]. Nicolo Campagnol;Tom Van Assche;Tom Boudewijns.Journal of Materials Chemistry, A. Materials for energy and sustainability,2013(19)

Metal-organic framework materials with ultrahigh surface areas: is the sky the limit?[J]. Farha Omar K;Eryazici Ibrahim;Jeong Nak Cheon;Hauser Brad G;Wilmer Christopher E;Sarjeant Amy A;Snurr Randall Q;Nguyen SonBinh T;Yazayd?n A ?zgür;Hupp Joseph T.Journal of the American Chemical Society,2012(36)

Two azolium rings are better than one: A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks[J]. Roberts, J.M.;Farha, O.K.;Sarjeant, A.A.;Hupp, J.T.;Scheidt, K.A..Crystal growth & design,2011(11)

Metal-organic framework MIL-101 for high-resolution gas-chromatographic separation of xylene isomers and ethylbenzene.[J]. Gu Zhi-Yuan;Yan Xiu-Ping.Angewandte Chemie (International ed. in English),2010(8)

Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0[J]. Tranchemontagne David J.;Hunt Joseph R.;Yaghi Omar M..Tetrahedron,2008(36)

High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to Co? Capture[J]. Banerjee Rahul;Phan Anh;Wang Bo;Knobler Carolyn;Furukawa Hiroyasu;O"Keeffe Michael;Yaghi Omar M..Science,2008(5865)

Zeolite A imidazolate frameworks.[J]. Hayashi Hideki;C?té Adrien P;Furukawa Hiroyasu;O'Keeffe Michael;Yaghi Omar M.Nature materials,2007(7)

Supramolecular isomerism in coordination compounds: nanoscale molecular hexagons and chains.[J]. Abourahma Heba;Moulton Brian;Kravtsov Victor;Zaworotko Michael J.Journal of the American Chemical Society,2002(34)

Selective binding and removal of guests in a microporous metal–organic framework[J]. O. M. Yaghi;Guangming Li;Hailian Li.Nature,1995

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据