双乙酰基哌嗪季铵盐Gemini表面活性剂的合成与聚集性能

刘晓; 周良志; 涂伟强; 严习昌; 李鹏程; 姚军龙; 张旗

doi:10.16056/j.2096-7705.2022.01.008

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双乙酰基哌嗪季铵盐Gemini表面活性剂的合成与聚集性能

研究与探讨 | 更新时间：2026-01-19

- 双乙酰基哌嗪季铵盐Gemini表面活性剂的合成与聚集性能
- Synthesis and Aggregation Properties of Diacetyl Piperazine Quaternary Ammonium Salt-Gemini Surfactant
- 能源研究与管理 2022年第1期页码：49-56
- 作者机构：
  
  武汉工程大学材料科学与工程学院
- 作者简介：
- 基金信息：
  
  国家自然科学基金（NSFC51903194）
- DOI：10.16056/j.2096-7705.2022.01.008
  中图分类号： TQ423
- 纸质出版：2022
- 稿件说明：
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刘晓, 周良志, 涂伟强, 等. 双乙酰基哌嗪季铵盐Gemini表面活性剂的合成与聚集性能[J]. 能源研究与管理, 2022,(1):49-56.

刘晓, 周良志, 涂伟强, et al. Synthesis and Aggregation Properties of Diacetyl Piperazine Quaternary Ammonium Salt-Gemini Surfactant[J]. 2022, (1): 49-56.
刘晓, 周良志, 涂伟强, 等. 双乙酰基哌嗪季铵盐Gemini表面活性剂的合成与聚集性能[J]. 能源研究与管理, 2022,(1):49-56. DOI： 10.16056/j.2096-7705.2022.01.008.

刘晓, 周良志, 涂伟强, et al. Synthesis and Aggregation Properties of Diacetyl Piperazine Quaternary Ammonium Salt-Gemini Surfactant[J]. 2022, (1): 49-56. DOI： 10.16056/j.2096-7705.2022.01.008.

摘要

合成新颖的双子(Gemini)表面活性剂一直都是令人着迷的话题，以1

4-(双氯乙酰基)哌嗪(p)为连接基团，长链烷基二甲基叔胺C

(m=12

18)为尾链合成一系列新的季铵盐Gemini表面活性剂C

-p-C

，并通过吊环表面张力法、电导法以及动态光散射(DLS)研究了其在水溶液中的吸附、聚集行为。研究发现：在室温下C

-p-C

随着尾链碳原子数m的增加，临界胶束浓度c

的对数ln c

呈线性下降，平衡表面张力γ

cmc

增加，单分子占有面积A

min

增大；随着温度的升高，不同尾链长度的C

-p-C

临界胶束浓度c

增大，胶束反离子结合度β减小，在测试温度范围C

-p-C

在水溶液中的聚集为自发过程(ΔG

0);2c

浓度的C

-p-C

水溶液中，都有囊泡聚集体形成，且C

-p-C

、C

-p-C

、C

-p-C

和C

-p-C

聚集体溶液中囊泡的水合半径依次递增。C

-p-C

的表面性能和水相聚集形态为其应用提供了理论数据基础。

Abstract

Novel Gemini surfactants are synthesized

which has always been a fascinating topic.A series of new quaternary ammonium Gemini surfactants C

-p-C

were synthesized with 1

4-（dichloroacetyl） piperazine （p

） as the spacer and longchain alkyl dimethyl tertiary amine C

（m=12

18） as the tail chain.The adsorption and aggregation behavior in aqueous solution were studied by conductivity method and dynamic light scattering （DLS）.With the increase of the number of carbon atoms in the tail chain

it is found that the logarithm ln ccm of the critical micelle concentration (c

) decreases linearly at room temperature.With the increase of c

the occupied area of single molecule (A

min

) increases.With the increase of temperature

the c

increases and the degree of counterions binding in micelles （β） decreases of C

-p-C

with different tail chain lengths.The aggregation of C

-p-C

in aqueous solution is a spontaneous process in the test temperature range（ΔG

0）.Vesicle aggregates were formed in C

-p-C

aqueous solutions with twice the concentration of c

and the hydration radius of vesicles in C

-p-C

and C

-p-C

aggregate solutions increase successively.The surface properties and water phase aggregation morphology of C

-p-C

provide a theoretical data basis for its application.

关键词

Keywords

references

新型长链头基季铵盐Gemini表面活性剂的合成及其吸附、聚集行为研究[D]. 张旗.武汉大学,2012

吡咯烷头基季铵盐Gemini表面活性剂的制备及性能研究[D]. 卫婉英.武汉大学,2017

季铵盐型两性双子表面活性剂的合成及应用研究进展[J]. 郭乃妮;王小荣;古元梓;韩一诺;孔裕;荆程程.石油化工,2021(06)

系列咪唑Gemini表面活性剂的合成及应用研究进展[J]. 郭乃妮;韩一诺;孔裕;白哲;徐如意;胡景涛.皮革与化工,2021(02)

含酰胺键的吡啶双子表面活性剂合成及性能[J]. 王丽艳;武江雷;楼慈涵;杨佳;段松言;陈嫚.化学研究与应用,2020(06)

含吡啶杂环氯化铵阳离子表面活性剂的杀菌活性[J]. 李云晴;王丽艳;唐丽;刘家庆;杜昱瀛;吴定成.日用化学工业,2020(05)

咪唑啉型Gemini表面活性剂合成与应用进展[J]. 王汐璆;庄文昌;罗新泽;马亚蕾.河南化工,2020(05)

一种酰胺型Gemini表面活性剂的合成及性能[J]. 蔡永晨;郑华生;许虎君.日用化学工业,2020(03)

哌啶季铵盐双子表面活性剂的合成及聚集行为[J]. 葛一凡;张旗;刘治田.武汉工程大学学报,2017(03)

含哌啶环的阳离子双子表面活性剂的合成及性能研究[J]. 谢益诚;许虎君;刘佳佳;刘凡.日用化学工业,2017(04)

咪唑型Gemini表面活性剂的合成及性能[J]. 何颜艺;张路;姜小明;郝春玲.精细化工,2017(01)

Synthesis, physiochemical properties, and antimicrobial activities of a novel gemini surfactants with biphenyl and multiple amide groups[J]. Liyu Zhang;Lihua Jia;Zhenlong Zhao;Rui Yang;Jinping Wang;Xiangfeng Guo.Colloids and Surfaces A: Physicochemical and Engineering Aspects,2020(prep)

The impact of dissymmetry on the aggregation properties of heterogemini surfactants[J]. Heng Zhang;Jincheng Mao;Jinzhou Zhao;Xiaojiang Yang;Wenlong Zhang;Chon Lin;Chen Wang.Colloids and Surfaces A: Physicochemical and Engineering Aspects,2020(C)

Synthesis and aggregation properties of ethylene glycol ester-based cationic Gemini surfactants[J]. Yanzhen Wen;Xiujuan Ge;Wenchao Gao;Wenlong Wei;Yan Qiao;Honghong Chang.Colloid and Interface Science Communications,2020

Synthesis, surface/interfacial properties, and biological activity of amide-based Gemini cationic surfactants with hydroxyl in the spacer group[J]. Yakui Wang;Yajie Jiang;Tao Geng;Hongbin Ju;Shengfu Duan.Colloids and Surfaces A: Physicochemical and Engi,2019

Self-assembly properties of ultra-long-chain gemini surfactants bearing multiple amide groups with high performance in fracturing fluid application[J]. Chunpeng Yang;Zhaozheng Song;Jingjing Zhao;Zhiyuan Hu;Yuan Zhang;Qingzhe Jiang.Colloids and Surfaces A: Physicochemical and Engi,2017

Rational Design and Synthesis of Carboxylate Gemini Surfactants with an Excellent Aggregate Behavior for Nano-La 2 O 3 Morphology-Controllable Preparation.[J ] . Liao Xueming;Gao Zhinong;Xia Yan;Niu Fei;Zhai Wenzhong.Langmuir : the ACS journal of surfaces and colloids,2017(13)

Hydrophilicity and flexibility of the spacer as critical parameters on the aggregation behavior of long alkyl chain cationic gemini surfactants in aqueous solution[J]. M. Teresa Garcia;Olga Kaczerewska;Isabel Ribosa;Bogumi? Brycki;Paulina Materna;Ma?gorzata Drgas.Journal of Molecular Liquids,2017

Novel Cationic Gemini Surfactants Based on Piperazine: Synthesis, Surface Activity, and Foam Ability[J]. Yue Xin Wang;Yu Qi Cao;Qian Zhang;Qing Meng.Journal of Dispersion Science and Technology,2016(4)

Amplifying the sensitivity of zinc(II) responsive MRI contrast agents by altering water exchange rates.[J]. Yu Jing;Martins André F;Preihs Christian;Clavijo Jordan Veronica;Chirayil Sara;Zhao Piyu;Wu Yunkou;Nasr Khaled;Kiefer Garry E;Sherry A Dean.Journal of the American Chemical Society,2015(44)

Effect of hydrocarbon structure of the headgroup on the thermodynamic properties of micellization of cationic gemini surfactants: An electrical conductivity study[J]. Qi Zhang;Zhinong Gao;Feng Xu;Shuxin Tai.Journal of Colloid And Interface Science,2012(1)

Synthesis and aggregation behavior of a hexameric quaternary ammonium surfactant.[J]. Fan Yaxun;Hou Yanbo;Xiang Junfeng;Yu Defeng;Wu Chunxian;Tian Maozhang;Han Yuchun;Wang Yilin.Langmuir : the ACS journal of surfaces and colloids,2011(17)

Mechanism of cationic surfactant adsorption – Effect of molecular structure and multiple charge[J]. Gra?yna Para;Agnieszka Hamerska-Dudra;Kazimiera Anna Wilk;Piotr Warszyński.Colloids and Surfaces A: Physicochemical and Engineering Aspects,2011(1)

Molecular conformation-controlled vesicle/micelle transition of cationic trimeric surfactants in aqueous solution.[J]. Wu Chunxian;Hou Yanbo;Deng Manli;Huang Xu;Yu Defeng;Xiang Junfeng;Liu Yu;Li Zhibo;Wang Yilin.Langmuir : the ACS journal of surfaces and colloids,2010(11)

Micellization behavior of [C 16 -12-C 16 ], 2Br ? gemini surfactant in binary aqueous-solvent mixtures[J]. Sancheeta Kolay;Kallol K. Ghosh;Pierluigi Quagliotto.Colloids and Surfaces A: Physicochemical and Engineering Aspects,2009(1)

Synthesis and properties of ionic liquid-type Gemini imidazolium surfactants[J]. Mingqi Ao;Guiying Xu;Yanyan Zhu;Yan Bai.Journal of Colloid And Interface Science,2008(2)

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