段卫党, 赵红, 夏聪聪, et al. Removal Effect and Condition Optimization of Low Carbon to Nitrogen Ratio Wastewater by Potassium Ferrate[J]. 2021, (3): 53-57. DOI: 10.16056/j.2096-7705.2021.03.011.
高铁酸钾对低碳氮比废水的去除效果及条件优化
摘要
为探讨一种用于处理低碳氮比(c(C)/c(N))猪场沼液的应急处理方法
采用高铁酸钾(K
2
FeO
4
)这种绿色氧化剂分别从投加量、pH值及温度等3个因素开展对猪场沼液中COD、NH
3
-N和TP的去除研究。结果表明
K
2
FeO
4
对NH
3
-N的去除效果不明显
但能快速有效去除沼液中的COD和TP
且呈现正相关的剂量关系。在400m L猪场沼液中加入0.48 g高铁酸钾形成含有1 200 mg/L K
2
FeO
4
的反应体系
反应120 min后
出水COD和TP质量浓度分别达146.0 mg/L和11.2 mg/L
去除率为49.7%和58.7%;而酸性体系可进一步提升其去除效率
在初始p H值为3.0时
对COD和TP去除率分别提升至92.1%和85.6%
出水质量浓度为23.0 mg/L和3.9 mg/L;而低温条件也更有利于促进该反应的进行。因此
可将K
2
FeO
4
作为去除猪场沼液的一种应急方法予以考虑和应用研究。
Abstract
An emergency treatment method for treating farm biogas slurry with low carbon to nitrogen ratio(c(C)/c(N)) was discussed. Potassium ferrate(K2 FeO4)
a green oxidant
was used to remove COD
NH
3
-N and TP from biogas slurry of pig farms. The removal experiments were carried out from three factors including dosage
pH value and temperature. The experiments results that the removal effect of K
2
FeO
4
on NH
3
-N was not obvious
but K
2
FeO
4
could quickly and effectively remove COD and TP in farm biogas slurry
and showed a positive dose correlation. A reaction system containing 1 200 mg/L K
2
FeO
4
was formed by adding 0.48 g potassium ferrate into 400 m L pig biogas slurry. After 120 min of reaction
the effluent COD and TP mass concentrations reached 146.0 mg/L and 11.2 mg/L
respectively
and the removal rates were 49.7% and58.7%. The acid system can further improve the removal efficiency. When the initial pH value was 3.0
the removal rates of COD and TP were increased to 92.1% and 85.6%
respectively
and the effluent mass concentration was 23.0 mg/L and 3.9 mg/L. And the low temperature condition is more conducive to the reaction. Therefore
K
2
FeO
4
could be considered as an emergency method for removing farm biogas slurry and applied research.