栾超, 廖梦垠, 徐文媛, et al. Research Progress of Catalysts and Membrane Electrode Technology for Direct Methanol Fuel Cell[J]. 2021, (2): 23-29. DOI: 10.16056/j.2096-7705.2021.02.006.
直接甲醇燃料电池所用催化剂和膜电极工艺研究进展
摘要
直接甲醇燃料电池由于其高效的能量转化效率、清洁环保、体积小、重量轻、可低温快速启动等优点
在未来将得到广泛应用。介绍了直接甲醇燃料电池工作原理及核心部件的相关研究进展
包括阳极催化剂、阴极催化剂和膜电极工艺。阐述了电极催化剂的工作原理
并按负载的活性金属组分的不同
对电极催化剂进行分类总结。阳极贵金属基催化剂中
Pt分别与Ru、Co、Fe、Ni的合金催化剂表现出比纯Pt催化剂更优越的性能。阴极贵金属基催化剂中
Pt-Fe体系催化效果较好。研究分析表明
贵金属基合金纳米结构均匀分散与载体上
产生更高的电化学活性表面积和更低的电荷转移电阻
催化剂稳定性与催化活性较大提高。非贵金属基催化剂则是以氧化物及过渡金属为代表取代Pt
展现较好性能
但还存在催化效率不足的问题。膜电极工艺流程较为成熟固定
活化工艺及质子交换膜有待深入研究。
Abstract
Direct methanol fuel cell(DMFC) will be widely used in the future due to its high energy conversion efficiency
clean and environmental protection
small size
light weight
low temperature and fast start-up. The working principle of DMFC and the related research progress of its core components were introduced
including anode catalyst
cathode catalyst and membrane electrode technology. The working principle of electrode catalysts was described. According to the different active metal components
the electrode catalysts were classified and summarized. Among the anode noble metal based catalysts
the alloy catalysts of Pt with Ru
Co
Fe and Ni show better performance than pure Pt. Pt-Fe system is the best one among the cathode noble metal based catalysts. The results show that the noble metal based alloy nanostructures are uniformly dispersed on the support
resulting in higher electrochemically active surface area and lower charge transfer resistance
and the stability and catalytic activity of the catalyst are greatly improved. Non noble metal based catalysts are represented by oxides and transition metals instead of Pt
showing good performance
but there is still the problem of insufficient catalytic efficiency. The membrane electrode process is relatively mature
and the activation process and proton exchange membrane need to be further studied.