黄膑. Radioactive Pollution and Activity Calculation Method in Tantalum Niobium Ore Smelting[J]. 2020, (3): 91-95. DOI: 10.16056/j.2096-7705.2020.03.019.
钽铌矿冶炼中的放射性污染及活度计算方法
摘要
钽铌矿通常伴生有天然放射性元素铀、钍、镭
在其冶炼过程中
会对工作人员产生不同程度的放射性危害
且冶炼后的矿渣如未经处理直接堆放会对周边环境造成放射性危害。综述了钽铌矿冶炼过程中的放射性污染现状
大部分矿渣的放射性活度高于国家标准
属于中低放废渣
废水中残留的部分放射性核素使水体放射性升高
另外氡作为铀、钍的放射性子体
扩散到空气中造成一定的大气放射性污染。对某厂矿的钽铌矿渣进行X射线荧光光谱分析和X射线衍射分析
分析得出矿渣是由多种金属氧化物和放射性元素铀钍组成
金属元素中铁含量最高
铀钍含量相对较高。钽铌矿渣的放射性活度在冶炼后遭到破坏
其活度浓度应该用非平衡情况下的几个特征核素活度共同计算得到。根据各核素的不同衰变性质
在特定衰变时间范围内
对3个放射系在平衡与非平衡状态下的活度进行计算
由衰变链和各核素的半衰期得出
总活度计算公式可简化为某些特定核素活度的相关计算。
Abstract
Tantalum niobium ore is usually associated with natural radioactive elements such as uranium
thorium and radium
in the smelting process
it will cause different degrees of radioactive hazards to workers
if the slag is directly piled up without treatment
it will cause radioactive damage to the surrounding environment. The present situation of radioactive pollution in tantalum niobium smelting process is reviewed. The radioactivity of most of the slag is higher than the national standard
which belongs to low and medium level radioactive waste
the residual radionuclides in the wastewater increase the radioactivity of water
in addition
radon
as the radioactive daughter of uranium and thorium
diffuses into the air will causes certain air radioactive pollution. The tantalum niobium slag was analyzed by X-ray fluorescence spectrometry and X-ray diffraction
it is concluded that the slag is composed of various metal oxides and radioactive elements uranium and thorium
the content of iron is the highest
while that of uranium and thorium is relatively high. The activity of tantalum niobium slag is destroyed after smelting
so the activity concentration should be calculated by the activity of several characteristic nuclides under non-equilibrium condition. According to the different decay properties of each nuclide
within a specific decay time range
Calculating the activities of 3 radiation systems in equilibrium and unbalanced states
from the decay chain and the half-life of each nuclide
the calculation formula of total activity can be simplified to the related calculation of certain specific nuclide activity.