1. 中国矿业大学教育部煤层气资源与成藏过程重点实验室,江苏 徐州 221116中国矿业大学资源与地球科学学院,江苏,徐州,221116
2. 中国矿业大学资源与地球科学学院,江苏 徐州 221116中国石化华东油气分公司,江苏,南京,210000
3. 中国石化华东油气分公司,江苏,南京,210000
[ "吴财芳(1976—),男,博士,教授,主要从事非常规天然气勘探开发研究。地址:江苏省徐州市铜山区大学路1号中国矿业大学南湖校区,邮政编码:221116。E-mail:caifangwu@sina.com" ]
纸质出版:2024
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吴财芳, 高彬, 李清, 等. 气体水合物合成研究进展[J]. 油气藏评价与开发, 2024,14(2):267-276.
WU Caifang, GAO Bin, LI Qing, et al. Research progress of gas hydrate synthesis[J]. Petroleum Reservoir Evaluation and Development, 2024, 14(2): 267-276.
吴财芳, 高彬, 李清, 等. 气体水合物合成研究进展[J]. 油气藏评价与开发, 2024,14(2):267-276. DOI: 10.13809/j.cnki.cn32-1825/te.2024.02.012.
WU Caifang, GAO Bin, LI Qing, et al. Research progress of gas hydrate synthesis[J]. Petroleum Reservoir Evaluation and Development, 2024, 14(2): 267-276. DOI: 10.13809/j.cnki.cn32-1825/te.2024.02.012.
水合物法捕集与封存CO
2
气体可服务于大规模减排的技术需求,加速“碳中和”目标的实现,对应对气候变化具有重要意义。从气体水合物的基本性质、生成机理及模型,多孔介质中水合物合成,水合物合成的分子动力学模拟等方面,综述了前人针对水合物合成领域的研究现状,提出了气体水合物合成过程中存在的科学问题,并对气体水合物的发展及煤系地层CO
2
水合物的封存方向进行了评价。研究认为,CO
2
气体的溶解度是限制准确计算多孔介质中水合物储气量的关键因素;气体水合物的局部结构化(成核)机制复杂,仍需深入研究;高纬度及永久冻土区煤系地层可作为水合物法封存CO
2
气体的地下空间。
The utilization of hydrate-based capture and storage of CO
2
presents a promising avenue for substantial emissions reduction
contributing significantly to achieving carbon neutrality goals and addressing climate change. This paper delves into the foundational aspects of gas hydrates
including their properties
formation mechanisms
and models
as well as hydrate synthesis within porous media and the use of molecular dynamics simulations for understanding hydrate formation. Key challenges identified in the synthesis process of gas hydrates include the limited solubility of CO
2
in porous media
which poses a significant hurdle in precisely determining the storage capacity of CO
2
hydrates. Additionally
the local structural mechanisms
particularly nucleation processes involved in
gas hydrate formation
are highlighted as complex areas that warrant further investigation. The paper also evaluates the potential of coal-bearing strata
especially in high-latitude and permafrost regions
as viable underground repositories for CO
2
storage via hydrate formation. This approach not only offers a method for reducing atmospheric CO
2
levels but also leverages the unique geological characteristics of these regions to enhance the efficiency and stability of CO
2
storage. In summary
while hydrate-based CO
2
capture and storage technologies hold considerable promise for climate change mitigation
addressing the scientific and technical challenges identified in this review is crucial for advancing the field and optimizing the efficacy of this storage method.
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