清华大学深圳国际研究生院,深圳,518055
纸质出版:2025
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范文强, 1, 史梓男, 等. 锂电池热失控气体的逸散及时空分布特性[J]. 高电压技术, 2025,51(6):3010-3020.
FAN Wenqiang, 1, SHI Zinan, et al. Release and Spatiotemporal Evolution Characteristics of Thermal Runaway Gas in Lithium Batteries[J]. 2025, 51(6): 3010-3020.
范文强, 1, 史梓男, 等. 锂电池热失控气体的逸散及时空分布特性[J]. 高电压技术, 2025,51(6):3010-3020. DOI: 10.13336/j.1003-6520.hve.20241674.
FAN Wenqiang, 1, SHI Zinan, et al. Release and Spatiotemporal Evolution Characteristics of Thermal Runaway Gas in Lithium Batteries[J]. 2025, 51(6): 3010-3020. DOI: 10.13336/j.1003-6520.hve.20241674.
热失控气体预警是储能系统的重要安全防线,气体的扩散和分布对热失控预警的有效性至关重要。为研究热失控早期气体的逸散及时空分布特性,通过数值仿真模拟预制舱储能系统内不同位置单个电池发生热失控时H2的逸散规律,并结合实验结果分析舱内气体时空分布特性。研究结果表明:热失控位置由A(电池簇底层中部)变为B(电池簇底层角落)后,仿真及实验中舱内全空间H2传感器响应时刻的差值分别增大15 s、25 s,上、中切面内最大H2体积分数及传感器最大特征值的均值下降,舱内大部分区域的H2稳态体积分数、传感器稳态特征值均下降且稳态体积分数及稳态特征值的差异程度均增大;底部电池产生的气体受其上方模组的阻挡,会造成气体的瞬态逸散行为及稳态分布的空间不对称性;预制舱储能系统中,舱内上部气体传感器不宜布置在角落处,中下部气体传感器不宜布置在过道两端;热失控发生在电池簇底层角落处时的气体探测条件较恶劣,舱内传感器的整体响应效果相对差于电池簇底层中部热失控的情形。研究成果可为储能系统中气体传感器布局方案的设计及优化提供参考
Thermal runaway gas warning is an important safety defense line for energy storage systems
and the diffusion and distribution of gases are crucial to the effectiveness of thermal runaway warning. To study the escape and spatiotemporal distribution characteristics of gases in the early stage of thermal runaway
this paper simulates the escape law of H2 when a single battery in a prefabricated cabin energy storage system experiences thermal runaway at different positions
and analyzes the spatiotemporal distribution characteristics of gas in the cabin based on experimental results. The research results show that
after the thermal runaway position changes from A (middle of the bottom layer of the battery cluster) to B (corner of the bottom layer of the battery cluster)
the difference in response time of H2 sensors in the entire space of the cabin in simulation and experiment increases by 15 s and 25 s
respectively. The average maximum H2 volume fraction and the average maximum characteristic value of sensors in the upper and middle sections of the cabin decrease
the steady-state H2 volume fraction and steady-state characteristic value of sensors in most areas of the cabin decrease
and the difference in steady-state volume fraction and steady-state characteristic value increase. The gas generated by the bottom battery is blocked by the module above it
which can cause spatial asymmetry of gas transient escape behavior and steady-state distribution. In prefabricated cabin energy storage systems
the upper gas sensors inside the cabin should not be arranged in corners
and the middle and lower gas sensors should not be arranged at both ends of the aisle. When thermal runaway occurs in the bottom corner of the battery cluster
the gas detection conditions are more severe
and the overall response effect of the cabin sensors is relatively poor compared to the situation of thermal runaway in the middle of the battery cluster bottom. The research results can provide reference for the design and optimization of gas sensors layout schemes in energy storage systems.
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