1. 输变电装备技术全国重点实验室(重庆大学电气工程学院),重庆,400044
2. 国网江苏省电力有限公司电力科学研究院,南京,211103
纸质出版:2025
移动端阅览
孙魄韬, 杨温清, 司马文霞, 等. 水分诱导固化型自愈微胶囊及其对RTV复合涂料的自修复性能[J]. 高电压技术, 2025,(11):5539-5548.
SUN Potao, YANG Wenqing, SIMA Wenxia, et al. 水分诱导固化型自愈微胶囊及其对RTV复合涂料的自修复性能[J]. 2025, (11): 5539-5548.
孙魄韬, 杨温清, 司马文霞, 等. 水分诱导固化型自愈微胶囊及其对RTV复合涂料的自修复性能[J]. 高电压技术, 2025,(11):5539-5548. DOI: 10.13336/j.1003-6520.hve.20241451.
SUN Potao, YANG Wenqing, SIMA Wenxia, et al. 水分诱导固化型自愈微胶囊及其对RTV复合涂料的自修复性能[J]. 2025, (11): 5539-5548. DOI: 10.13336/j.1003-6520.hve.20241451.
RTV涂料在长期服役过程中承受复杂电气、机械应力,导致材料内产生机械裂纹和电树枝损伤,严重时甚至会诱发绝缘故障。赋予RTV涂料自修复能力是解决上述问题的有效途径,但当前的自修复技术普遍面临体系复杂、触发苛刻等问题,其工业化应用仍面临挑战。该文针对上述问题构筑了水分诱导固化型自愈微胶囊并将其复合在RTV涂料内部,当复合涂料受到损伤时,芯材修复剂可自主流出,其无需催化剂即可与外界水分子发生交联聚合反应实现对损伤的自主修复。对微胶囊及复合涂料进行测试表征,结果表明:所制备的微胶囊形态完整,包覆良好,在180 ℃以下具有热稳定性;当微胶囊掺杂质量分数小于1%时,自修复复合涂料疏水性和附着力无明显下降,具有良好的力学性能且电气性能基本不受影响,能够在保持较好本征性能的同时长期服役,实现对RTV涂料机械/电气损伤的原位、主动、无监督自修复,大幅延长RTV涂料的服役寿命。
RTV coatings are subjected to complex electrical and mechanical stresses during prolonged service
resulting in the generation of mechanical cracks and electrical tree damage within the material
which can potentially lead to insulation failures. Empowering RTV coatings with self-repair capability presents an effective avenue for addressing the aforementioned issues. However
current self-repair technologies commonly encounter challenges such as complex systems and stringent triggering conditions
thereby impeding their industrial application. This study addresses the aforementioned issues by constructing water-induced curing-type self-healing microcapsules and incorporating them into RTV coatings. Upon damage to the composite coating
the core healing agent autonomously flows out. Without the need for a catalyst
the core healing agent undergoes crosslinking polymerization with external water molecules
thereby achieving autonomous repair of the damage. Characterization tests on the microcapsules and composite coatings indicate that the prepared microcapsules exhibit intact morphology and excellent encapsulation
with thermal stability below 180 ℃. When the mass fraction of microcapsules is less than 1%
the self-repairing composite coatings exhibits no significant decrease in hydrophobicity and adhesion
retains good mechanical properties
and its electrical performance remains essentially unaffected. This allows for long-term service while maintaining superior intrinsic properties
enabling in-situ
autonomous
and unsupervised self-repair of mechanical/electrical damages to the RTV coating
thereby significantly extending the service life of the RTV coating.
0
浏览量
0
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621