输配电装备及系统安全与新技术全国重点实验室(重庆大学电气工程学院),重庆,400044
纸质出版:2025
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李晨昕, 黄正勇, 杨森元, 等. 催化剂促进环氧树脂互穿网络动态重组与回收性能[J]. 高电压技术, 2025,51(7):3339-3349.
LI Chenxin, HUANG Zhengyong, YANG Senyuan, et al. Catalyst-promoted Dynamic Restructuring and Recycling Properties of Epoxy Resin Interpenetrating Networks[J]. 2025, 51(7): 3339-3349.
李晨昕, 黄正勇, 杨森元, 等. 催化剂促进环氧树脂互穿网络动态重组与回收性能[J]. 高电压技术, 2025,51(7):3339-3349. DOI: 10.13336/j.1003-6520.hve.20240980.
LI Chenxin, HUANG Zhengyong, YANG Senyuan, et al. Catalyst-promoted Dynamic Restructuring and Recycling Properties of Epoxy Resin Interpenetrating Networks[J]. 2025, 51(7): 3339-3349. DOI: 10.13336/j.1003-6520.hve.20240980.
环氧树脂具有优良的电气绝缘性能、耐热性和机械强度,被广泛应用于电力设备之中,但传统环氧树脂存在难以回收再制造等问题;随着动态键与催化剂的引入,环氧树脂的回收再利用也逐渐可能,然而催化剂的直接引入会影响树脂等材料的的部分性能,同时传统热压回收所需环氧树脂颗粒较小,工业回收成本较高。为此提出一种将TBD与双固化树脂回收颗粒直接复合以增强互穿网络动态重组的方法,保留了环氧树脂本身优异性能,实现良好的大颗粒环氧树脂回收效果,并研究了大粒径回收颗粒在不同热压条件下回收试样的力学和介电性能。结果表明:将TBD与双固化树脂破碎颗粒混合后热压回收可以提升大粒径回收双固化环氧树脂的界面愈合能力且不影响其原始性能。TBD质量分数2%的回收样件弯曲强度恢复至46.0 MPa,性能回复率为51.68%;击穿强度恢复至21.7 kV,性能回复率为66.98%。研究结果表明,该方法能有效解决传统环氧树脂回收难度大成本高的问题。
Epoxy resin has excellent electrical insulation properties
heat resistance
and mechanical strength
and is widely used in electrical equipment
however
it is difficult for the traditional epoxy resin cured to recycle and remanufacture; meanwhile
with the introduction of dynamic bonding and catalysts
epoxy resin recycling is also gradually possible
however
the direct introduction of catalysts will affect the intrinsic properties of the resin and other materials
the traditional hot-pressing recycling of epoxy resin requires the particles required for traditional hot press recycling to be small
and the cost of industrial recycling is high. In this paper
we propose a direct composite of TBD and dual-cured resin recycling particles to enhance the dynamic restructuring of the interpenetrating network
which retains the excellent properties of the epoxy resin itself and achieves a good recycling effect of the epoxy resin in large particles; moreover
we study the mechanical and dielectric properties of the recycled specimens with large-size recycling particles under different hot-pressing conditions. The results show that mixing TBD with crushed particles of dual-cured resin and then hot-pressing the recycled particles can improve the interfacial healing ability of the large-size recycled dual-cured epoxy resin without affecting its original properties. The bending strength of the sample containing 2% TBD was recovered to 46.0 MPa
with a performance recovery rate of 51.68%; the breakdown strength was recovered to 21.7 kV
with a performance recovery rate of 66.98%.Thus the problem of high cost and difficulty of traditional epoxy resin recycling can be effectively solved.
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