Corrosion Failure Risk Zones and Exploration of Temperature-variable Corrosion Mechanism in Typical Material T91 on Steam Side Under Deep Load Cycling of Boilers
CHEN Guoxi, DING Shaoming, LI Yanhui, et al. Corrosion Failure Risk Zones and Exploration of Temperature-variable Corrosion Mechanism in Typical Material T91 on Steam Side Under Deep Load Cycling of Boilers[J]. 2026, 46(14): 5959-5970.
CHEN Guoxi, DING Shaoming, LI Yanhui, et al. Corrosion Failure Risk Zones and Exploration of Temperature-variable Corrosion Mechanism in Typical Material T91 on Steam Side Under Deep Load Cycling of Boilers[J]. 2026, 46(14): 5959-5970.DOI: 10.13334/j.0258-8013.pcsee.251220.
The frequent and deep load cycling of thermal power plant boilers can lead to significant temperature variations in components such as superheaters
thereby increasing the risk of corrosion failure. This necessitates in-depth research to optimize boiler operation and safety. Therefore
in this study
a novel analysis framework combining combustion heat transfer numerical simulations and corrosion experiments is employed to systematically investigate the temperature field fluctuations under different load-cycling conditions
identify high-risk corrosion failure zones
and explore the steam-side corrosion and oxide film spalling characteristics and mechanisms of typical materials such as T91 in corresponding cyclic-variable-temperature supercritical water. The results show that when the boiler load varies between 100% and 30%
the temperature fluctuation in the horizontal section of the outermost pipes of the screen superheater can exceed 100℃
making it a high-risk zone for corrosion failure. Furthermore
steam-side corrosion studies of the typical material T91 in cyclic-variable-temperature supercritical water at 500℃ to 600℃ reveal that
unlike in constant-temperature supercritical water
cracks are more likely to form between the inner and transition layers of the oxide film under cyclic-variable conditions
increasing the risk of film cracking and spallation. Additionally
the transition layer promotes the formation of a non-uniform chromium-rich oxide layer below it
exacerbating substrate damage. The results offers theoretical guidance for material selection and safe operation of boilers.