1.上海电力学院能源与机械工程学院, 上海市 杨浦区 200090
2.上海电气电站环保工程有限公司, 上海市 静安区 201600
3.上海发电环保工程技术研究中心, 上海市 杨浦区 200090
[ "丁红蕾(1968), 女, 博士, 副教授, 主要从事大气污染控制技术的研究, hlding2005@zju.edu.cn" ]
郭得通(1992), 男, 硕士研究生, 主要从事等离子体脱除CO2的研究, 本文通信作者, Email:157881686@qq.com
收稿:2019-01-16,
纸质出版:2019-10
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丁红蕾, 郭得通, 潘卫国, 等. DBD转化CO2的研究现状及进展[J]. 发电技术, 2019,40(5):481-487.
Honglei DING, Detong GUO, Weiguo PAN, et al. Recent Advances of CO2 Conversion Based on DBD[J]. Power Generation Technology, 2019, 40(5): 481-487.
丁红蕾, 郭得通, 潘卫国, 等. DBD转化CO2的研究现状及进展[J]. 发电技术, 2019,40(5):481-487. DOI: 10.12096/j.2096-4528.pgt.19009.
Honglei DING, Detong GUO, Weiguo PAN, et al. Recent Advances of CO2 Conversion Based on DBD[J]. Power Generation Technology, 2019, 40(5): 481-487. DOI: 10.12096/j.2096-4528.pgt.19009.
为了更高效地进行CO
2
的转化利用,许多学者开展了多种CO
2
转化方法的研究。介电阻挡放电(dielectric barrier discharge,DBD)能在低温常压的环境下还原CO
2
,是CO
2
转化利用的重要方法之一。为了设计出更好的DBD反应器、更佳的反应条件和催化剂,总结了近年来DBD转化CO
2
的相关研究。通过分析不同研究中过程参数、稀释性气体和催化剂等因素对CO
2
转化量和能量效率的影响,发现催化剂能大幅度提高DBD转化CO
2
的反应效率,并介绍了DBD中一些常用的催化剂。最后简要分析了此类研究的可能发展趋势。
In order to convert CO
2
more efficiently
many scholars have carried out research on various CO
2
conversion methods. Dielectric barrier discharge (DBD) is one of the important methods of CO
2
conversion and utilization
it can reduce CO
2
under the condition of low temperature and normal pressure. In order to design a better DBD reactor
reaction conditions and catalysts
this paper summarized the researches on CO
2
conversion based on DBD in recent years. The effects of process parameters
diluting gases and catalysts on CO
2
conversion and energy efficiency in different studies were analyzed. It was found that the catalyst can greatly improve the efficiency of CO
2
conversion by DBD
and introduced some commonly used catalysts in DBD. Finally
the possible development trend of CO
2
conversion by DBD was briefly analyzed.
Rogelj J, Den E M, Höhne N, et al.Paris agreement climate proposals need a boost to keep warming well below 2℃[J].Nature, 2016, 534(7609):631-639.
毛健雄.燃煤电站CO 2 减排技术的探讨[J ] .分布式能源, 2017, 2(1):35-43.
Zheng Y, Wen Q, Li F, et al.Energy related CO 2 conversionand utilization:Advanced materials/nanomaterials, reaction mechanisms and technologies[J ] .Nano Energy, 2017, 4:512-539.
孔飞, 王思韬, 马翊洋, 等.等离子体改性对环氧树脂材料表面电荷动态特性的影响[J].广东电力, 2018, 31(8):161-166.
Bogaerts A, Kozak T, van Laer K, et al.Plasma-based conversion of CO 2 :current status and future challenges[J ] .Faraday Discussions, 2015, 183:217-232.
Sergey Y S, Hwaung L, Song H K, et al.The decomposition of CO 2 in glow discharge[J ] .Journal of Chemical Engineering, 2002, 19(4):564-566.
Horvath, G, Skalny J D, Mason N J.FTIR study of decomposition of carbon dioxide in DC corona discharges[J].Journal of Physics D:Applied Physics, 2008, 41(22):207-225
Abramski K M, Colley A D, Baker H J, et al.Power scaling of large area transverse radio frequency discharge CO 2 lasers[J ] .Applied Physics Letters, 1989, 54(19):1833-1835.
Wang W Z, Mei D H, Tu X, et al.Gliding arc plasma for CO 2 conversion:better insights by a combined experimental and modelling approach[J ] .Chemical Engineering Journal, 2017, 330:11-25.
Chen G X, Godfroid T, Britun N, et al.Plasma-catalytic conversion of CO 2 and CO 2 /H 2 O in a surface-wave sustained microwave discharge[J ] .Applied Catalysis B:Environmental, 2017, 214:114-125..
Sadat H, Dubus N, Tatibouet J M.Temperature runaway in a pulsed dielectric barrier discharge reactor[J].Applied Thermal Engineering, 2012, 37:324-328.
Snoeckx R, Bogaerts A.Plasma technology:a novel solution for CO 2 conversion[J ] .Chemical Society Reviews, 2017, 46(19):5805-5863.
Mei D H, Tu X.Conversion of CO 2 in a cylindrical dielectric barrier discharge reactor:effects of plasma processing parameters and reactor design[J ] .Journal of CO 2 Utilization, 2017, 19:68-78..
Ray D, Saha R, Subrahmanyam C.DBD plasma assisted CO 2 decomposition:influence of diluent gases[J ] .Catalysis, 2017, 7(9):244-250.
Wang L, Yi Y H, Guo H C, et al.Atmospheric pressure and room temperature synthesis of methanol through plasma-catalytic hydrogenation of CO 2 [J ] .ACS Catalysis, 2017, 8(1):90-100.
Nunnally T, Gutsol K, Rabinovich A, et al.Dissociation of CO 2 in a low current gliding arc plasmatron[J ] .Journal of Physics D:Applied Physics, 2011, 44(27):274-290.
Fridman A.Plasma Chemistry[M].New York:Cambridge University Press, 2008.
Chen P, Shen J, Ran T C, et al.Investigation of operating parameters on CO 2 splitting by dielectric barrier discharge plasma[J ] .Plasma Science and Technology, 2017, 19(12):123-128.
Snoeckx R, Heijkers S, Wesenbeeck Van K, et al.CO 2 conversion in a dielectric barrier discharge plasma:N 2 in the mix as a helping hand or problematic impurity[J ] .Energy & Environmental Science, 2016, 9(3):999-1011..
Xu S J, Whitehead J C, Martin P A.CO 2 conversion in a non-thermal, barium titanate packed bed plasma reactor:the effect of dilution by Ar and N 2 [J ] .Chemical Engineering Journa l, 2017, 327:764-773..
Zeng Y X, Tu X.Plasma-catalytic hydrogenation of CO 2 for the cogeneration of CO and CH 4 in a dielectric barrier discharge reactor:effect of argon addition[J ] .Journal of Physics D:Applied Physics, 2017, 50(18):184-190..
Mei D H, Zhu X B, He Y L, et al.Plasma-assisted conversion of CO 2 in a dielectric barrier discharge reactor:understanding the effect of packing materials[J ] .Plasma Sources Science & Technology, 2015, 24(1):11-15.
Ray D, Subrahmanyam C.CO 2 decomposition in a packed DBD plasma reactor:influence of packing materials[J ] .RSC Advances, 2016, 6(96):93997-93999.
Tu X, Whitehead J C.Plasma-catalytic dry reforming of methane in an atmospheric dielectric barrier discharge:understanding the synergistic effect at low temperature[J].Applied Catalysis B:Environmental, 2012, 125:439-448.
Kattel S, Yan B H, Chen J G, et al.CO 2 hydrogenation on Pt, Pt/SiO 2 and Pt/TiO 2 :importance of synergy between Pt and oxide support[J ] .Journal of Catalysis, 2016, 343:115-126..
Li K, Yin C, Zheng Y, et al.DFT Study on the methane synthesis from syngas on a Cerium-Doped Ni (111) surface[J].Journal of Physical Chemistry C, 2016, 120(40):23030-23043.
Choe S J, Kang H J, Kim S J, et al.Adsorbed carbon formation and carbon hydrogenation for CO 2 methanation on the Ni (111) surface:ASED-MO study[J ] .Bulletin of the Korean Chemical Society, 2005, 26(11):1682-1688.
Zeng Y X, Zhu X B, Mei D H, et al.Plasma-catalytic dry reforming of methane over γ-Al 2 O 3 supported metal catalysts[J ] .Catalysis Today, 2015, 256:80-87..
黄秋实.Ni基催化剂与等离子体协同作用下的CO 2 甲烷化[D ] .大连: 大连理工大学, 2017.
杨志强.低温等离子体协同催化CO 2 甲烷化反应研究[D ] .大连: 大连理工大学, 2014.
Zeng Y X, Tu X.Plasma-catalytic CO 2 hydrogenation at low temperatures[J ] .IEEE Transactions on Plasma Science, 2016, 44(4):405-411.
Falbo L, Martinelli M, Visconti C G, et al. Kinetics of CO 2 methanation on a Ru-based catalyst at process conditions relevant for power-to-gas applications[J ] .Applied Catalysis B:Environmental, 2018, 225:354-363.
Garbarino G, Bellotti D, Finocchio E, et al.Meth-anation of carbon dioxide on Ru/Al 2 O 3 :catalytic activity and infrared study[J ] .Catalysis Today, 2016, 277:21-28..
Mebrahtu C, Abate S, Perathoner S, et al.CO 2 methanation over Ni catalysts based on ternary and quaternary mixed oxide:a comparison and analysis of the structure-activity relationships[J ] .Catalysis Today, 2018, 304:181-189.
Lim Y G, McGregor J, Sederman A J, et al.Kinetic studies of CO 2 methanation over a Ni/γ-Al 2 O 3 catalyst using a batch reactor[J ] .Chemical Engineering Science, 2016, 141:28-45..
Ocampo F, Louis B, Roger A C, et al.Methanation of carbon dioxide over nickel-based Ce 0.72 Zr 0.28 O 2 mixed oxide catalysts prepared by sol-gel method[J ] .Applied Catalysis A:General, 2009, 369:90-96..
Le A T, Kim S M, Lee S H, et al.CO and CO 2 methanation over supported Ni catalysts[J ] Catalysi s Today, 2017, 293/294:89-96.
Jwa E, Lee S B, Lee H W, et al.Plasma-assisted catalytic methanation of CO and CO 2 over Ni-zeolite catalysts[J ] .Fuel Processing Technology, 2013, 108(6):89-93.
Mei D H, Zhu X B, Wu C F, et al.Plasma-photocatalytic conversion of CO 2 at low temperatures:understanding the synergistic effect of plasma-catalysis[J ] .Applied Catalysis B:Environmental, 2016, 182:525-532.
Ahmad W, Younis M N, Shawabkeh R, et al.Synthesis of lanthanide series (La, Ce, Pr, Eu & Gd) promoted Ni/γ-Al 2 O 3 catalysts for methanation of CO 2 at low temperature under atmospheric pressure[J ] .Catalysis Communications, 2017, 100:121-126..
张丽.等离子体和助剂改性镍基催化剂二氧化碳甲烷化研究[D].天津: 天津大学, 2015.
Mihet M, Lazar M D.Methanation of CO 2 on Ni/-Al 2 O 3 :influence of Pt, Pd or Rh promotion[J ] .Catalysis Today, 2016, 304:286-290..
Liu Q, Gu F N, Gao J J, et al.Ni/Al 2 O 3 -ZrO 2 catalyst for CO 2 methanation:the role of γ-(Al, Zr) 2 O 3 formation[J ] .Catalysis Today, 2018, 306:294-299..
Lim J Y, McGregor G, Sederman A J, et al.The role of the Boudouard and water-gas shift reactions in the methanation of CO or CO 2 over Ni/γ-Al 2 O 3 catalyst[J ] .Chemical Engineering Science, 2016, 152:754-766..
Mebrahtu C, Abate S, Chen S M, et al.Enhanced catalytic activity of Fe-promoted Ni over γ-Al 2 O 3 nanosheets for CO 2 methanation[J ] .Energy Technology, 2017, 6(6):1196-1207..
Benrabbah R, Cavaniol C, Liu H, et al.Plasma DBD activated ceria-zirconia-promoted Ni-catalysts for plasma catalytic CO 2 hydrogenation at low temperature[J ] .Catalysis Communications, 2017, 89:73-76.
Nizio M, Albarazi A, Cavadias S, et al.Hybrid plasma-catalytic methanation of CO 2 at low temperature over ceria zirconia supported Ni catalysts[J ] .International Journal of Hydrogen Energy, 2016, 41(27):11584-11592.
聂望欣, 邹秀晶, 汪学广, 等.介孔γ-Al 2 O 3 负载的高分散Ni-Ce-Zr氧化物的制备及其二氧化碳甲烷化研究(英文)[J ] .物理化学学报, 2016, 32(11):2803-2810..
Bie C D, Dijk J V, Bogaerts A.CO 2 hydrogenation in a dielectric barrier discharge plasma revealed[J ] .Journal of Physical Chemistry C, 2016, 120(44):1123-1129.
Studt F, Behrens M, Kunkes E L, et al.The mechanism of CO and CO 2 hydrogenation to methanol over Cu-based catalysts[J ] .Chem Cat Chem, 2015, 44(27):182-190.
Eliasson B, Kogelschatz U, Xue B, et al.Hydroge-nation of carbon dioxide to methanol with a discharge-activated catalyst[J].Industrial&Engineering Chemistry Research, 1998, 37(8):3350-3357.
Bradford M C J, Vannice M A.CO 2 reforming of CH 4 [J ] .Catalysis Reviews, 2007, 41(1):1-42..
Bie C D, Dijk J V, Bogaerts A.The dominant pathways for the conversion of methane into oxygenates and syngas in an atmospheric pressure dielectric barrier discharge[J].Journal of Physical Chemistry C, 2015, 119(39):22331-22350.
Zeng Y X, Wang L, Wu C F, et al.Low temperature reforming of biogas over K-, Mg-and Ce-promoted Ni/Al 2 O 3 catalysts for the production of hydrogen rich syngas:understanding the plasma-catalytic synergy[J ] .Applied Catalysis B:Environmental, 2018, 224:469-478..
Amin M H, Putla S, Hamid S B, et al.Understanding the role of lanthanide promoters on the structure:activity of nanosized Ni/-Al 2 O 3 catalysts in carbon dioxide reforming of methane[J ] .Applied Catalysis A:General, 2015, 492:160-168..
Pham M H, Goujard V, Tatibouët J M, et al.Activation of methane and carbon dioxide in dielectric-barrier discharge-plasma reactor to produce hydrocarbons-influence of La 2 O 3 /γ-Al 2 O 3 catalyst[J ] .Catalysis Today, 2011, 171:67-71..
Ray D, Reddy P M K, Subrahmanyam C.Ni-Mn/γ-Al 2 O 3 assisted plasma dry reforming of methane[J ] .Catalysis Today, 2017, 309:212-218..
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