气相色谱–离子迁移谱检测畜禽有机废物堆肥中的挥发性硫化合物

段腾飞; 左林子; 张立新; 许燕滨

doi:10.12052/gdutxb.230197

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气相色谱–离子迁移谱检测畜禽有机废物堆肥中的挥发性硫化合物

环境科学与工程 | 更新时间：2026-05-27

- 气相色谱–离子迁移谱检测畜禽有机废物堆肥中的挥发性硫化合物
- Determination of Volatile Sulfur Compounds in Livestock Waste Compost by Gas Chromatography-ion Mobility Spectrometry
- 广东工业大学学报 2024年41卷第5期页码：66-71
- 作者机构：
  
  1. 广东工业大学环境科学与工程学院,广东,广州,510006
  2. 广东工业大学分析测试中心,广东,广州,510006
  3. 山东海能科学仪器有限公司,山东,德州,251500
- 作者简介：
  
  段腾飞(1995–)，男，硕士研究生，主要研究方向为畜禽养殖固废处理技术，E-mail：1826577375@qq.com
  左林子(1987–)，女，实验师，博士，主要研究方向为有机气相质谱类分析，E-mail：zuolz@gdut.edu.cn
- 基金信息：
  
  广东省联合基金重点项目(2019B1515210033);广州市科技计划项目(202102021066)
- DOI：10.12052/gdutxb.230197
  中图分类号： X831
- 纸质出版：2024
- 稿件说明：
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段腾飞, 左林子, 张立新, 许燕滨. 气相色谱–离子迁移谱检测畜禽有机废物堆肥中的挥发性硫化合物[J]. 广东工业大学学报, 2024, 41(5): 66-71.

Duan Teng-fei, Zuo Lin-zi, Zhang Li-xin, et al. Determination of Volatile Sulfur Compounds in Livestock Waste Compost by Gas Chromatography-ion Mobility Spectrometry[J]. 2024, 41(5): 66-71.
段腾飞, 左林子, 张立新, 许燕滨. 气相色谱–离子迁移谱检测畜禽有机废物堆肥中的挥发性硫化合物[J]. 广东工业大学学报, 2024, 41(5): 66-71. DOI： 10.12052/gdutxb.230197.

Duan Teng-fei, Zuo Lin-zi, Zhang Li-xin, et al. Determination of Volatile Sulfur Compounds in Livestock Waste Compost by Gas Chromatography-ion Mobility Spectrometry[J]. 2024, 41(5): 66-71. DOI： 10.12052/gdutxb.230197.

摘要

采用气相色谱–离子迁移谱技术，建立了检测畜禽有机废物堆肥中挥发性硫化合物–甲硫醚、乙硫醚、二甲基二硫醚和二硫化碳的方法。样品经除氨后用采气袋收集，经MXT-1气相色谱填充柱分离，采用正、负两种模式，在优化的载气流量和系统温度条件下进行检测。结果表明，4种挥发性硫化合物在各自线性范围内均表现出良好的线性关系(

0.99)；检出限为0.008~0.097 mg/m

，回收率为85%~116%，相对标准偏差(Relative Standard Deviation，RSD)为1.13%~8.42%。该方法无需浓缩富集等预处理，仅采用气袋就可完成堆肥恶臭气体的收集，检测灵敏、响应快速，可用于堆肥气体中挥发性硫化合物的现场监测。

Abstract

A method for determination of volatile sulfur compounds-dimethyl sulfide

diethyl sulfide

dimethyl disulfide

and carbon disulfide in livestock waste compost was established using gas chromatography–ion mobility spectroscopy technology. The sample was collected using a gas sampling bag after ammonia removal

separated on a packed gas chromatography column of MXT-1

and detected in both positive and negative modes under the optimized experimental conditions. The results showed that the four sulfur compounds represented good linearity (

0.99) in their respective linear ranges; the detection

limits were 0.008~0.097 mg/m

with recoveries of 85%~116% and relative standard deviation (RSD) of 1.13%~8.42%. The method is free of pretreatment such as pre-concentration or enrichment

sensitive and rapid

and the collection of odorous composting gas can be conducted using a gas sampling bag. The method is sensitive and rapid

which can be used for on-site monitoring of volatile sulfur in compost gas.

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Keywords

references

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