海水提铀技术研究进展与挑战

蓝芳芳; 李贤辉; 杨阳

doi:10.12052/gdutxb.230146

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

海水提铀技术研究进展与挑战

生态环境 | 更新时间：2026-05-27

- 海水提铀技术研究进展与挑战
- Seawater Uranium Extraction: Progress and Challenges
- 广东工业大学学报 2023年40卷第6期页码：139-146
- 作者机构：
  
  1. 广东工业大学生态环境与资源学院,广东,广州,510006
  2. 南方海洋科学与工程广东省实验室(广州) 滨海与深海生态环境研究中心,广东,广州,511458
- 作者简介：
  
  蓝芳芳(2000–) ，女，硕士研究生，主要研究方向为海水提铀材料的制备与表征
  李贤辉(1986–)，男，教授，博士，主要研究方向为膜法水处理技术，E-mail：lixianhui@gdut.edu.cn
  杨阳(1986–)，女，研究员，博士，主要研究方向为功能纳米膜材料，E-mail：yang_yang@gmlab.ac.cn
- 基金信息：
  
  广东省粤港科技创新联合资助项目(2021A0505110013);国家重点研发计划项目(2021YFC3201401);“珠江人才计划”引进创新创业团队(2019ZT08L213)
- DOI：10.12052/gdutxb.230146
  中图分类号： P746;TB34
- 网络首发：2023-11-25，
  
  纸质出版：2023
- 稿件说明：
移动端阅览
蓝芳芳, 李贤辉, 杨阳. 海水提铀技术研究进展与挑战[J]. 广东工业大学学报, 2023, 40(6): 139-146.

Lan Fang-fang, Li Xian-hui, Yang Yang. Seawater Uranium Extraction: Progress and Challenges[J]. 2023, 40(6): 139-146.
蓝芳芳, 李贤辉, 杨阳. 海水提铀技术研究进展与挑战[J]. 广东工业大学学报, 2023, 40(6): 139-146. DOI： 10.12052/gdutxb.230146.

Lan Fang-fang, Li Xian-hui, Yang Yang. Seawater Uranium Extraction: Progress and Challenges[J]. 2023, 40(6): 139-146. DOI： 10.12052/gdutxb.230146.

摘要

铀资源作为核燃料中关键的组成成分，对于保障我国核工业建设和可持续发展至关重要。然而，常规陆地铀资源面临着可开采铀矿相对贫乏、品位较低的问题，而海水铀资源储量却是陆地的近千倍，且我国海域辽阔、海水资源富足。因此，如何能高效地从海水中提取铀资源，进而满足我国核工业发展需求，是亟待探究和解决的重要科学问题。本文系统介绍了国内外海水提铀技术的发展现状，综述了海水提铀材料特别是当前最具发展前景的铀吸附材料的研究概况，并以材料设计和工程应用为切入点，阐晰了海水提铀技术的主要挑战和未来发展展望。

Abstract

As a key component of nuclear fuel

uranium resources are crucial to ensuring the construction and sustainable development of our country's nuclear industry. However

conventional terrestrial uranium resources are facing the challenges of relatively poor and low-grade mineable uranium ore. In contrast

seawater uranium resource reserves are nearly a thousand times that of land

and China owns vast sea areas and is rich in seawater resources. Therefore

how to efficiently extract uranium resources from seawater to meet the development needs of nuclear industry in China is an important scientific issue that needs to be explored and solved urgently. The development status of seawater uranium extraction technology is systematically introduced

the research progress of the uranium extraction materials especially the most promising adsorption materials summarized

taking material design and engineering application as the key points to clarify the main challenges and future development prospects of seawater uranium extraction technology.

关键词

Keywords

references

WANG S J, YUAN P, LI D, et al . An overview of ocean renewable energy in China [J ] . Renewable and Sustainable Energy Reviews, 2011, 15(1): 91-111.

LIU C Z, RAO Z H. Challenges in various thermal energy storage technologies [J]. Science Bulletin, 2017, 62(4): 231-233.

PIECHOWICZ M, ABNEY C W, ZHOU X, et al . Design, synthesis, and characterization of a bifunctional chelator with ultrahigh capacity for uranium uptake from seawater simulant [J ] . Industrial Engineering Chemistry Research, 2016, 55(15): 4170-4178.

ENDRIZZI F, LEGGETT C J, RAO L F. Scientific basis for efficient extraction of uranium from seawater. I: understanding the chemical speciation of uranium under seawater conditions [J]. Industrial Engineering Chemistry Research, 2016, 55(15): 4249-4256.

DONIA A M, ATIA A A, MOUSSA E M, et al . Removal of uranium(VI) from aqueous solutions using glycidyl methacrylate chelating resins [J ] . Hydrometallurgy, 2009, 95(3-4): 183-189.

LIU A P, ZHONG Z C. Geochemical characteristics of uranium and the application to oil gas exploration [J]. Acta Petrolei Sinica, 1999, 20(6): 32-37.

WANG Y, WANG J J, WANG J, et al . Efficient recovery of uranium from saline lake brine through photocatalytic reduction [J ] . Journal of Molecular Liquids, 2020, 308: 113007.

KRAKOWSKI R A. Presentations of the international conference on preparing the ground for renewal of nuclear power[M]// KURSUNOGLU B N, MINTZ S L, PERLMUTTER A, et al. Preparing the Ground for Renewal of Nuclear Power. Boston : Springer, 1999: 167-193.

The Nuclear Energy Agency and the International Atomic Energy Agency. Uranium 2020: resources, production and demand [J]. Ux Weekly, 2021, 35(2): 1-4.

XIONG J, WEN J, HU S, et al . Progress in extraction uranium from seawater of China [J ] . Journal of Nuclear and Radiochemistry, 2015, 37(5): 257-265.

LI H, WEN J, WANG X L. Research advances on extracting uranium from seawater in China [J]. Chinese Science Bulletin, 2018, 63(Z1): 481-494.

CHEN S S, REN Y, DING H Y, et al . Research progress of extraction uranium from seawater [J ] . Atomic Energy Science and Technology, 2015, 49(3): 415-423.

DAVIES R V, KENNEDY J, MCILROY R W, et al . Extraction of uranium from sea water [J ] . Nature, 1964, 203(4950): 1110-1115.

FENG J, HE G Q, WEI Y X, et al . Research progress on adsorption material for U extraction from seawater [J ] . New Chemical Materials, 2022, 50(3): 1-7.

TUREKIAN K K, HOLLAND H D. Treatise on geochemistry[M]. Amsterdam: Elsevier Science, 2003.

TIAN G X, TEAT S J, ZHANG Z Y, et al . Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime [J ] . Dalton Transactions, 2012, 41(38): 11579-11586.

KIM J, OYOLA Y, TSOURIS C, et al . Characterization of uranium uptake kinetics from seawater in batch and flow-through experiments [J ] . Industrial Engineering Chemistry Research, 2013, 52(27): 9433-9440.

DRYSDALE J A, BUESSEIER K O. Uranium adsorption behaviour of amidoximated fibers under coastal ocean conditions [J]. Progress in Nuclear Energy, 2020, 119: 103170.

HU J T, MA H J, XING Z, et al . Preparation of amidoximated ultrahigh molecular weight polyethylene fiber by radiation grafting and uranium adsorption test [J ] . Industrial Engineering Chemistry Research, 2016, 55(15): 4118-4124.

BAI Z, LIU Q, ZHANG H, et al . Anti-biofouling and water—stable balanced charged metal organic framework-based polyelectrolyte hydrogels for extracting uranium from seawater [J ] . ACS Applied Materials Interfaces, 2020, 12(15): 18012-18022.

MA D, XU X, LI Z, et al . Nano emulsion assembly toward vaterite mesoporous CaCO3 for high-efficient uranium extraction from seawater [J ] . Journal of Hazardous Materials, 2022, 432: 128695.

LIU M X, DONG F Q, YAN X Y, et al . Biosorption of uranium by saccharomyces cerevisiae and surface interactions under culture conditions [J ] . Bioresource Technology, 2010, 101(22): 8573-8580.

FENG M L, SARMA D, QI X H, et al . Efficient removal and recovery of uranium by a layered organic-inorganic hybrid thiostannate [J ] . Journal of the American Chemical Society, 2016, 138(38): 12578-12585.

LEE S, KANG U, PIAO G, et al . Homogeneous photoconversion of seawater uranium using copper and iron mixed-oxide semiconductor electrodes [J ] . Applied Catalysis B:Environmental, 2017, 207: 35-41.

SODAYE H, NISAN S, POLETIKO C, et al . Extraction of uranium from the concentrated brine rejected by integrated nuclear desalination plants [J ] . Desalination, 2009, 235(1-3): 9-32.

WANG Y, ZHANG Y, LI Q, et al . Amidoximated cellulose fiber membrane for uranium extraction from simulated seawater [J ] . Carbohydrate Polymers, 2020, 245: 116627.

BAI Z Y, XU H B, WANG J, et al . New development of uranium extraction from sea water [J ] . Journal of Natural Science of Heilongjiang University, 2020, 37(1): 61-70.

JIN K Y, YU S C, GAO C J. Present situation of uranium recovery from seawater [J]. Marine Science Bulletin, 2001, 20(2): 78-82.

WANG Y, LI Q, CAO L X, et al . Progress of biomass-based materials for uranium adsorption [J ] . CIESC Journal, 2021, 72(3): 1205-1216.

YAMASHITA H, OZAWA Y, NAKAJIMA F, et al . The collection of uranium from sea water with hydrous metal oxide. II. The mechanism of uranium adsorption on hydrous titanium (IV) oxide [J ] . Bulletin of the Chemical Society of Japan, 1980, 53(1): 1-5.

LI X Y, ZHANG M, LIU Y B, et al . Removal of U(VI) in aqueous solution by nanoscale zero-valent iron(nZVI) [J ] . Water Quality, Exposure and Health, 2013, 5(1): 31-40.

DONG Z, ZHANG Z, ZHOU R. Construction of oxidized millimeter-sized hierarchically porous carbon spheres for U(VI) adsorption [J]. Chemical Engineering Journal, 2020, 386: 123944.

GIANNAKOUDAKIS D A, ANASTOPOULOS I, BARCZAK M, et al . Enhanced uranium removal from acidic wastewater by phosphonate-functionalized ordered mesoporous silica: Surface chemistry matters the most [J ] . Journal of Hazardous Materials, 2021, 413: 125279.

AHMAD M, WANG J Q, YANG Z T, et al . Ultrasonic-assisted preparation of amidoxime functionalized silica framework via oil-water emulsion method for selective uranium adsorption [J ] . Chemical Engineering Journal, 2020, 389: 124441.

WANG Y Q, ZHANG Z B, LIU Y H, et al . Adsorption of U(VI) from aqueous solution by the carboxyl-mesoporous carbon [J ] . Chemical Engineering Journal, 2012, 198: 246-253.

LIU S, WANG Z, LU Y X, et al . Sunlight-induced uranium extraction with triazine-based carbon nitride as both photocatalyst and adsorbent [J ] . Applied Catalysis B:Environmental, 2021, 282: 119523.

CHEN M Q, LI S S, LI L P, et al . Memory effect induced the enhancement of uranium(VI) immobilization on low-cost MgAl-double oxide: Mechanism insight and resources recovery [J ] . Journal of Hazardous Materials, 2021, 401: 123447.

LI M X, LIU H B, CHEN T H, et al . Efficient U(VI) adsorption on iron/carbon composites derived from the coupling of cellulose with iron oxides: performance and mechanism [J ] . Science of the Total Environment, 2020, 703: 135604.

AGRAWAL Y K, SHRIVASTAV P, MENON S K. Solvent extraction, separation of uranium(VI) with crown ether [J]. Separation and Purification Technology, 2000, 20(2-3): 177-183.

WANG F H, LI H P, LIU Q, et al . A graphene oxide/amidoxime hydrogel for enhanced uranium capture [J ] . Scientific Reports, 2016, 6(1): 19367.

XU X, ZHANG H J, AO J X, et al . 3D hierarchical porous amidoxime fibers speed up uranium extraction from seawater [J ] . Energy Environmental Science, 2019, 12(6): 1979-1988.

CHENG G, ZHANG A R, ZHAO Z W, et al . Extremely stable amidoxime functionalized covalent organic frameworks for uranium extraction from seawater with high efficiency and selectivity [J ] . Science Bulletin, 2021, 66(19): 1994-2001.

AO J X, HAN J G, XU X, et al . Enhanced performance in uranium extraction by quaternary ammonium-functionalized amidoxime-based fibers [J ] . Industrial Engineering Chemistry Research, 2020, 59(13): 5828-5837.

XU L, CHEN Y, SU W, et al . Synergistic adsorption of U(VI) from seawater by Mxene and amidoxime mixed matrix membrane with high efficiency [J ] . Separation and Purification Technology., 2023, 309: 123024.

GÓRKA J, MAYES R T, BAGGETTO L, et al . Sonochemical functionalization of mesoporous carbon for uranium extraction from seawater [J ] . Journal of Materials Chemistry A, 2013, 1(9): 3016-3026.

YUAN Y H, NIU B Y, YU Q H, et al . Photoinduce d multiple effects to enhance uranium extraction from natural seawater by black phosphorus nanosheets [J ] . Angewandte Chemie International Edition, 2020, 59(3): 1220-1227.

ZHAO S, YUAN Y, YU Q, et al . A dual-surface amidoximated halloysite nanotube for high-efficiency economical uranium extraction from seawater [J ] . Angewandte Chemie International Edition, 2019, 131(42): 15121-15127.

YAGHI M O, LI H L. Hydrothermal synthesis of a metal-organic framework containing large rectangular channels [J]. Journal of the American Chemical Society, 2002, 117(41): 10401-10402.

ZHU Y J, XU Y, JIAN M P, et al . Progress of metal-organic frameworks for uranium extraction from seawater [J ] . Chemical Industry and Engineering Progress, 2023, 42(6): 3029-3048.

CARBONI M, ABNEY C W, LIU S B, et al . Highly porous and stable metal-organic frameworks for uranium extraction [J ] . Chemical Science, 2013, 4(6): 2396-2402.

LIU T, ZHANG X, GU A, et al . In-situ grown bilayer MOF from robust wood aerogel with aligned microchannel arrays toward selective extraction of uranium from seawater [J ] . Chemical Engineering Journal, 2022, 433: 134346.

GUTOV O V, HEVIA M G, ESCUDERO-ADAN E C, et al . Metal-Organic Framework (MOF) defects under control: insights into the missing linker sites and their implication in the reactivity of zirconium-based frameworks [J ] . Inorganic Chemistry, 2015, 54(17): 8396-8400.

CHEN L, BAI Z L, ZHU L, et al . Ultrafast and efficient extraction of uranium from seawater using an amidoxime appended metal-organic framework [J ] . ACS Applied Materials Interfaces, 2017, 9(38): 32446-32451.

ZHAO Z W, LEI R C, ZHANG Y Z, et al . Defect controlled MOF-808 for seawater uranium capture with high capacity and selectivity [J ] . Journal of Molecular Liquids, 2022, 367: 120514.

YUAN Y H, FENG S W, FENG L J, et al . A bio-inspired nano-pocket spatial structure for targeting uranyl capture [J ] . Angewandte Chemie International Edition, 2020, 59(11): 4262-4268.

FENG L J, WANG H, FENG T T, et al . In situ synthesis of uranyl-imprinted nanocage for selective uranium recovery from seawater [J ] . Angewandte Chemie International Edition, 2022, 134(13): e202101015.

LIU D H, ZHONG C L. Understanding gas separation in metal-organic frameworks using computer modeling [J]. Journal of Materials Chemistry, 2010, 20(46): 10308-10318.

LIN Z J, LU J, HONG M C, et al . Metal-Organic Frameworks based on flexibleligands (FL-MOFs) : structures and applications [J ] . Chemical Society Reviews, 2014, 43(16): 5867-5895.

WANG M, FENG L, LUO G, et al . Ultrafast extraction of uranium from seawater using photosensitized biohybrid system with bioinspired cascaded strategy [J ] . Journal of Hazardous Materials, 2023, 445: 130620.

LI C, WANG M L, LUO X G. Uptake of uranium from aqueous solution by nymphaea tetragona georgi: the effect of the accompanying heavy metals [J]. Applied Radiation and Isotopes, 2019, 150: 157-163.

YUAN Y H, YU Q H, YANG S, et al . Ultrafast recovery of uranium from seawater by bacillus velezensis strain UUS-1 with innate anti-biofouling activity [J ] . Advanced Science, 2019, 6(18): 1900961.

HE D, TAN N, LUO X, et al . Preparation, uranium (VI) absorption and reuseability of marine fungus mycelium modified by the bis-amidoxime-based groups[J ] Radiochimica Acta, 2019, 108(1) : 37-49.

ZHOU L, BOSSCHER M, ZHANG, C, et al . A protein engineered to bind uranyl selectively and with femtomolar affinity [J ] . Nature Chemistry, 2014, 6: 236-241.

YANG L, XIAO H, QIAN, Y, et al . Bioinspired hierarchical porous membrane for efficient uranium extraction from seawater [J ] . Nature Sustainability, 2022, 5: 71-80.

YUAN Y H, YU Q H, WEN J, et al . Ultrafast and highly selective uranium extraction from seawater by hydrogel-like spidroin-based protein fiber [J ] . Angewandte Chemie International Edition, 2019, 58(34): 11785-11790.

YU Q H, YUAN Y H, FENG L J, et al . Spidroin-inspired, high-strength, loofah-shaped protein fiber for capturing uranium from seawater [J ] . Angewandte Chemie International Edition, 2020, 59(37): 15997-16001.

AGUILA B, SUN Q, CASSADY H, et al . Design strategies to enhance amidoxime chelators for uranium recovery [J ] . ACS Applied Materials Interfaces, 2019, 11(34): 30919-30926.

SEKO N, KATAKAI A, HASEGAWA S, et al . Aquaculture of uranium in seawater by a fabric-adsorbent submerged system [J ] . Nuclear Technology, 2003, 144(2): 274-278.

LADSHAW A P, DAS S, LIAO W P, et al . Experiments and modeling of uranium uptake by amidoxime-based adsorbent in the presence of other ions in simulated seawater [J ] . Industrial Engineering Chemistry Research, 2016, 55(15): 4241-4248.

GILL G A, KUO L J, JANKE C J, et al . The uranium from seawater program at the pacific northwest national laboratory: overview of marine testing, adsorbent characterization, adsorbent durability, adsorbent toxicity, and deployment studies [J ] . Industrial Engineering Chemistry Research, 2016, 55(15): 4264-4277.

XIE Y, LIU Z Y, GENG Y Y, et al . Uranium extraction from seawater: material design, emerging technologies and marine engineering [J ] . Chemical Society Reviews, 2023, 52(1): 97-162.

LI Z M, NIU Y Q, SU Y T, et al . Latest research progress of uranium extraction from seawater [J ] . Journal of Nuclear and Radiochemistry, 2022, 44(3): 233-245.

LEJARS M, MARGAILLAN A, BRESSY C. Fouling release coatings: a nontoxic alternative to biocidal antifouling coatings [J]. Chemical Reviews, 2012, 112(8): 4347-4390.

PARK J, GILL G A, STRIVENS J E, et al . Effect o f biofouling on the performance of amidoxime-based polymeric uranium adsorbents [J ] . Industrial Engineering Chemistry Research, 2016, 55(15): 4328-4338.

ZHU J, ZHANG H, CHEN R, et al . An anti-algae adsorbent for uranium extraction: i-arginine functionalized graphene hydrogel loaded with Ag nanoparticles [J ] . Journal of Colloid and Interface Science, 2019, 543: 192-200.

LI N, GAO P, CHEN H, et al , Amidoxime modified Fe304@TiO 2 particles for antibacterial and efficient uranium extraction from seawater[J ] . Chemosphere, 2022, 287: 132137.

MA H C, ZHANG F, LI Q Y, et al . Preparation of ZnO nanoparticle loaded amidoximated wool fibers as a promising antibiofouling adsorbent for uranium(VI) recovery [J ] . RSC Advances, 2019, 9(32): 18406-18414.

LI H, HE N N, CHENG C, et al . Antimicrobial polymer contained adsorbent: a promising candidate with remarkable anti-biofouling ability and durability for enhanced uranium extraction from seawater [J ] . Chemical Engineering Journal, 2020, 388: 124273.

ZHANG Y, CAI T, ZHAO Z, et al . Poly (amidoxime) -graft-magnetic chitosan for highly efficient and selective uranium extraction from seawater [J ] . Carbohydrate Polymers, 2023, 301: 12036 7.

KUO L J, PAN H B, WAI C M, et al . Investigations into the reusability of amidoxime-based polymeric adsorbents for seawater uranium extraction [J ] . Industrial Engineering Chemistry Research, 2017, 56(40): 11603-11611.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

具守恒量波动方程的循环双子网物理信息神经网络

基于数字混频的脉冲式激光测距方法的研究与实现

面向灾后救援的多无人机通感算一体化资源分配优化方法

SCA-YOLO: 基于可变形卷积与上下文感知注意力的实时目标检测

多尺度对比嵌入增强的自适应入侵检测模型