金属有机框架材料化学微环境调控及在锂硫电池中的应用

欢迎来到能源电力期刊网！

English Version 期刊登录

您当前的位置：

首页 >

文章列表页 >

金属有机框架材料化学微环境调控及在锂硫电池中的应用

催化与能源材料 | 更新时间：2026-05-27

- 金属有机框架材料化学微环境调控及在锂硫电池中的应用
- Chemical Regulation of Microenvironment in Metal-organic Frameworks for Lithium-sulfur Batteries
- 广东工业大学学报 2023年40卷第6期页码：75-87
- 作者机构：
  
  广东工业大学材料与能源学院,广东,广州,510006
- 作者简介：
  
  翁竟洽(2001–) ，男，硕士研究生，主要研究方向为金属有机框架材料在锂硫电池中的应用
  张琪(1990–)，男，副教授，博士，主要研究方向为储能材料与器件，E-mail：qzhangmse@gdut.edu.cn
  黄少铭(1965–)，男，教授，博士生导师，主要研究方向为低维功能材料与器件，E-mail：smhuang@gdut.edu.cn
- 基金信息：
  
  国家自然科学基金资助项目(51920105004, 51902060);广州市基础与应用基础研究一般项目(2023A04J1602)
- DOI：10.12052/gdutxb.230123
  中图分类号： TM911
- 网络首发：2023-11-25，
  
  纸质出版：2023
- 稿件说明：
移动端阅览
翁竟洽, 张琪, 黄少铭. 金属有机框架材料化学微环境调控及在锂硫电池中的应用[J]. 广东工业大学学报, 2023, 40(6): 75-87.

Weng Jing-qia, Zhang Qi, Huang Shao-ming. Chemical Regulation of Microenvironment in Metal-organic Frameworks for Lithium-sulfur Batteries[J]. 2023, 40(6): 75-87.
翁竟洽, 张琪, 黄少铭. 金属有机框架材料化学微环境调控及在锂硫电池中的应用[J]. 广东工业大学学报, 2023, 40(6): 75-87. DOI： 10.12052/gdutxb.230123.

Weng Jing-qia, Zhang Qi, Huang Shao-ming. Chemical Regulation of Microenvironment in Metal-organic Frameworks for Lithium-sulfur Batteries[J]. 2023, 40(6): 75-87. DOI： 10.12052/gdutxb.230123.

摘要

锂硫电池(Lithium-Sulfur Batteries

LSBs)因硫具有高理论比容量、较低的成本以及环境友好性，被认为是最有潜力的新一代储能器件之一。然而，目前LSBs仍存在一些未解决的关键问题，如氧化还原动力学缓慢、多硫化物(Lithium Polysulfides

LiPSs)溶解和扩散引发的穿梭效应，以及充放电过程中电极的体积变化等。这些问题导致LSBs容量及循环稳定性较差，严重阻碍了LSBs的实际应用。金属有机框架(Metal-organic Frameworks

MOFs)材料具有高度可调的孔化学微环境，通过调控金属中心/团簇和有机配体可以在分子层级调控MOFs对多硫离子等客体分子的化学吸附和催化能力。因此，将MOFs应用于LSBs中，能够有效地实现对多硫离子的捕获、阻隔并加速其催化转化，进而实现对穿梭效应的抑制并提高LSBs的电化学性能。本文总结了通过对MOFs孔化学微环境进行调控，开发出的各种基于MOFs的高性能插层膜材料、正极材料和多功能隔膜材料，并分析了MOFs孔化学微环境进行调控影响LSBs性能的机理，最后提出了可应用于高性能LSBs的MOFs材料开发存在的问题及发展方向。

Abstract

Lithium-sulfur batteries (LSBs) are considered to be one of the most promising new generation energy storage device owing to the high theoretical specific capacity

low cost

and environmental friendliness of sulfur. However

there are still some unsolved critical issues in LSBs

such as slow redox kinetics

shuttle effect caused by dissolution and diffusion of lithium polysulfides (LiPSs)

as well as volume changes in electrodes during charge/discharge processes. which result in poor capacity and cycling stability

severely hinder the practical application of LSBs. Metal-organic frameworks (MOFs) have highly tunable pore microenvironment

and their chemical adsorption and catalytic abilities towards guest molecules

such as polysulfides

can be precisely controlled at the molecular level by regulating the metal centers/clusters and organic ligands. Therefore

applying MOFs to LSBs can effectively capture

block and accelerate the catalytic conversion of polysulfides

thus inhibiting the shuttle effect and improving the electrochemical performance of LSBs. This review summarizes various high performance interlayer materials

cathode materials and multifunctional separator materials based on MOFs developed by regulating the pore microenvironment of MOFs

and analyzes the mechanism of regulating MOFs’ microenvironment affecting the performance of LSBs. Finally

the problem and development direction of MOFs materials applicable to high performance LSBs are proposed.

关键词

Keywords

references

WU M M, ZHOU Z, et al . Covalent organic frameworks as electrode materials for rechargeable metal-ion batteries [J ] . Interdisciplinary Materials, 2023, 2(2): 231-259.

CHAYAMBUKA K, MULDER G, DANILOV D L, et al . From li-ion batteries toward Na-ion chemistries: challenges and opportunities [J ] . Advanced Energy Materials, 2020, 10(38): 2001310.

XIAO Y B, GONG W, GUO S J, et al . Regulating coordination environment in metal-organic frameworks for adsorption and redox conversion of polysulfides in lithium-sulfur batteries [J ] . ACS Materials Letters, 2021, 3(12): 1684-1694.

MENG R J, DU Q J, ZHONG N, et al . A tandem electrocatalysis of sulfur reduction by bimetal 2D MOFs [J ] . Advanced Energy Materials, 2021, 11(47): 2102819.

ZENG Q H, LI X, GONG W, et al . Copolymerization of sulfur chains with vinyl functionalized metal-organic framework for accelerating redox kinetics in lithium-sulfur batteries [J ] . Advanced Energy Materials, 2022, 12(21): 2104074.

LIANG J, SUN Z H, LI F, et al . Carbon materials for Li-S batteries: Functional evolution and performance improvement [J ] . Energy Storage Materials, 2016, 2: 76-106.

DU M, LI Q, ZHANG G, et al . Metal-organic framework-based sulfur-loaded materials [J ] . Energy Environmental Materials, 2022, 5(1): 215-230.

NI L B, ZHAO G J, YANG G, et al . Dual core-shell-structured S@ C@ MnO2 nanocomposite for highly stable lithium-sulfur batteries [J ] . ACS Applied Materials Interfaces, 2017, 9(40): 34793-34803.

LEI T Y, CHEN W, HUANG J, et al . Multi-functional layered WS 2 nanosheets for enhancing the performance of lithium-sulfur batteries [J ] . Advanced Energy Materials, 2017, 7(4): 1601843.

ZHENG Y, ZHENG S S, XUE H G, et al . Metal-organic frameworks for lithium-sulfur batteries [J ] . Journal of Materials Chemistry A, 2019, 7(8): 3469-3491.

GENG P, WANG L, DU M, et al . MIL-96-Al for Li- S batteries: shape or size? [J ] . Advanced Materials, 2022, 34(4): 2107836.

ZHOU M, J LI Y Y, LEI T Y, et al . Ion-inserted metal-organic frameworks accelerate the mass transfer kinetics in lithium-sulfur batteries [J ] . Small, 2021, 17(44): 2104367.

CAPKOVÁ D, KAZDA T, ČECH O, et al . Influence of metal-organic framework MOF-76 (Gd) activation/carbonization on the cycle performance stability in Li-S battery [J ] . Journal of Energy Storage, 2022, 51: 104419.

WANG Z Q, HUANG W Y, HUA J C, et al . An anionic-MOF-based bifunctional separator for regulating lithium deposition and suppressing polysulfides shuttle in Li-S batteries [J ] . Small Methods, 2020, 4(7): 2000082.

ZHANG L, HOU Y L. The rise and development of MOF-based materials for metal-chalcogen batteries: current status, challenges, and prospects[J]. Advanced Energy Materials, 2023, 13(20): 2204378.

QI C, XU L, WANG J, et al . Titanium-containing metal-organic framework modified separator for advanced lithium-sulfur batteries [J ] . ACS Sustainable Chemistry Engineering, 2020, 8(34): 12968-12975.

BAI S Y, LIU X Z, ZHU K, et al . Metal-organic framework-based separator for lithium-sulfur batteries [J ] . Nature Energy, 2016, 1(7): 1-6.

MANTHIRAM A, FU Y Z, SU Y S. Challenges and prospects of lithium-sulfur batteries [J]. Accounts of Chemical Research, 2013, 46(5): 1125-1134.

MANTHIRAM A, FU Y Z, CHUNG S H, et al . Rechargeable lithium-sulfur batteries [J ] . Chemical Reviews, 2014, 114(23): 11751-11787.

WANG D W, ZENG Q C, ZHOU G M, et al . Carbon-sulfur composites for Li-S batteries: status and prospects [J ] . Journal of Materials Chemistry A, 2013, 1(33): 9382-9394.

FANG R P, ZHAO S Y, SUN Z H, et al . More reliable lithium-sulfur batteries: status, solutions and prospects [J ] . Advanced Materials, 2017, 29(48): 1606823.

YAGHI O M, LI H L. Hydrothermal synthesis of a metal-organic framework containing large rectangular channels [J]. Journal of the American Chemical Society, 1995, 117(41): 10401-10402.

GUO S J, XIAO Y B, WANG J, et al. Ordered structure of interlayer constructed with metal-organic frameworks improves the performance of lithium-sulfur batteries[J]. Nano Research, 2021, 14(12): 4556-4562.

TIAN M, PEI F, YAO M S, et al . Ultrathin MOF nanosheet assembled highly oriented microporous membrane as an interlayer for lithium-sulfur batteries [J ] . Energy Storage Materials, 2019, 21: 14-21.

HONG X J, SONG C L, YANG Y, et al . Cerium based metal-organic frameworks as an efficient separator coating catalyzing the conversion of polysulfides for high performance lithium-sulfur batteries [J ] . ACS Nano, 2019, 13(2): 1923-1931.

ZHOU J W, LI R, FAN X X, et al . Rational design of a metal-organic framework host for sulfur storage in fast, long-cycle Li-S batteries [J ] . Energy Environmental Science, 2014, 7(8): 2715-2724.

YANG D W, LIANG Z F, TANG P Y, et al . A high conductivity 1d π-d conjugated metal-organic framework with efficient polysulfide trapping-diffusion-catalysis in lithium-sulfur batteries [J ] . Advanced Materials, 2022, 34(10): 2108835.

HAN D D, WANG Z Y, PAN G L, et al . Metal-organic-framework-based gel polymer electrolyte with immobilized anions to stabilize a lithium anode for a quasi-solid-state lithium-sulfur battery [J ] . ACS Applied Materials Interfaces, 20 19, 11(20): 18427-18435.

CHIOCHAN P, YU X, SAWANGPHRUK M, et al . A metal organic framework derived solid electrolyte for lithium-sulfur batteries [J ] . Advanced Energy Materials, 2020, 10(27): 2001285.

LIU B, TAHERI M, TORRES J F, et al . Janus conductive/insulating microporous ion-sieving membranes for stable Li-S batteries [J ] . ACS Nano, 2020, 14(10): 13852-13864.

LI L, LUO Y, WANG Y, et al . Rational design of a well-aligned metal-organic framework nanopillar array for superior lithium-sulfur batteries [J ] . Chemical Engineering Journal, 2023, 454: 140043.

WANG X, WANG Y, WU F, et al . Continuous zirconium-based MOF-808 membranes for polysulfide shuttle suppression in lithium-sulfur batteries [J ] . Applied Surface Science, 2022, 596: 153628.

SU Y, WANG W, WANG W, et al . Cerium-based MOF as a separator coating for high-performance lithium-sulfur batteries [J ] . Journal of The Electrochemical Society, 2022, 169(3): 030528.

ZHU Z, ZENG Y, PEI Z, et al . Bimetal-organic framework nanoboxes enable accelerated redox k inetics and polysulfide trapping for lithium-sulfur batteries [J ] . Angewandte Chemie, 2023, 135(31): e202305828.

RANA M, AL-FAYAAD H A, LUO B, et al . Oriented nanoporous MOFs to mitigate polysulfides migration in lithium-sulfur batteries [J ] . Nano Energy, 2020, 75: 105009.

LI X, ZHANG X, XU Y, et al. Metallic and dimensional optimization of metal-organic frameworks for high-performance lithium-sulfur batteries[J]. Chemistry: A European Journal, 2023, 29(31): e202300407.

CAPKOVÁ D, ALMÁŠI M, KAZDA T, et al . Metal-organic framework MIL-101 (Fe) -NH 2 as an efficient host for sulphur storage in long-cycle Li-S batteries [J ] . Electrochimica Acta, 2020, 354: 136640.

LI Y, LIN S, WANG D, et al . Single atom array mimic on ultrathin MOF nanosheets boosts the safety and life of lithium–sulfur batteries [J ] . Advanced Materials, 2020, 32(8): 1906722.

LEE D H, AHN J H, PARK M S, et al . Metal-organic framework/carbon nanotube-coated polyethylene separator for improving the cycling performance of lithium-sulfur cells [J ] . Electrochimica Acta, 2018, 283: 1291-1299.

LI J, JIAO C M, ZHU J H, et al . Hybrid co-based MOF nanoboxes/CNFs interlayer as microreactors for polysulfides-trapping in lithium-sulfur batteries [J ] . Journal of Energy Chemistry, 2021, 57: 469-476.

SUNG S H, KIM B H, LEE S T, et al . Increasing sulfur utilization in lithium-sulfur batteries by a Co-MOF-74@ MWCNT interlayer [J ] . Journal of Energy Chemistry, 2021, 60: 186-193.

XIAO Y B, XIANG Y C, GUO S J, et al . An ultralight electroconductive metal-organic framework membrane for multistep catalytic conversion and molecular sieving in lithium-sulfur batteries [J ] . Energy Storage Materials, 2022, 51: 882-889.

FENG P, HOU W, BAI Z, et al . Ultrathin two-dimensional bimetal NiCo-based MOF nanosheets as ultralight interlayer in lithium-sulfur batteries [J ] . Chinese Chemical Letters, 2023, 34(4): 107427.

GUO S J, XIAO Y B, CHEREVAN A, et al . Catalytic multivariable metal-organic frameworks for lithium-sulfur batteries [J ] . Materials Today, 2023, 65: 37-46.

DANG B Y, GAO D Y, LUO Y H, et al . Bifunctional design of cerium-based metal-organic framework-808 membrane modified separator for polysulfide shuttling and dendrite growt h inhibition in lithium-sulfur batteries [J ] . Journal of Energy Storage, 2022, 52: 104981.

ZHENG J M, TIAN J, WU D X, et al . Lewis acid-base interactions between polysulfides and metal organic framework in lithium sulfur batteries [J ] . Nano Letters, 2014, 14(5): 2345-2352.

LI P R, MA L, WU T P, et al . Chemical immobilization and conversion of active polysulfides directly by copper current collector: a new approach to enabling stable room-temperature Li-S and Na-S batteries [J ] . Advanced Energy Materials, 2018, 8(22): 1800624.

GENG P B, DU M, GUO X T, et al . Bimetallic metal-organic framework with high-adsorption capacity toward lithium polysulfides for lithium-sulfur batteries [J ] . Energy Environmental Materials, 2022, 5(2): 599-607.

LI W T, GUO X T, GENG P B, et al . Rational design and general synthesis of multimetallic metal-organic framework nano-octahedra for enhanced Li-S battery [J ] . Advanced Materials, 2021, 33(45): 2105163.

ZENG Q H, XU L L, LI G X, et al. Integrating sub-nano catalysts into metal-organic framework toward pore-confined polysulfides conversion in lithium-sulfur batteries[J]. Advanced Functional Materials, 2023, 33(43): 2304619.

CAI D, LU M J, LI L, et al . A highly conductive MOF of graphene analogue Ni 3 (HITP) 2 as a sulfur host for high-performance lithium-sulfur batteries [J ] . Small, 2019, 15(44): 1902605.

BAO W Z, ZHANG Z A, QU Y H, et al . Confine sulfur in mesoporous metal-organic framework@ reduced graphene oxide for lithium sulfur battery [J ] . Journal of Alloys and Compounds, 2014, 582: 334-340.

HOU Y P, MAO H Z, XU L Q. et al. MIL-100 (V) and MIL-100 (V) /rGO with various valence states of vanadium ions as sulfur cathode hosts for lithium-sulfur batteries [J]. Nano Research, 2017, 10: 344-353.

ZHANG H, ZHAO W Q, ZOU M C, et al . 3D, mutually embedded MOF@ carbon nanotube hybrid networks for high-performance lithium-sulfur batteries [J ] . Advanced Energy Materials, 2018, 8(19): 1800013.

JIANG H Q, LIU X C, WU Y S, et al . Metal-organic frameworks for high charge-discharge rates in lithium-sulfur batteries [J ] . Angewandte Chemie International Edition, 2018, 57(15): 3916-3921.

GENG P B, CAO S, GUO X T, et al . Polypyrrole coated hollow metal- organic framework composites for lithium-sulfur batteries [J ] . Journal of Materials Chemistry A, 2019, 7(33): 19465-19470.

BAI S Y, ZHU K, WU S C, et al . A long-life lithium-sulphur battery by integrating zinc-organic framework based separator [J ] . Journal of Materials Chemistry A, 2016, 4(43): 16812-16817.

0

浏览量

0

下载量

0

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

相关文章

钒基硫化物-MXene异质催化剂的制备及锂硫电池催化机理对比研究

人工噪声辅助无人机太赫兹安全通信的鲁棒设计

多套餐共享储能模式下考虑功率互济的社区联盟优化运行策略

基于高效时序建模的RGB-T跟踪

基于数字混频的脉冲式激光测距方法的研究与实现

相关作者

王心英

陈丽

张嘉城

玉耀江

王译

李运勇

相关机构

暂无数据

AI问答

⁰