SnSe<sub>2</sub>@C储钠负极材料的合成及电化学性能研究

钟家锐; 林琳; 郑程

doi:10.12052/gdutxb.230116

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SnSe₂@C储钠负极材料的合成及电化学性能研究

材料科学与技术 | 更新时间：2026-05-27

- SnSe₂@C储钠负极材料的合成及电化学性能研究
- Synthesis and Electrochemical Research of Sodium Storage Anode SnSe₂@C
- 广东工业大学学报 2024年41卷第3期页码：29-35
- 作者机构：
  
  广东工业大学材料与能源学院,广东,广州,510006
- 作者简介：
  
  钟家锐(1998–) ，男，硕士研究生，主要研究方向为钠离子电池电极材料制备，E-mail：2769094782@qq.com
  郑程(1985–) ，女，副教授，博士研究生，主要研究方向为钠离子电池，E-mail：zhengcheng@gdut.edu.cn
- 基金信息：
  
  国家自然科学基金资助面上项目(52372184)
- DOI：10.12052/gdutxb.230116
  中图分类号： TM912.5
- 网络首发：2024-05-25，
  
  纸质出版：2024
- 稿件说明：
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钟家锐, 林琳, 郑程. SnSe₂@C储钠负极材料的合成及电化学性能研究[J]. 广东工业大学学报, 2024, 41(3): 29-35. DOI: 10.12052/gdutxb.230116.

Zhong Jia-rui, Lin Lin, Zheng Cheng. Synthesis and Electrochemical Research of Sodium Storage Anode SnSe₂@C[J]. 2024, 41(3): 29-35. DOI: 10.12052/gdutxb.230116.
钟家锐, 林琳, 郑程. SnSe₂@C储钠负极材料的合成及电化学性能研究[J]. 广东工业大学学报, 2024, 41(3): 29-35. DOI: 10.12052/gdutxb.230116. DOI：

Zhong Jia-rui, Lin Lin, Zheng Cheng. Synthesis and Electrochemical Research of Sodium Storage Anode SnSe₂@C[J]. 2024, 41(3): 29-35. DOI: 10.12052/gdutxb.230116. DOI：

摘要

二硒化锡(SnSe

)具有高理论比容量、原料广泛、成本低廉等优点，是一种十分有前途的钠离子电池负极材料，但同时在实际充放电过程中也受限于体积膨胀导致的结构破坏问题。鉴于此，本文通过高温煅烧的方法成功合成了碳包覆的二硒化锡(SnSe

@C)。碳包覆提高了二硒化锡材料作为钠离子电池负极的导电性和稳定性，使得SnSe

@C具有优异的高比容量(在1.0 A·g

−1

下，比容量为549.0 mAh·g

−1

)和倍率性能(在5.0 A·g

−1

下，比容量为427.7 mAh·g

−1

)。

Abstract

Tin selenide (SnSe

) is a very promising negative electrode material for sodium ion batteries

which has advantages such as high theoretical specific capacity

wide range of raw materials

and low cost. However

it is also limited by the structural damage caused by volume expansion during charging and discharging processes. A research is conducted on the successful synthesis of carbon coated tin selenide (SnSe

@C) through high-temperature annealing. Carbon coating improves the conductivity and stability of the material as sodium-ion battery anode

making SnSe

@C has high specific capacity (549.0 mAh·g

−1

at 1.0 A·g

−1

) and excellen

t rate performance (427.7 mAh·g

−1

at 5.0 A·g

−1

关键词

Keywords

references

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SnSe2@C储钠负极材料的合成及电化学性能研究

Synthesis and Electrochemical Research of Sodium Storage Anode SnSe2@C

DOI：10.12052/gdutxb.230116

摘要

Abstract

关键词

Keywords

references

SnSe₂@C储钠负极材料的合成及电化学性能研究

Synthesis and Electrochemical Research of Sodium Storage Anode SnSe₂@C