Zn/Fe纳米颗粒共嵌入碳纳米管提高氧还原反应性能

吴梦雪; 马金福; 刘子逸; 刘慧泽; 王冠东; 陈轩毅; 施志聪

doi:10.12052/gdutxb.230114

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Zn/Fe纳米颗粒共嵌入碳纳米管提高氧还原反应性能

催化与能源材料 | 更新时间：2026-05-27

- Zn/Fe纳米颗粒共嵌入碳纳米管提高氧还原反应性能
- Zn/Fe Nanoparticles Co-embedded with Carbon Nanotubes Improve the Oxygen Reduction Reaction Performance
- 广东工业大学学报 2023年40卷第6期页码：106-113, 184
- 作者机构：
  
  1. 广东工业大学材料与能源学院,广东,广州,510006
  2. 北方民族大学材料科学与工程学院,宁夏,银川,750021
- 作者简介：
  
  吴梦雪(1997–)，女，博士研究生，主要研究方向为金属−空气电池，E-mail：wumengxue1741@163.com
  马金福(1980–)，教授，博士，主要研究方向为新能源材料、燃料电池，E-mail：ma_jinfu@nun.edu.cn
  施志聪(1976–)，男，教授，博士，主要研究方向为新能源材料、新型电池、电化学测试技术，E-mail：zhicong@gdut.edu.cn
- 基金信息：
  
  国家自然科学基金资助项目(21865002);宁夏自然科学基金资助项目(2022AAC02044)
- DOI：10.12052/gdutxb.230114
  中图分类号： TM912
- 网络首发：2023-11-25，
  
  纸质出版：2023
- 稿件说明：
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吴梦雪, 马金福, 刘子逸, 刘慧泽, 王冠东, 陈轩毅, 施志聪. Zn/Fe纳米颗粒共嵌入碳纳米管提高氧还原反应性能[J]. 广东工业大学学报, 2023, 40(6): 106-113, 184.

Wu Meng-xue, Ma Jin-fu, Liu Zi-yi, et al. Zn/Fe Nanoparticles Co-embedded with Carbon Nanotubes Improve the Oxygen Reduction Reaction Performance[J]. 2023, 40(6): 106-113, 184.
吴梦雪, 马金福, 刘子逸, 刘慧泽, 王冠东, 陈轩毅, 施志聪. Zn/Fe纳米颗粒共嵌入碳纳米管提高氧还原反应性能[J]. 广东工业大学学报, 2023, 40(6): 106-113, 184. DOI： 10.12052/gdutxb.230114.

Wu Meng-xue, Ma Jin-fu, Liu Zi-yi, et al. Zn/Fe Nanoparticles Co-embedded with Carbon Nanotubes Improve the Oxygen Reduction Reaction Performance[J]. 2023, 40(6): 106-113, 184. DOI： 10.12052/gdutxb.230114.

摘要

开发低成本、高稳定、高催化活性氧化还原反应(Oxygen Reduction Reaction

ORR)的非贵金属催化剂对燃料电池和金属−空气电池的应用至关重要。本文研究了以ZIF-8为前驱体一步合成ZnFe纳米颗粒嵌入N、S掺杂碳纳米管的复合催化剂(ZnS-FeS-Fe

C/S

NCNT)。通过电化学测试确定最优煅烧温度后的样品ZFF/S

NCNT-8的起始电位

为0.99 V vs. RHE和半波电位

1/2

为0.84 V vs. RHE，并且与商业Pt/C相当，具有良好的甲醇耐受性和长期稳定性。同时也提出S、N共掺杂碳纳米管(Carbon Nanotube

CNT) 和额外的ZnS、FeS和Fe

C提供活性位点可以提高ORR催化性能。文中所采用的原位生长CNT方法，可为制备燃料电池和金属−空气电池的阴极催化剂提供思路。

Abstract

The development of low-cost

highly stable

and catalytically active oxygen reduction reaction (ORR) non-precious metal catalysts is essential for fuel cells and metal-air batteries applications. In this study

the one-step synthesis of composite catalysts of ZnFe nanoparticles embedded with nitrogen and sulfur doped carbon nanotubes (ZnS-FeS-Fe

C/S

NCNT) was reported using ZIF-8 as precursor. The sample of ZFF/S

NCNT-8 after the optimal calcination temperature was determined by electrochemical tests to be onset potential of 0

.99 V vs. RHE and a half-wave potential of 0.84 V vs. RHE

as well as a good methanol tolerance and long-term durability comparable to commercial Pt/C. It is also proposed that S

N co-doped carbon nanotube (CNT) and additional ZnS

FeS and Fe

C providing active sites can enhance the ORR catalytic performance. The in-situ growth CNT method used in the study can provide ideas for the preparation of cathode catalysts for fuel cells and metal-air batteries.

关键词

Keywords

references

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